Open Quantum Systems' Decay across Time.

The description of an open quantum system's decay almost always requires several approximations so as to remain tractable. In this Letter, we first revisit the meaning, domain, and seeming contradictions of a few of the most widely used of such approximations: (semigroup) Markovianity, linear response theory, Wigner-Weisskopf approximation, and rotating-wave approximation. Second, we derive an effective time-dependent decay theory and corresponding generalized quantum regression relations for an open quantum system linearly coupled to an environment. This theory covers all timescales and subsumes the Markovian and linear-response results as limiting cases. Finally, we apply our theory to the phenomenon of quantum friction.

Orientational Dependence of the van der Waals Interactions for Finite-Sized Particles.

Dispersion forces, especially van der Waals forces as interactions between neutral and polarizable particles act at small distances between two objects. Their theoretical origin lies in the electromagnetic interaction between induced dipole moments caused by the vacuum fluctuations of the ground-state electromagnetic field. The resulting theory well describes the experimental situation in the limit of the point dipole assumption. At smaller distances, where the finite size of the particles has to be taken into account, this description fails and has to be corrected by higher orders of the multipole expansion, such as quadrupole moments and so on. With respect to the complexity of the spatial properties of the particles this task requires a considerable effort. In order to describe the van der Waals interaction between such particles, we apply the established method of a spatially spread out polarizability distribution to approximate the higher orders of the multipole expansion. We thereby construct an effective theory for effects from anisotropy and finite size on the van der Waals potential.

Effective Polarizability Models.

Theories for the effective polarizability of a small particle in a medium are presented using different levels of approximation: we consider the virtual cavity, real cavity, and the hard-sphere models as well as a continuous interpolation of the latter two. We present the respective hard-sphere and cavity radii as obtained from density-functional simulations as well as the resulting effective polarizabilities at discrete Matsubara frequencies. This enables us to account for macroscopic media in van der Waals interactions between molecules in water and their Casimir-Polder interaction with an interface.