Plants, animals, and fisheries waste-mediated bioremediation of contaminants of environmental and emerging concern (CEECs)-a circular bioresource utilization approach.

The release of contaminants of environmental concern including heavy metals and metalloids, and contaminants of emerging concern including organic micropollutants from processing industries, pharmaceuticals, personal care, and anthropogenic sources, is a growing threat worldwide. Mitigating inorganic and organic contaminants, which can be coined as contaminants of environmental and emerging concern (CEECs), is a big challenge as traditional physicochemical processes are not economically viable for managing mixed contaminants of low concentrations. As a result, low-cost materials must be designed to provide high CEEC removal efficiency. One of the environmentally viable and energy-efficient approaches is biosorption, which involves using biomass or biopolymers isolated from plants or animals to decontaminate heavy metals in contaminated environments using inherent biological mechanisms. Among chemical constituents in plant biomass, cellulose, lignin, hemicellulose, proteins, polysaccharides, phenolic compounds, and animal biomass include polysaccharides and other compounds to bind heavy metals covalently and non-covalently. These functional groups include carboxyl, hydroxyl, carbonyl, amide, amine, and sulfhydryl. Cation-exchange capacities of these bioadsorbents can be improved by applying chemical modifications. The relevance of chemical constituents and bioactives in biosorbents derived from agricultural production such as food and fodder crops, bioenergy and cash crops, fruit and vegetable crops, medicinal and aromatic plants, plantation trees, aquatic and terrestrial weeds, and animal production such as dairy, goatery, poultry, duckery, and fisheries is highlighted in this comprehensive review for sequestering and bioremediation of CEECs, including as many as ten different heavy metals and metalloids co-contaminated with other organic micropollutants in circular bioresource utilization and one-health concepts.

Metallic and non-metallic nanoparticles from plant, animal, and fisheries wastes: potential and valorization for application in agriculture.

Global agriculture is facing tremendous challenges due to climate change. The most predominant amongst these challenges are abiotic and biotic stresses caused by increased incidences of temperature extremes, drought, unseasonal flooding, and pathogens. These threats, mostly due to anthropogenic activities, resulted in severe challenges to crop and livestock production leading to substantial economic losses. It is essential to develop environmentally viable and cost-effective green processes to alleviate these stresses in the crops, livestock, and fisheries. The application of nanomaterials in farming practice to minimize nutrient losses, pest management, and enhance stress resistance capacity is of supreme importance. This paper explores innovative methods for synthesizing metallic and non-metallic nanoparticles using plants, animals, and fisheries wastes and their valorization to mitigate abiotic and biotic stresses and input use efficiency in climate-smart and stress-resilient agriculture including crop plants, livestock, and fisheries.

Heavy metals biosorption mechanism of partially delignified products derived from mango (Mangifera indica) and guava (Psidium guiag) barks.

This paper evaluates the biosorption of toxic metal ions onto the bioadsorbents derived from mango (Mangifera indica) and guava (Psidium guiag) barks and their metal fixation mechanisms. Maximum metal biosorption capacities of the mango bioadsorbent were found in the following increasing order (mg/g): Hg (16.24) < Cu (22.24) < Cd (25.86) < Pb (60.85). Maximum metal biosorption capacities of guava bioadsorbent follow similar order (mg/g): Hg (21.48) < Cu (30.36) < Cd (32.54) < Pb (70.25), but with slightly higher adsorption capacities. The removal mechanisms of heavy metals using bioadsorbents have been ascertained by studying their surface properties and functional groups using various spectrometric, spectroscopic, and microscopic methods. Whewellite (C2CaO4·H2O) has been identified in bioadsorbents based on the characterization of their surface properties using X-ray techniques (XPS and XRD), facilitating the ion exchange of metal ions with Ca2+ bonded with carboxylate moieties. For both the bioadsorbents, the Pb2+, Cu2+, and Cd2+ are biosorbed completely by ion exchange with Ca2+ (89-94%) and Mg2+ (7-12%), whereas Hg2+ is biosorbed partially (57-66%) by ion exchange with Ca2+ (38-42%) and Mg2+ (19-24%) due to involvement of other cations in the ion exchange processes. Bioadsorbents contain lignin which act as electron donor and reduced Cr(VI) into Cr(III) (29.87 and 37.25 mg/g) in acidic medium. Anionic Cr(VI) was not adsorbed onto bioadsorbents at higher pH due to their electrostatic repulsion with negatively charged carboxylic functional groups.