Air pollution trends and exceedances: ozone and particulate matter outlook in Brazilian highly urbanized zones.

In Brazil, scarce air quality data hinders air pollutant chemical understanding and policy decisions regarding public health and environmental impacts. From this perspective, our study assessed the O3, PM2.5, and PM10 yearly and seasonal trends and also the WHO Air Quality Guidelines 2021 exceedance trends at 40 air quality stations located in four highly urbanized zones in Brazil (Belo Horizonte, São Paulo, Rio de Janeiro, and Espírito Santo) from early 1990s up to 2019. We applied the Mann-Kendall test aligned with Sen's Slope estimator to assess the trends and the Cox-Stuart test to verify the WHO AQG 2021 exceedances trends. Our findings pointed out that the current national legislation is outdated when compared to WHO AQG 2021 values, leading to multiple exceedances episodes. We also found out that 62% of São Paulo's stations presented O3 increasing trends, while in Rio de Janeiro 85.7% presented decreasing trends. The Cox-Stuart test pointed out that PM2.5 exceedance trends showcase positive values, and most of the significative values are located in São Paulo stations. Therefore, we endorse that the national legislation needs to be updated meanwhile the air monitoring network needs to expand its coverage.

São Paulo's atmospheric pollution reduction and its social isolation effect, Brazil.

Since January 2020, studies report reductions in air pollution among several countries due to social isolation measures, which have been adopted in order to contain the coronavirus outbreak progress (COVID-19). This study aims to evaluate the change in the atmospheric pollution levels by NO and NO2 in São Paulo City for the social isolation period. The NO and NO2 hourly concentrations were obtained through air quality monitoring stations from CETESB, from January 14, 2020 to April 12, 2020. Mann-Kendall and the Pettitt tests were performed in the air pollutant time series. We observed an overall negative trend in all stations, indicating a decreasing temporal pattern in concentrations. Regarding NO, the highest absolute decrease rates were observed in the Congonhas (- 6.39 µg m-3 month-1) and Marginal Tietê (- 6.19 µg m-3 month-1) stations; regarding NO2, the highest rates were observed in the Marginal Tietê (- 4.45 µg m-3 month-1) and Cerqueira César (- 4.34 µg m-3 month-1) stations. In addition, we identified a turning point in the NO and NO2 series trends that occurred close to the start date of the social isolation period (March 20, 2020). Moreover, from statistical analysis, it was found that NO2 is a suitable surrogate for monitoring economic activities during social isolation periods. Thus, we concluded that social isolation measures implemented on March 20, 2020 caused significant changes in the air pollutant concentrations in the city of São Paulo (as high as - 200% in NO2 levels).