RESUMO
Multi-ion ionic liquids featuring large numbers of distinct imidazolium cations can be easily and reproducibly prepared in a simple one-pot procedure. The method provides a dramatic improvement in efficiency over the almost universally used approach of mixing pre-existing ILs to make multi-ion systems.
RESUMO
The practical utility of ionic liquids (ILs) makes the absence (heretofore) of reported examples from nature quite puzzling, given the facility with which nature produces many other types of exotic but utilitarian substances. In that vein, we report here the identification and characterization of a naturally occurring protic IL. It can be formed during confrontations between the ants S.â invicta and N.â fulva. After being sprayed with alkaloid-based S.â invicta venom, N.â fulva detoxifies by grooming with its own venom, formic acid. The mixture is a viscous liquid manifestly different from either of the constituents. Further, we find that the change results as a consequence of formic acid protonation of the N centers of the S.â invicta venom alkaloids. The resulting mixed-cation ammonium formate milieu has properties consistent with its classification as a protic IL.
Assuntos
Líquidos Iônicos/metabolismo , Animais , FormigasRESUMO
In a head-to-head study, ILs based upon tetraarylphosphonium cations exhibit superior long-term thermal stability compared to familiar salts based upon imidazolium, quaternary ammonium, or tetraalkylphosphonium cations.