U.S. plastic waste exports: A state-by-state analysis pre- and post-China import ban.

This study analyzes the regional implications of China's 2017 import ban on plastic waste by examining U.S. census data. A statistically significant decrease in total U.S. plastic waste exports was found, dropping from about 1.4 million tons to 0.6 million tons in the post-ban period. California remained the top exporter, throughout both pre- and post-ban periods, while South Carolina exhibited the highest per capita exports. Malaysia emerged as the largest importer of U.S. plastic waste, followed by Vietnam, Indonesia, and Thailand. The ban also led to a change in the composition of the exported plastic waste. Ethylene polymers increased from 32.6% of total exports in the pre-ban period to 46.9% in the post-ban period. Other plastics (vinyl chloride polymers, styrene polymers, and for plastics not elsewhere specified or included) decreased from 67.4% of total exports in the pre-ban period to 53.1% in the post-ban period. Moreover, we found that exporting plastic waste has significant environmental and human health impacts. For example, the Global Warming Potential (GWP) decreased from 20 million tons CO2-eq in the scenario where 100% of plastics are exported, or 25 million tons exported from the U.S. since 2002, to -11.1 million tons CO2-eq in the scenario where 100% of plastics are treated domestically. Transportation exacerbates these impacts for exported waste scenarios, increasing to 5.4 million tons CO2-eq when plastics are exported by ship while decreasing to 0.9 million tons CO2-eq for domestic treatment. Although exporting plastic waste is initially cost-effective, our study highlights that investing in domestic waste management can yield significant long-term benefits, considering the environmental and public health impacts. Therefore, it is crucial to prioritize context-specific solutions to address the challenges of the evolving global plastic waste landscape.

Stabilization of Waste-to-Energy (WTE) fly ash for disposal in landfills or use as cement substitute.

This study investigated two approaches for managing Waste-to-Energy (WTE) fly ash (FA): (i) phosphoric acid stabilization of FA and disposal in non-hazardous landfills, so that it can pass the U.S. TCLP procedure and meet the U.S. Resource Conservation and Recovery Act (RCRA) standards; (ii) use of FA or phosphoric acid stabilized fly ash (PFA) as cement substitute in construction for avoiding disposal in landfills and reducing the consumption of Portland cement. The effect of stabilization was identified by TCLP tests and XRD quantification (QXRD), which showed that the economically optimal concentration for PFA to pass the RCRA was 1 mol/L H3PO4 (equivalent to 0.4 mol of H3PO4/kg of FA). Zn/Pb-phosphates were formed in treated ash by using high concentration H3PO4 (e.g., 3 mol/L). Thus, the hazardous FA was chemically stabilized to PFA, that were both discussed as cement substitute. QXRD and SEM results showed that both FA and PFA (1 mol/L H3PO4) chemically reacted with cement and water. Up to 25 vol% of the cement can be replaced by FA or PFA, with similar mechanical performance of cement mortars than that of reference. Testing by LEAF Method 1313-pH dependence showed that the FA and PFA cement mortars exhibited the same leachability of heavy metals; therefore, this study demonstrated the technical feasibility of utilizing either raw FA or stabilized PFA as supplementary cementitious material. The leachability of heavy metals in optimal FA or PFA 25 vol% cement mortar was under the U.K. WAC non-hazardous limits.

Materials and energy recovery at six European MBT plants.

Mechanical Biological Treatment (MBT; called "dirty" Materials Recovery Facilities in the U.S.) is a waste management method, developed mostly in Europe, which combines sorting of recyclable materials (metals, paper, plastics, glass) with composting/digestion of green/ food wastes and, in some cases production of a fuel material. In 2018-19, the authors visited six MBT facilities in Europe that use different approaches for the recovery of materials and energy from mixed MSW. These plants were studied with respect to feedstock composition, operating conditions, capital expenditure, financial viability and environmental impacts. The compost product of most facilities examined did not comply with agricultural standards and, therefore, it was classified as compost-like output (CLO) and used as daily cover in landfills. The best composting practice used source separated organic materials (yard and other green wastes) and yielded a marketable compost. MBT plants that did not include the recovery of fuel materials had lower landfill diversion rates and, also, lower capital and operating costs. It was concluded that an MBT plant must include a very efficient sorting and recyclables recovery line and charge a sufficient gate fee. Also, in addition to the recycled products, there should be a stream to recover fuel materials sent to a power plant or cement plant, thus increasing revenue, and landfill diversion, and maximizing greenhouse gas (GHG) savings.

Performance of structural concrete using Waste-to-Energy (WTE) combined ash.

In the U.S., about 27 million metric tons of municipal solid waste are used as fuel in Waste-to-Energy (WTE) power plants, generating about seven million tons of mixed bottom ash and fly ash (combined ash) annually, which are disposed of in landfills after metal separation. This study assessed the effect of using combined ash as a substitute of mined stone aggregates on the mechanical properties and leachability of cement mortar and concrete. The as-received combined ash was separated into three fractions: fine (<2 mm), medium (2-9.5 mm), and coarse (9.5-25 mm). The substitution of up to 100% of stone aggregate by the coarse and medium fractions of combined ash produced concrete with compressive strength exceeding 28 MPa after 28 days of curing. Similar results were obtained when the fine combined ash was used as a sand substitute, at 10 wt%, in mortar. The concrete specimens were subjected to several days of curing and mechanical testing. The results were comparable to the properties of commercial concrete products. The mechanical test results were supplemented by XRD and SEM analysis, and leachability tests by EPA Method 1313 showed that the optimal concrete products effectively immobilized the heavy metals in the combined ash.

