Detection of molecular oxygen using nanosecond-laser-induced plasma.

Molecular oxygen (O2) concentration is measured by employing nanosecond laser-induced plasmas (ns-LIP) over a broad temperature spectrum ranging from 300 K to 1000 K, in the presence of an additional oxygen-containing molecule, CO2. Typically, emission spectra emanating from ns-LIP are devoid of molecular information, as the ns-LIP causes the dissociation of molecular species within the plasma. However, atomic oxygen absorption lines that momentarily appear at 777 nm in the broadband emission from the early-stage plasma are determined to be highly sensitive to the O2 mole fraction but negligibly affected by the CO2 mole fraction. The atomic O absorbing the plasma emission originates from the O2 adjacent to the plasma: robust UV radiation from the early-stage plasma selectively dissociates adjacent O2, exhibiting a relatively low photodissociation threshold, thus generating the specific meta-stable oxygen capable of absorbing photons at 777 nm. A theoretical model is introduced, explicating the formation of the meta-stable O atom from adjacent O2. To sustain the UV radiation from the plasma under high-temperature and low-density ambient conditions, a preceding breakdown is triggered by a split laser pulse (532 nm). This breakdown acts as a precursor, seeding electrons to intensify the inverse-Bremsstrahlung photon absorption of the subsequent laser pulse (1064 nm). Techniques such as proper orthogonal decomposition (POD) and support vector regression (SVR) are employed to precisely evaluate the O2 mole fraction (<1% uncertainty), by analyzing the short-lived (<10 ns) O2-indicator depicted in the early-stage plasma.

Nanosecond laser pulse modulation using seed electrons from cascade ionization induced by inverse-Bremsstrahlung photon absorption.

Nanosecond (ns) laser pulses are modulated by seeding electrons on the laser beam path. The seed-electrons are from auxiliary ns-laser-induced breakdown (ALIB), and the ALIB is induced by a focused 1064-nm pulse, which is split after the frequency-doubling that generates the 532-nm pulse; therefore, the 532-nm and 1064-nm pulses are synchronized. The slowly converging (focal length = 500 mm) 532-nm pulse is re-directed to transmit through the region in where the ALIB-generated electrons reside. The seed-electrons from the ALIB then absorb the 532-nm photons via the inverse-Bremsstrahlung photon absorption (IBPA) process. The number density of the seed-electrons on the 532-nm beam path (ne,ALIB) is controlled by varying 1) the 532-nm pulse arrival time at the ALIB region (ΔPAT) after the 1064-nm pulse triggers the ALIB and 2) the location of the 532-nm beam relative to the core of the ALIB; the electron number density in ALIB is highly non-uniform and evolves in time. Electron-seeded laser-induced breakdown (ESLIB) occurs when ne,ALIB is sufficiently high. The 532-nm beam convergence (controlled by the focusing lens) is adjusted so that the breakdown does not occur without the electron seeding. The ESLIB immediately stops the transmission of the trailing edge of the laser pulse acting as a fast shutter, and ne,ALIB above a threshold can cut the pulse leading edge to modulate the 532-nm laser pulse.

An experimental/numerical investigation of non-reacting turbulent flow in a piloted premixed Bunsen burner.

ABSTRACT: In this paper, an experimental study of the non-reacting turbulent flow field characteristics of a piloted premixed Bunsen burner designed for operational at elevated pressure conditions is presented. The generated turbulent flow fields were experimentally investigated at atmospheric and elevated pressure by means of high-speed particle image velocimetry (PIV). The in-nozzle flow through the burner was computed using large-eddy simulation (LES), and the turbulent flow field predicted at the burner exit was compared against the experimental results. The findings show that the burner yields a reasonably homogeneous, nearly isotropic turbulence at the nozzle exit with highly reproducible boundary conditions that can be well predicted by numerical simulations. Similar levels of turbulence intensities and turbulent length scales were obtained at varied pressures and bulk velocities with turbulent Reynolds numbers up to 5300. This work demonstrates the burner's potential for the study of premixed flames subject to intermediate and extreme turbulence at the elevated pressure conditions found in gas turbine combustors.

100 kHz krypton planar laser-induced fluorescence imaging.

Krypton planar laser-induced fluorescence (Kr PLIF) was demonstrated at a repetition rate of 100 kHz. To achieve this increased rate, a custom injection-seeded optical parametric oscillator was built to efficiently convert the 355 nm output of a high-energy, high-repetition-rate nanosecond burst-mode laser to 212.56 nm to excite Kr from the ground to the 5p[1/2]0 electronic state. Successful tracking of flow structures and mixture fraction was demonstrated using detection speeds 100 times greater than previously attained with a femtosecond laser source. The increase in repetition rate makes time-resolved Kr PLIF relevant for high-speed flows in particular.

Comparison of femtosecond and nanosecond two-photon-absorption laser-induced fluorescence of krypton.

