Precipitation effects on parasite, indicator bacteria, and wastewater micropollutant loads from a water resource recovery facility influent and effluent.

The variability of fecal microorganisms and wastewater micropollutants (WWMPs) loads in relation to influent flow rates was evaluated for a water resource recovery facility (WRRF) in support of a vulnerability assessment of a drinking water source. Incomplete treatment and bypass discharges often occur following intense precipitation events that represent conditions that deviate from normal operation. Parasites, fecal indicator bacteria, and WWMPs concentrations and flow rate were measured at the WRRF influent and effluent during dry and wet weather periods. Influent concentrations were measured to characterize potential bypass concentrations that occur during wet weather. Maximum influent Giardia and C. perfringens loads and maximum effluent Escherichia coli and C. perfringens loads were observed during wet weather. Influent median loads of Cryptosporidium and Giardia were 6.8 log oocysts/day and 7.9 log cysts/day per 1,000 people. Effluent median loads were 3.9 log oocysts/day and 6.3 log cysts/day per 1,000 people. High loads of microbial contaminants can occur during WRRF bypasses following wet weather and increase with increasing flow rates; thus, short-term infrequent events such as bypasses should be considered in vulnerability assessments of drinking water sources in addition to the increased effluent loads during normal operation following wet weather.

Temporal variability of parasites, bacterial indicators, and wastewater micropollutants in a water resource recovery facility under various weather conditions.

Wastewater discharges lead to the deterioration of receiving waters through treated effluents and by-passes, combined and sanitary sewer overflows, and cross-connections to storm sewers. The influence of weather conditions on fecal indicator bacteria, pathogens and wastewater micropollutants on raw and treated sewage concentrations has not been extensively characterized. However, such data are needed to understand the effects of by-pass discharges and incomplete treatment on receiving waters. A water resource recovery facility was monitored for pathogenic parasites (Cryptosporidium oocysts, Giardia cysts), fecal indicator bacteria (Escherichia coli, Clostridium perfringens), and wastewater micropollutants (caffeine, carbamazepine, 2-hydroxycarbamazepine, acesulfame, sucralose, and aspartame) during 6 events under different weather conditions (snowmelt and trace to 32 mm 2-day cumulative precipitation). Greater intra- and inter-event variability was observed for Giardia, E. coli and C. perfringens than for studied WWMPs. Even with the addition of inflow and infiltration, daily variations dominated concentration trends. Thus, afternoon and early evening were identified as critical times with regards to high concentrations and flows for potential by-pass discharges. Peak concentrations of Giardia were observed during the June wet weather event (1010 cysts/L), with the highest flowrates relative to the mean monthly flowrate. Overall, Giardia, E. coli and C. perfringens concentrations were positively correlated with flowrate (R > 0.32, p < 0.05). In raw sewage samples collected under high precipitation conditions, caffeine, carbamazepine and its metabolite 2-OH-carbamazepine were significantly correlated (p < 0.05) with Giardia, E. coli, and C. perfringens demonstrating that they are useful markers for untreated sewage discharges. Data from the study are needed for estimating peak concentrations discharged from wastewater sources in relation to precipitation or snowmelt events.

Effect of ozone on biopolymers in biofiltration and ultrafiltration processes.

The focus of this full-scale study was to determine the effect of ozone on biopolymer concentrations in biofiltration and ultrafiltration (UF) processes treating surface water from Lake Ontario. Ozonation was out of service for maintenance for 9 months, hence, it was possible to investigate ozone's action on biologically active carbon contactors (BACCs) and UF, in terms of biopolymer removal. Given the importance of biopolymers for fouling, this fraction was quantified using a chromatographic technique. Ozone pre-treatment was observed to positively impact the active biomass in biofilters. However, since an increase of the active biomass did not result in higher biopolymer removal, active biomass concentration cannot be a surrogate for biofiltration performance. It was evident that increasing empty bed contact time (EBCT) from 4 to 19 min only had a positive effect on biopolymer removal through BACCs when ozone was out of service. However, as a mass balance experiment showed, ozone-free operation resulted in higher deposition of biopolymers on a UF membrane and slight deterioration in its performance.