The status of waste management and waste to energy for district heating in South Korea.

This paper focuses on waste management and waste to energy (WTE) for district heating in S. Korea. The chemical formula for the materials disposed of in volume base waste fee (VBWF) bags that are processed in WTE plants was calculated as: C6H9.9O2.3, with a heat of formation of 27.6 MJ/kg. The average heating value for the 35 WTE plants was 9.7 MJ/kg, and the average amount of energy recovered was calculated at 1.5 MWh/ton waste processed. 22 of the 35 WTE plants comply with the limits of the R1 formula for energy recovery plants (R1 > 0.61), as introduced by the EU. It was estimated that 8% of the district heating demand is provided by WTE in S. Korea. WTE plants can contribute to about 0.6% to the total electricity demand of S. Korea and aid the efforts of the nation to phase out the dependence on fossil fuels. The average dioxin emissions of all WTE plants were 0.005 ng TEQ/Nm3 (limit:0.1 ng TEQ/Nm3), and most of the other pollutants examined indicated a ten-fold to hundred-fold lower emissions than the national and the EU standards. S. Korea indicated an improved performance in sustainable waste management, with combined recycling/ composting and WTE rates of about 80%, as compared to the average of the EU-28 with 65%, and the US with 36.5%, even if the EU and the US had higher GDP/capita (PPP) than S. Korea.

Major sources of mercury emissions to the atmosphere: The U.S. case.

In 1989, the two major sources of mercury emissions to the atmosphere in the U.S. were coal-fired power plants (80 tons Hg) and waste to energy power plants (82 tons Hg). This paper examines what has happened to these two major sources of mercury emissions since 1989. A comparison within the waste management industry is, also, provided. The 2014 total anthropogenic emissions of mercury in the U.S. were 51.8 t. The results of the analysis of emissions by industrial sector showed that the largest source of anthropogenic mercury were coal-fired power plants. Among industrial processes, the ferrous metals recycling and the cement industries were the largest emitters of mercury. With regard to waste-to-energy power plants, all of which, since the nineties, have installed advanced emission control systems, the results have been very satisfactory: The authors obtained mercury emission data from operators of most of the waste-to-energy (WTE) power plants in the US. The results showed that in 2014 the 77 U.S. WTE plants in total emitted 0.4 tons of mercury, corresponding to 0.77% of the U.S. total. This number was one half of that reported by the National Emissions Inventory (NEI) for "municipal waste combustion'' (0.64 t) due to the fact that the NEI survey included incinerators without energy recovery. A 2002 Earth Engineering Center study had shown that the mercury emissions of the U.S. WTE industry decreased from 81.8 t in 1989 to 2.2 t in 2001. The present study showed that between 2001 and 2014 the U.S. WTE industry mercury emissions were reduced further, by a factor of seven.

Review on fate of chlorine during thermal processing of solid wastes.

Chlorine (Cl) is extensively present in solid wastes, causing significant problems during the thermal conversion of waste to energy or fuels, by combustion, gasification or pyrolysis. This paper introduces the analytical methods for determining the Cl content in solid materials and presents the concentrations of Cl in various types of wastes, as reported in literature. Then, it provides a comprehensive analysis on the Cl emission behavior and Cl species formed during the thermal processing of the inorganic and organic Cl sources. The challenges resulted from the reactions between the formed Cl species and the ferrous metals, the heavy metals and the organic matters are summarized and discussed, e.g., high temperature corrosion, heavy metal evaporation and dioxin formation. The quality degradation of products (oil, char and syngas) by Cl is analyzed. Finally, the available controlling methods of Cl emission, including pre-treatment (water washing, sorting, microwave irradiation and stepwise pyrolysis) and in-furnace (absorbents, co-treatment and catalysts) methods are assessed.

Production of pyroxene ceramics from the fine fraction of incinerator bottom ash.

Incinerator bottom ash (IBA) is normally processed to extract metals and the coarse mineral fraction is used as secondary aggregate. This leaves significant quantities of fine material, typically less than 4mm, that is problematic as reuse options are limited. This work demonstrates that fine IBA can be mixed with glass and transformed by milling, calcining, pressing and sintering into high density ceramics. The addition of glass aids liquid phase sintering, milling increases sintering reactivity and calcining reduces volatile loss during firing. Calcining also changes the crystalline phases present from quartz (SiO2), calcite (CaCO3), gehlenite (Ca2Al2SiO7) and hematite (Fe2O3) to diopside (CaMgSi2O6), clinoenstatite (MgSiO3) and andradite (Ca3Fe2Si3O12). Calcined powders fired at 1080°C have high green density, low shrinkage (<7%) and produce dense (2.78 g/cm(3)) ceramics that have negligible water absorption. The transformation of the problematic fraction of IBA into a raw material suitable for the manufacture of ceramic tiles for use in urban paving and other applications is demonstrated.