Technogenic magnetic particles in topsoil: Characteristic features for different emission sources.

Variations in mineralogical composition, grain size internal structure and stoichiometry of technogenic magnetic particles (TMPs) deposited in topsoil may provide crucial information necessary to trace main pollution sources and recognize various technological processes. The aim of the study was to characterize, by means of magnetic parameters and Mössbauer spectra, the TMPs from non-ferrous metallurgy, cement, coke, glass production as well as long range transport (LRT) and compare the obtained data with previous results focused on iron mining and metallurgy. This research shows that only certain pollution sources (e.g. mainly iron mining, iron metallurgy, LRT and partly glass production) can be successfully distinguished by the applied parameters. The main features characteristic for TMPs produced by Fe-mining are: high values of concentration-dependent magnetic parameters, low values of coercivity, significant contribution from coarse MD (multi-domain) grains and a relatively high stoichiometry of magnetite. The most discriminative feature for TMPs generated by the glass industry is the abundance of goethite in the topsoil samples, which is confirmed by magnetic and Mössbauer techniques. The TMPs released by the Ni-Cu smelter and the Pb-Zn waste exhibit significant differences in the Mössbauer parameters, indicating different stoichiometry of magnetite for each group. Such variations are due to replacement of Fe by other elements at tetrahedral sites in the case of TMPs released from the Ni-Cu smelter. TMPs characteristic for the LRT emissions contain higher amount of finer fraction of low-stoichiometry magnetite (mostly single-domain SD particles) than those originating from other sources. The TMPs accumulated in the topsoils around the coking plants cannot be clearly discriminated by the applied methodology due to strong influence of the local pollution sources. Magnetic studies of the TMPs generated by cement production are complicated, since their properties mainly depend on individual technology (e.g. additives) used by the local cement plants.

Characteristics of current roadside pollution using test-monitoring plots.

The aim of the study was the qualitative recognition of the existing roadside pollutants deposited in topsoils located close to roads with high traffic volume. So far, the studies have helped to determine the content of pollutants that accumulated over a long period of time. Traditionally, it has been difficult to distinguish between roadside pollution and pollution from other industrial sources. In order to avoid such problems and to accurately recognize present threats originating from road traffic, test-monitoring plots were installed in Poland (Gliwice and Opole), Germany (Tübingen, Ulm and Böblingen), Finland (Helsinki), Tajikistan (Dushanbe) and China (Lanzhou). To install the monitoring plots, the upper 7 cm of topsoil was removed and replaced with boxes filled with clean quartz sand. The sand, with a known chemical composition and neutral magnetic (diamagnetic) properties, was considered as a neutral matrix for the accumulation of traffic pollutants. Within 24 months of exposure, both the magnetic susceptibility values and heavy metal content increased, but with highly diverse differences. The highest values were observed in Germany, Tajikistan and China. Correlation coefficients between the magnetic susceptibility values and investigated elements, as well as PAHs indicate that magnetic susceptibility is a geophysical parameter that can be used, under defined conditions, as an indicator of soil pollution caused by traffic emissions.

Identification of magnetic particulates in road dust accumulated on roadside snow using magnetic, geochemical and micro-morphological analyses.

The aim of this study is to test the applicability of snow surveying in the collection and detailed characterization of vehicle-derived magnetic particles. Road dust extracted from snow, collected near a busy urban highway and a low traffic road in a rural environment (southern Finland), was studied using magnetic, geochemical and micro-morphological analyses. Significant differences in horizontal distribution of mass specific magnetic susceptibility (χ) were noticed for both roads. Multi-domain (MD) magnetite was identified as the primary magnetic mineral. Scanning electron microscope (SEM) analyses of road dust from both roads revealed: (1) angular-shaped particles (diameter∼-300 µm) mostly composed of Fe, Cr and Ni, derived from circulation of motor vehicles and (2) iron-rich spherules (d∼2-70 µm). Tungsten-rich particles (d<2 µm), derived from tyre stud abrasion were also identified. Additionally, a decreasing trend in χ and selected trace elements was observed with increasing distance from the road edge.