An immobilized homogeneous catalyst for efficient and selective hydrogenation of functionalized aldehydes, alkenes, and alkynes

An immobilized cationic rhodium(I) catalyst bearing the diphosphine 1,1'-bis(diisopropylphosphino)ferrocene (DiPFc, 1) allows efficient and chemoselective hydrogenation of a range of functionalized aldehydes, as well as alkenes and alkynes, under mild conditions. This heterogenized catalyst system is convenient to prepare, is stable to air and moisture over extended periods, and is readily recycled.

A catalyst for efficient and highly enantioselective hydrogenation of aromatic, heteroaromatic, and alpha,beta-unsaturated ketones

PhanePhos-ruthenium-diamine complexes catalyze the asymmetric hydrogenation of a wide range of aromatic, heteroaromatic, and alpha, beta-unsaturated ketones with high activity and excellent enantioselectivity.