The occurrence of acidic drugs and caffeine in sewage effluents and receiving waters from three coastal watersheds in Atlantic Canada.

Pharmaceuticals, by design, induce biological responses in animals and humans at very low doses, making their presence in the aquatic environment an issue of concern. Prescription and over-the-counter drugs commonly found in wastewater are discharged on a continuous basis into the waters of two coastal watersheds in Atlantic Canada. Ten acidic drugs and caffeine were observed in the final effluents of sewage treatment facilities in Millcove (Halifax watershed), and Trenton (Pictou watershed), Nova Scotia. Naproxen and ibuprofen, two highly used non-steroidal anti-inflammatory drugs (NSAIDs), and caffeine, were the predominant compounds. Naproxen, ibuprofen, salicylic acid (metabolite of acetylsalicylic acid), diclofenac (NSAID) and gemfibrozil (lipid regulator) were also detected in the low ng/L range in the receiving waters of treated and untreated sewage outflows. Acidic drugs were not detected in the marine waters of the Cocagne watershed located in southeast New Brunswick. This watershed was evaluated for the possibility of contamination of near-shore coastal waters from domestic septic systems in the vicinity of a densely populated cottage area. The observation of traces of caffeine suggests some organic pollution in the area.

Impact of a commercial peat moss operation on water quality and biota in a small tributary of the Richibucto River, Kent County, New Brunswick, Canada.

The St-Charles Plain (Kent County, New Brunswick, Canada) commercial peat moss operation has been ongoing since 1983. To process the peat, a dry extraction method is used that requires extensive drainage of the peat bog. The water is directed toward sedimentation ponds, where it drains into a small brook, which feeds into a river affected by tidal salt water. Water discharge from the bog contains large amounts of peat particles that deposit in the surrounding watershed. As a result, the pH of the freshwater sites that receive the drainage water from the commercial operation, is fairly acidic (pH 3.9-4.7). Water samples from or near the peat moss operation have a higher concentration of total phosphorous and total organic carbon. The peat particles contain relatively high levels of total mercury, as reflected by analysis of peat sediments. However, the water samples contained low levels of dissolved mercury. Indigenous samples of biota-namely, sand shrimps (Crangon septemspinosa) and mummichogs (Fundulus heteroclitus)-did not contain mercury levels higher in the impacted sites than in the reference sites. Introduced blue mussels (Mytilus edulis) did not accumulate significant amounts of mercury during a 62-day exposure in the study area. Overall, the data suggest that although relatively large amounts of mercury-containing peat particles are discharged into the ecosystem, bioaccumulation of mercury in the biota does not occur.