Two-photon-absorption laser-induced fluorescence of Kr was explored using both nanosecond- and femtosecond-duration laser excitation sources. Fluorescence signals following two-photon excitation at two wavelengths (212.56 nm and 214.77 nm) were compared while varying laser pulse duration, energy, and excitation wavelength as well as pressure and Kr mole fraction in mixtures with nitrogen. Our findings show that stronger fluorescence was observed when the excitation wavelength was tuned to 212.56 nm, regardless of the excitation-pulse duration. Moreover, an approximate 100-fold signal enhancement from nanosecond excitation (∼3 mJ/pulse, 10 ns duration) was observed as compared to femtosecond excitation (∼6 µJ/pulse, 90 fs duration).

Laser pulse width control using inverse-Bremsstrahlung photon absorption.

Nanosecond laser pulses (6 ns FWHM, produced by a Q-switched, frequency-doubled Nd:YAG laser) are chopped using the inverse-Bremsstrahlung (IB) photon absorption process in a cell with variable pressure. The IB process that quickly absorbs the majority of the laser pulse energy is triggered by focusing the pulse in the cell. Prior to the initiation of the IB process, the gaseous medium in the cell is transparent, while it suddenly becomes opaque with the IB process activated; therefore, the pressure cell can be used as a virtual optical shutter. The shutter "closing time" depends strongly on the pressure of the cell and the laser pulse energy and thus can be controlled. Dependence of the "closing time" on these two parameters is experimentally investigated.

20 kHz CH2O and OH PLIF with stereo PIV.

Planar laser-induced fluorescence (PLIF) of hydroxyl (OH) and formaldehyde (CH2O) radicals was performed alongside stereo particle image velocimetry (PIV) at a 20 kHz repetition rate in a highly turbulent Bunsen flame. A dual-pulse burst-mode laser generated envelopes of 532 nm pulse pairs for PIV as well as a pair of 355 nm pulses, the first of which was used for CH2O PLIF. A diode-pumped solid-state Nd:YAG/dye laser system produced the excitation beam for the OH PLIF. The combined diagnostics produced simultaneous, temporally resolved two-dimensional fields of OH and CH2O and two-dimensional, three-component velocity fields, facilitating the observation of the interaction of fluid dynamics with flame fronts and preheat layers. The high-fidelity data acquired surpass the previous state of the art and demonstrate dual-pulse burst-mode laser technology with the ability to provide pulse pairs at both 532 and 355 nm with sufficient energy for scattering and fluorescence measurement at 20 kHz.

Direct comparison of two-dimensional and three-dimensional laser-induced fluorescence measurements on highly turbulent flames.

This Letter reports the first direct comparison between two-dimensional (2D) and three-dimensional (3D) laser-induced fluorescence (LIF) applied to highly turbulent flames, with the goal of experimentally illustrating the capabilities and limitations of volumetric LIF (VLIF). To accomplish these goals, planar LIF (PLIF) and VLIF measurements were simultaneously performed on turbulent flames based on the CH radical. The PLIF measurements imaged a planar cross-section of the target flames across a 2D field-of-view (FOV) of 42 mm×42 mm. The VLIF measurements imaged the same region in the target flame with a 3D FOV of 42 mm×42 mm×5 mm, with 5 mm being the thickness of the measurement volume. The VLIF signals generated in this volume were captured by five intensified cameras from different perspectives, based on which a 3D tomographic reconstruction was performed to obtain the 3D reconstruction of the CH radical (as a marker of the flame front). The PLIF measurements were then compared to a cross-section of the VLIF measurement to demonstrate the feasibility and accuracy of instantaneous 3D imaging of flame topography and flame surface area in highly turbulent flames.

Comparison of 2D and 3D flame topography measured by planar laser-induced fluorescence and tomographic chemiluminescence.

The goal of this work was to contrast and compare the 2D and 3D flame topography of a turbulent flame. The 2D measurements were obtained using CH-based (methylidyne radical-based) planar laser-induced fluorescence (PLIF), and the 3D measurements were obtained through a tomographic chemiluminescence (TC) technique. Both PLIF and TC were performed simultaneously on a turbulent premixed Bunsen flame. The PLIF measurements were then compared to a cross section of the 3D TC measurements, both to provide a validation to the 3D measurements and also to illustrate the differences in flame structures inferred from the 2D and 3D measurements.

Nitric-oxide planar laser-induced fluorescence at 10 kHz in a seeded flow, a plasma discharge, and a flame.

