Coexistence of Bulk-Nodal and Surface-Nodeless Cooper Pairings in a Superconducting Dirac Semimetal.

The interplay of nontrivial topology and superconductivity in condensed matter physics gives rise to exotic phenomena. However, materials are extremely rare where it is possible to explore the full details of the superconducting pairing. Here, we investigate the momentum dependence of the superconducting gap distribution in a novel Dirac material PdTe. Using high resolution, low temperature photoemission spectroscopy, we establish it as a spin-orbit coupled Dirac semimetal with the topological Fermi arc crossing the Fermi level on the (010) surface. This spin-textured surface state exhibits a fully gapped superconducting Cooper pairing structure below T_{c}∼4.5 K. Moreover, we find a node in the bulk near the Brillouin zone boundary, away from the topological Fermi arc. These observations not only demonstrate the band resolved electronic correlation between topological Fermi arc states and the way it induces Cooper pairing in PdTe, but also provide a rare case where surface and bulk states host a coexistence of nodeless and nodal gap structures enforced by spin-orbit coupling.

Mn-induced spin glass behavior in metallic Ir3Sn7-xMnx.

Transition metal stannides are usually semiconductors with a narrow band gap. We report experimental investigation on metallic Ir3Sn7-xMnx(x= 0 and 0.56). Single crystal x-ray diffraction refinement indicates that Ir3Sn7-xMnxcrystals form a cubic structure (space groupIm3̄m) with the lattice parametera= 9.362(4) Å forx= 0 and 9.328(6) Å forx= 0.56. The electrical resistivity shows metallic behavior between 2 K and 300 K withT2dependence atT< 30 K forx= 0, reflecting the Fermi-liquid ground state. While Ir3Sn7exhibits weak diamagnetism, partial substitution of Sn by Mn results in spin glass behavior in Ir3Sn7-xMnxbelowTg∼ 13 K forx= 0.56. Remarkably, an upturn in the resistivity is observed inx= 0.56 below ∼2Tg, suggesting strong spin fluctuation. This fluctuation is suppressed by the application of magnetic field, which is reflected in the observation of negative magnetoresistance. The unusual properties that emerge due to Mn doping are discussed.

Low-Dimensional Magnetic Semimetal Cr0.65Al1.35Se3.

While exploring novel magnetic semiconductors, the new phase Cr0.65Al1.35Se3 was discovered and characterized by both structural and physical properties. Cr0.65Al1.35Se3 was found to crystallize into orthorhombic CrGeTe3-type structure with space group Pnma (no. 62). Vacancies and mixed occupancies were tested, and the results show that one of the 4c sites accommodates a mixture of Cr and Al atoms, while the other 4c site is fully occupied by Al atoms. Unique structural features include a T-shaped channel network created from the edge-sharing Cr/Al@Se6 and Al@Se4 polyhedra and a zipper effect of the puckered Se atoms inside the columnar channels. The round peak observed in the temperature-dependent magnetic susceptibility (χg) plot at ∼8(1) K corresponds to the antiferromagnetic-type transition in Cr0.65Al1.35Se3. However, the positive θCW indicates an additional ferromagnetic interaction, which is highly likely due to the complex magnetic structure arising from the mixed Cr/Al occupancies on the 4c site. Electrical resistivity measurements confirm that Cr0.65Al1.35Se3 is a semimetal with a positive magnetoresistance. Here we present the characterization and determination of the crystal structure and physical properties for this new material.