Clustering induces switching between phoretic and osmotic propulsion in active colloidal rafts.

Active particles driven by chemical reactions are the subject of intense research to date due to their rich physics, being intrinsically far from equilibrium, and their multiple technological applications. Recent attention in this field is now shifting towards exploring the fascinating dynamics of active and passive mixtures. Here we realize active colloidal rafts, composed of a single catalytic particle encircled by several shells of passive microspheres, and assembled via light-activated chemophoresis. We show that the cluster propulsion mechanism transits from diffusiophoretic to diffusioosmotic as the number of colloidal shells increases. Using the Lorentz reciprocal theorem, we demonstrate that in large clusters self-propulsion emerges by considering the hydrodynamic flow via the diffusioosmotic response of the substrate. The dynamics in our active colloidal rafts are governed by the interplay between phoretic and osmotic effects. Thus, our work highlights their importance in understanding the rich physics of active catalytic systems.

Spontaneous spinning of a dichloromethane drop on an aqueous surfactant solution.

We report a series of experiments carried out with a dichloromethane drop deposited on the surface of an aqueous solution containing a surfactant, cetyltrimethylammonium bromide. After an induction stage during which the drop stays axisymmetric, oscillations occur along the contact line. These oscillations are succeeded by a spectacular spontaneous spinning of the drop. The latter quickly takes the form of a two-tip 'rotor' and the spinning rate stabilizes at a constant value, no longer varying despite the gradual changes of the drop shape and size. The drop eventually disappears due to the continual dissolution and evaporation of dichloromethane. Schlieren visualizations and particle image velocimetry are used to establish a consistent scenario capable of explaining the evolution of the system. The Marangoni effect induced by the dissolution of dichloromethane in the drop vicinity is shown to be responsible for the observed dynamics. Arguments borrowed from dynamical systems theory and from an existing low-order model allow us to explain qualitatively why the system selects the spinning configuration. The geometry of the immersed part of the drop is shown to play a crucial role in this selection process, as well as in the regulation of the spinning rate.

Blowing big bubbles.

Although street artists have the know-how to blow bubbles over one meter in length, the bubble width is typically determined by the size of the hoop, or wand they use. In this article we explore a regime in which, by blowing gently downwards, we generate bubbles with radii up to ten times larger than the wand. We observe the big bubbles at lowest air speeds, analogous to the dripping mode observed in droplet formation. We also explore the impact of the surfactant chosen to stabilize the bubbles. We are able to create bubbles of comparable size using either Fairy liquid, a commercially available detergent often used by street artists, or sodium dodecyl sulfate (SDS) solutions. The bubbles obtained from Fairy liquid detach from the wand and are stable for several seconds, however those from SDS tend to burst just before detachment.

Self-propulsion of symmetric chemically active particles: Point-source model and experiments on camphor disks.

Solid undeformable particles surrounded by a liquid medium or interface may propel themselves by altering their local environment. Such nonmechanical swimming is at work in autophoretic swimmers, whose self-generated field gradient induces a slip velocity on their surface, and in interfacial swimmers, which exploit unbalance in surface tension. In both classes of systems, swimmers with intrinsic asymmetry have received the most attention but self-propulsion is also possible for particles that are perfectly isotropic. The underlying symmetry-breaking instability has been established theoretically for autophoretic systems but has yet to be observed experimentally for solid particles. For interfacial swimmers, several experimental works point to such a mechanism, but its understanding has remained incomplete. The goal of this work is to fill this gap. Building on an earlier proposal, we first develop a point-source model that may be applied generically to interfacial or phoretic swimmers. Using this approximate but unifying picture, we show that they operate in very different regimes and obtain analytical predictions for the propulsion velocity and its dependence on swimmer size and asymmetry. Next, we present experiments on interfacial camphor disks showing that they indeed self-propel in an advection-dominated regime where intrinsic asymmetry is irrelevant and that the swimming velocity increases sublinearly with size. Finally, we discuss the merits and limitations of the point-source model in light of the experiments and point out its broader relevance.