Instantaneous thermometry imaging using two-photon laser-induced fluorescence.

Measuring temperature in complex two-phase flows is crucial for understanding the dynamics of heat and mass transfer. In this Letter, we introduce a novel, to the best of our knowledge, optical approach based on the combination of two-photon laser-induced fluorescence (2p-LIF) imaging and two-color laser-induced fluorescence (2CLIF) for instantaneous temperature mapping of complex liquid media. Using Kiton Red (KR) and Rhodamine 560 (R560), a temperature sensitivity of 1.54%/∘C has been achieved over a range of 17-60°C. The monitoring of two-dimensional transient temperature dynamics in the heating and degassing of water shows the efficiency of the 2p-2CLIF. This new approach contributes to the toolkit of optical temperature measurement techniques, providing a robust solution for studying transient scattering media and high-speed two-phase flows.

Gibbs Adsorption Impact on a Nanodroplet Shape: Modification of Young-Laplace Equation.

We present an efficient technique for the evaluation of the Gibbs adsorption of a liquid on a solid substrate. The behavior of a water nanodroplet on a silicon surface is simulated with molecular dynamics. An external field with varying strength is applied on the system to tune the solid-liquid interfacial contact area. A linear dependence of droplet's volume as a function of the contact area is observed. We introduce a modified Young-Laplace equation to explain the influence of the Gibbs adsorption on the nanodroplet volume contraction. Fitting of the molecular dynamics results with the analytical approach allows us to evaluate the number of atoms per unit area adsorbed on the substrate, which quantifies the Gibbs adsorption. Thus, a threshold of a droplet size is obtained, for which the impact of the adsorption is crucial. For instance, a water droplet with 5 nm radius has 3% of its molecules adsorbed on silicon substrate, while for droplets less than 1 nm this amount is more than 10%. The presented results could be beneficial for the evaluation of the adsorption impact on the physical-chemical properties of nanohybrid systems with large surface-to-volume ration.

Crossover between Rayleigh-Taylor instability and turbulent cascading atomization mechanism in the bag-breakup regime.

The question of whether liquid atomization depends on instability dynamics (through refinements of Rayleigh-Plateau, Rayleigh-Taylor, or Kelvin-Helmholtz mechanisms) or on turbulent cascades, as suggested by Richardson and Kolmogorov, is still open. In this paper, experimental results reveal that both mechanisms are needed to explain the probability density functions (PDFs) of the droplets in a spray obtained from an industrial fan spray nozzle. Instability of Rayleigh-Taylor type controls the size of the largest droplets while the smallest droplets follow a PDF given by a turbulent cascading mechanism characterized by a log-Lévy stable law that has a stability parameter equal to 1.70. This value is very close to the inverse value of the Flory exponent and can be related to a recent model developed by N. Rimbert for intermittency modeling stemming from self-avoiding random vortex stretching.