Enabling Circular Economy: The Overlooked Role of Inorganic Materials Chemistry.

Circular economy is considered a new chance to build a more sustainable world from both the social and the economic point of view. In this Essay, the possible contribution of inorganic chemistry towards a smooth transition to circularity in inorganic materials design and production is discussed by adopting an interdisciplinary approach.

Strain Evolution in Cold-Warm Forged Steel Components Studied by Means of EBSD Technique.

Electron BackScatter Diffraction (EBSD) in conjunction with Field-Emission Environmental Scanning Electron Microscopy (FEG-ESEM) has been used to evaluate the microstructural and local plastic strain evolution in different alloys (AISI 1005, AISI 304L and Duplex 2205) deformed by a single-stage cold and warm forging process. The present work is aimed to describe the different behavior of the austenite and ferrite during plastic deformation as a function of different forging temperatures. Several topological EBSD maps have been measured on the deformed and undeformed states. Then, image quality factor, distributions of the grain size and misorientation have been analyzed in detail. In the austenitic stainless steel, the γ-phase has been found to harden more easily, then α-phase and γ-phase in AISI 1005 and in duplex stainless steel, sequentially. Compared to the high fraction of continuous dynamic recrystallized austenitic zones observed in stainless steels samples forged at low temperatures, the austenitic microstructure of samples forged at higher temperatures, 600-700 °C, has been found to be mainly characterized by large and elongated grains with some colonies of fine nearly-equiaxed grains attributed to discontinuous dynamic recrystallization.

Evaluating the Tensile Properties of Aluminum Foundry Alloys through Reference Castings-A Review.

The tensile properties of an alloy can be exploited if detrimental defects and imperfections of the casting are minimized and the microstructural characteristics are optimized through several strategies that involve die design, process management and metal treatments. This paper presents an analysis and comparison of the salient characteristics of the reference dies proposed in the literature, both in the field of pressure and gravity die-casting. The specimens produced with these reference dies, called separately poured specimens, are effective tools for the evaluation and comparison of the tensile and physical behaviors of Al-Si casting alloys. Some of the findings of the present paper have been recently developed in the frame of the European StaCast project whose results are complemented here with some more recent outcomes and a comprehensive analysis and discussion.

Microstructure, texture evolution, mechanical properties and corrosion behavior of ECAP processed ZK60 magnesium alloy for biodegradable applications.

Ultra-fine grained ZK60 Mg alloy was obtained by multi-pass equal-channel angular pressing at different temperatures of 250°C, 200°C and 150°C. Microstructural observations showed a significant grain refinement after ECAP, leading to an equiaxed and ultrafine grain (UFG) structure with average size of 600nm. The original extrusion fiber texture with planes oriented parallel to extrusion direction was gradually undermined during ECAP process and eventually it was substituted by a newly stronger texture component with considerably higher intensity, coinciding with ECAP shear plane. A combination of texture modification and grain refinement in UFG samples led to a marked reduction in mechanical asymmetric behavior compared to the as-received alloy, as well as adequate mechanical properties with about 100% improvement in elongation to failure while keeping relatively high tensile strength. Open circuit potential, potentiodynamic and weight loss measurements in a phosphate buffer solution electrolyte revealed an improved corrosion resistance of UFG alloy compared to the extruded one, stemming from a shift of corrosion regime from localized pitting in the as-received sample to a more uniform corrosion mode with reduced localized attack in ECAP processed alloy. Compression tests on immersed samples showed that the rate of loss of mechanical integrity in the UFG sample was lower than that in the as-received sample.

Numerical analysis of titanium cast devices for dental implantology.

The present work pertains to a numerical investigation of the casting process of titanium devices adopted for dental implantology. The analysis of the titanium framework that connects different abutments, in a multi-implant configuration, is performed evaluating the characteristics of the material that depend on the manufacturing procedure. The connecting bar is obtained by a foundry process that is controlled through a numerical simulation by using a control volume technique. This analysis leads to the possibility to have detailed information on the process and control of the quality of the microstructure of the material produced that proves to be highly beneficial for defining mechanical properties. On the basis of the results obtained, a subsequent stress analysis can be performed, addressed to highlight critical conditions. Functional response of the whole bar-implant framework is studied by means of a numerical model, based on the geometric element method. This technique is particularly suited for describing complex morphology of the implant site. The present approach addresses a higher quality definition of the reliability of the device used in dental practice and represents a valuable tool in assisting optimisation procedures pertaining to manufacturing. In fact, the improvement of titanium devices is intended not only with regard to their mechanical performances, but also to requirements pertaining to manufacturing and clinical practice.