3D Carbon-Based Conductive Network Printed for Glucose Sensors on Curved and Flexible Substrates.

The rising prevalence of diabetes has led to an increased focus on real-time glucose monitoring. Wearable glucose sensor patches allow noninvasive, real-time monitoring, reducing patient discomfort compared to invasive sensors. However, most existing glucose sensor patches rely on complex and contaminating metal vapor deposition technologies, which pose limitations in practical production. In this study, we propose a novel approach for preparing graphite/multiwall carbon nanotubes (MWCNT)/reduced graphene oxide (rGO) using a high-viscosity ink, which can be easily obtained through simple mechanical stirring. To create intricate patterns and enable printing on curved substrates, we employed a 3D printer equipped with an infrared laser ranging system. The ink served as a working electrode, and we developed a three-electrode system patch with a concentric circle structure. Subsequently, the working electrode underwent enzymatic modification with glucose dehydrogenase with flavin adenine dinucleotide (GDH-FAD) using a polymer embedding method. The resulting wearable glucose sensor exhibited a sensitivity of 2.42 µA mM-1 and a linear detection range of 1-12 mM. In addition, the glucose sensor has excellent anti-interference capability and demonstrates good repeatability in simulated real human wear scenarios, which meets the requirements for accurate human detection. These findings provide valuable insights into the development of human health monitoring technologies.

High sensitivity carbon monoxide detector using iron tetraphenyl porphyrin functionalized reduced graphene oxide.

The detection of pollutant and toxic gases has attracted extensive attention due to the growing environmental issues. In the present investigation, free-based tetraphenyl porphyrin (TPP) and iron tetraphenyl porphyrin (FeTPP) are used to functionalize thermally reduced graphene oxide (rGO) and further used for the detection of carbon monoxide (CO). TPP and FeTPP functionalized rGO (FeTPP@rGO) sensors are fabricated on a glass substrate with thermally coated copper electrodes. The materials are characterized with X-ray diffraction (XRD), Fourier transforms infrared (FTIR) spectroscopy, Raman spectroscopy, UV-visible spectroscopy, atomic force microscopy, scanning electron microscopy, and energy dispersive spectroscopy. The current-voltage (I-V) characteristics have also been studied to demonstrate the operation of the device. In addition, the FeTPP@rGO device shows high sensitivity toward the detection of CO. By testing in the chemiresistive sensing modality, the as-fabricated device shows good response and recovery of 60 s and 120 s, respectively, with a low detection limit of 2.5 ppm.

Detection of Pb(II): Au Nanoparticle Incorporated CuBTC MOFs.

In the present investigation, copper benzene tricarboxylate metal organic frameworks (CuBTC MOF) and Au nanoparticle incorporated CuBTC MOF (Au@CuBTC) were synthesized by the conventional solvothermal method in a round bottom flask at 105°C and kept in an oil bath. The synthesized CuBTC MOF and Au@CuBTC MOFs were characterized by structure using X-ray diffraction (XRD) spectroscopic methods including Fourier Transform Infrared spectroscopy, Raman Spectroscopy, X-ray Photoelectron Spectroscopy (XPS), and Energy dispersive spectroscopy (EDS). We also characterized them using morphological techniques such as Field emission scanning electron microscopy (FE-SEM), and electrochemical approaches that included cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). We examined thermal stability by thermogravimetric analysis (TG/DTA) and N2 adsorption-desorption isotherm by Brunauer-Emmett-Teller (BET) surface area method. Both materials were tested for the detection of lead (II) ions in aqueous media. Au nanoparticle incorporated CuBTC MOF showed great affinity and selectivity toward Pb2+ ions and achieved a lower detection limit (LOD) of 1 nM/L by differential pulse voltammetry (DPV) technique, which is far below than MCL for Pb2+ ions (0.03 µM/L) suggested by the United States (U.S.) Environmental Protection Agency (EPA) drinking water regulations.

Nanocomposite Platform Based on EDTA Modified Ppy/SWNTs for the Sensing of Pb(II) Ions by Electrochemical Method.

Heavy metal ions are considered as one of the major water pollutants, revealing health hazards as well as threat to the ecosystem. Therefore, investigation of most versatile materials for the sensitive and selective detection of heavy metal ions is need of the hour. Proposed work emphasizes the synthesis of conducting polymer and carbon nanotube nanocomposite modified with chelating ligand for the detection of heavy metal ions. Carbon nanotubes are having well known features such as tuneable conductivity, low density, good charge transport ability, and current carrying capacity. Conducting polymers are the most reliable materials for sensing applications due to their environmental stability and tuning of conductivity by doping and de-doping. Formation of nanocomposite of these two idealistic materials is advantageous over the individual material, which can help to tackle the individual limitations of these materials and can form versatile materials with ideal chemical and electrical properties. Chelating ligands are the most favorable materials due to their ability of complex formation with metal ions. The present work possesses a sensing platform based on conducting polymer and carbon nanotube nanocomposite, which is stable in various aqueous media and possess good charge transfer ability. Chelating ligands played an important role in the increased selectivity toward metal ions. Moreover, in present investigation Ethylenediaminetetraacetic acid (EDTA) functionalized polypyrrole (Ppy) and single walled carbon nanotubes (SWNTs) nanocomposite was successfully synthesized by electrochemical method on stainless steel electrode (SSE). The electrochemical detection of Pb(II) ions using EDTA-Ppy/SWNTs nanocomposite was done from aqueous media. Cyclic voltammetry technique was utilized for the electrochemical synthesis of Ppy/SWNTs nanocomposite. Ppy/SWNTs nanocomposite was further modified with EDTA using dip coating technique at room temperature. The EDTA-Ppy/SWNTs modified stainless steel electrode (SSE) exhibited good sensitivity and selectivity toward heavy metal ions [Pb(II)]. Detection limit achieved for Pb(II) ions was 0.07 µM.