1.
Org Lett
; 3(16): 2571-3, 2001 Aug 09.
Artigo
em Inglês
| MEDLINE
| ID: mdl-11483063
RESUMO
[reaction: see text] A new method for the formation of C-glycosides has been developed employing a cationic rhodium(I)-catalyzed 1,4-addition of arylboronic acids to enones derived from glycals. The reaction is stereoselective for the alpha-anomer and is highly dependent on the nature of the rhodium catalyst.