This study demonstrates high-repetition-rate planar laser-induced fluorescence (PLIF) imaging of both cold (~300 K) and hot (~2400 K) nitric oxide (NO) at a framing rate of 10 kHz. The laser system is composed of a frequency-doubled dye laser pumped by the third harmonic of a 10 kHz Nd:YAG laser to generate continuously pulsed laser radiation at 226 nm for excitation of NO. The laser-induced fluorescence signal is detected using a high-frame rate, intensified CMOS camera, yielding a continuous cinematographic propagation of the NO plume where data acquisition duration is limited only by camera memory. The pulse energy of the beam is ~20 µJ with a spectral width ~0.15 cm(-1), though energies as high as 40 µJ were generated. Hot NO is generated by passing air through a DC transient-arc plasma torch that dissociates air. The plasma torch is also used to ignite and sustain a CH(4)/air premixed flame. Cold NO is imaged from a 1% NO flow (buffered by nitrogen). The estimated signal-to-noise ratio (SNR) for the cold seeded flow and air plasma exceeds 50 with expected NO concentrations of 6000-8000 parts per million (ppm, volume basis). Images show distinct, high-contrast boundaries. The plasma-assisted flame images have an SNR of less than 10 for concentrations reaching 1000 ppm. For many combustion applications, the pulse energy is insufficient for PLIF measurements. However, the equipment and strategies herein could be applied to high-frequency line imaging of NO at concentrations of 10-100 ppm. Generation of 226 nm radiation was also performed using sum-frequency mixing of the 532 nm pumped dye laser and 355 nm Nd:YAG third harmonic but was limited in energy to 14 µJ. Frequency tripling a 532 nm pumped dye laser produced 226 nm radiation at energies comparable to the 355 nm pumping scheme.

Collisional quenching of NO A 2Sigma+(v' = 0) between 125 and 294 K.

We report measurements of the temperature-dependent cross sections for the quenching of fluorescence from the A (2)Sigma(+)(v(')=0) state of NO for temperatures between 125 and 294 K. Thermally averaged cross sections were measured for quenching by NO(X (2)Pi), N(2), O(2), and CO in a cryogenically cooled gas flow cell. Picosecond laser-induced fluorescence was time resolved, and the thermally averaged quenching cross sections were determined from the dependence of the fluorescence decay rate on the quencher-gas pressure. These measurements extend to lower temperature the range of previously published results for NO and O(2) and constitute the first reported measurements of the N(2) and CO cross sections for temperatures below 294 K. Between 125 and 294 K, a negative temperature dependence is observed for quenching by NO, O(2), and CO, implicating collision-complex formation in all three cases. Over the same temperature range, a constant, nonzero cross section is measured for quenching by N(2). Updated empirical models for the temperature dependence of the cross sections between 125 and 4500 K are recommended based on weighted least-squares fits to the current low-temperature results and previously published measurements at higher temperature. The results of over 250 measurements presented here indicate that the collisionless lifetime of NO A (2)Sigma(+)(v(')=0) is approximately 192 ns.

Hydroxyl tagging velocimetry in a supersonic flow over a cavity.

Hydroxyl tagging velocimetry (HTV) measurements of velocity were made in a Mach 2 (M 2) flow with a wall cavity. In the HTV method, ArF excimer laser (193 nm) beams pass through a humid gas and dissociate H2O into H + OH to form a tagging grid of OH molecules. In this study, a 7 x 7 grid of hydroxyl (OH) molecules is tracked by planar laser-induced fluorescence. The grid motion over a fixed time delay yields about 50 velocity vectors of the two-dimensional flow in the plane of the laser sheets. Velocity precision is limited by the error in finding the crossing location of the OH lines written by the excimer tag laser. With a signal-to-noise ratio of about 10 for the OH lines, the determination of the crossing location is expected to be accurate within +/- 0.1 pixels. Velocity precision within the freestream, where the turbulence is low, is consistent with this error. Instantaneous, single-shot measurements of two-dimensional flow patterns were made in the nonreacting M 2 flow with a wall cavity under low- and high-pressure conditions. The single-shot profiles were analyzed to yield mean and rms velocity profiles in the M 2 nonreacting flow.

Near-infrared diode laser absorption diagnostic for temperature and water vapor in a scramjet combustor.

Tunable diode laser absorption measurements of gas temperature and water concentration were made at the exit of a model scramjet combustor fueled on JP-7. Multiplexed, fiber-coupled, near-infrared distributed feedback lasers were used to probe three water vapor absorption features in the 1.34-1.47 microm spectral region (2v1 and vl + v3 overtone bands). Ratio thermometry was performed using direct-absorption wavelength scans of isolated features at a 4-kHz repetition rate, as well as 2f wavelength modulation scans at a 2-kHz scan rate. Large signal-to-noise ratios demonstrate the ability of the optimally engineered optical hardware to reject beam steering and vibration noise. Successful measurements were made at full combustion conditions for a variety of fuel/air equivalence ratios and at eight vertical positions in the duct to investigate spatial uniformity. The use of three water vapor absorption features allowed for preliminary estimates of temperature distributions along the line of sight. The improved signal quality afforded by 2f measurements, in the case of weak absorption, demonstrates the utility of a scanned wavelength modulation strategy in such situations.