Investigation of concentric-zonal color effects in polyphase ceramic samples by x-ray fluorescence analysis.

The purpose of this study is to investigate and analyze new concentric-zonal color effects in polyphase ceramic samples, particularly in a ceramic sample obtained from coal ash in the Ekibastuz coal basin. The study aims to explore the nature and characteristics of these color bands through x-ray fluorescence analysis, and provide a qualitative and quantitative analysis of the obtained x-ray fluorescence spectra. This paper presents the results of the study of new volume-surface concentric-zonal color effects in polyphase ceramic samples. Concentric-zonal color bands on the cross-sectional surface of a ceramic cylindrical sample were investigated by using x-ray fluorescence analysis. The experimental work was carried out at the laboratory of the Faculty of Nuclear Sciences and Physical Engineering, Czech Technical University in Prague. A comparative qualitative and quantitative analysis of the obtained x-ray fluorescence spectra was carried out.

COMPARISON OF TWO TYPES EYE LENS DOSEMETERS USED IN INTERVENTIONAL CARDIOLOGY AND RADIOLOGY.

The aim of this contribution is to provide an overview of comparison of two types of eye lens dosemeter systems. The comparison was performed at the Department of Intravenous Cardiology using patient and physician phantoms and supplemented by dose simulation using the Monte Carlo method. The tests were performed in several specific geometries and in addition to eye lens dosemeters the value of a personal dosemeter located at the reference point was also monitored. The value of Hp(3) and Hp(10) was monitored. It is clear from the results that film dosemeters achieve more correct results in most cases. It is probably due to a better correction for the angle of exposure. This assumption must be verified by more detailed measurements in laboratory conditions.

X-ray Fluorescence Analysis of Pigments in Gothic Frescoes, Coats of Arms, and Polychromy on Sculptures on the Triforium in St. Vitus Cathedral on the Territory of the Czech Kingdom in the 14th Century.

Pigments in the paints used for the coats of arms, polychromy on sculptures, and pigments in frescoes characterize not only the epoch but also individual creators or groups of artists involved in their creation. X-ray fluorescence analysis is a non-destructive method suitable for determining the chemical composition of these artifacts. This article covers the results of measurements of selected objects, and compares them with similar objects from the territory of the Czech Kingdom in the 14th century.

X-ray fluorescence in investigations of cultural relics and archaeological finds.

Some characteristic features of X-ray fluorescence (XRF) analysis make it an ideal method for investigations of cultural relics and archaeological finds. It has therefore become a standard method used in archaeometry. Paintings, frescos, manuscripts, pottery, metalwork, glass, and many other objects are analysed with the aim of recognising their materials, production technologies and origin, and for identifying counterfeits. This paper reviews various techniques used in XRF analyses of works of art, summarises the advantages and limitations of the method, and presents some typical examples of its use. The general review is supplemented by some techniques used and some results achieved at CTU-FNSPE in Prague.

Application of X-ray fluorescence in investigations of Bohemian historical manuscripts.

In this work we present the application of X-ray fluorescence analysis (XRFA) in an investigation of the Land Register and the Register of the Court of the Kingdom of Bohemia and the manuscript of the Homiliary of the Opatovice Monastery from the 12th century. Radionuclide sources emitting radiation at an appropriate energy level and an X-ray tube were used to excite the characteristic radiation. A spectrometric Si(Li) detector and a Si-PIN detector with Peltier cooling were used to detect the excited characteristic radiation. Several types of pigments were identified and compositions of inks used within almost 5 centuries in the offices at the Prague Castle were determined.

X-ray fluorescence analyzers for investigating postmediaeval pottery from Southern Moravia.

This paper deals with an investigation of ceramic archaeological finds with the use of in-situ X-ray fluorescence analysis. Firstly, three configurations of X-ray fluorescence analyzers constructed and used at the Czech Technical University in Prague are described and compared for use in a non-destructive survey of siliceous materials. Detection limits, depth of analysis, the relation of the analyzed area, the homogeneity of the samples, and variations in the element concentrations are discussed. Secondly, many shards of postmediaeval pottery from Southern Moravia are analyzed with X-ray fluorescence analysis and some of them also with electron microprobe analysis. Selected results are described.

Recognition of pigment layers in illuminated manuscripts by means of Kalpha/Kbeta and Lalpha/Lbeta ratios of characteristic X-rays.

X-ray fluorescence analysis with an evaluation of the Kalpha/Kbeta or Lalpha/Lbeta count rate ratios enables a layered structure to be recognized, because the measured ratio of two lines of one element depends on the depth distribution of this element in the analyzed objects. Several specimens consisting of layers of various pigments were analyzed to demonstrate the possibilities of the proposed technique. Then the Lalpha/Lbeta technique was applied in an investigation of cinnabar distribution in mediaeval manuscripts.

Radiation sources in the environment near NPP Temelin.

A widely discussed question is how much a nuclear power plant really contributes to irradiation of the people living in its vicinity. A number of laboratory and in situ measurements were performed in the area surrounding NPP Temelin, on the basis of which we can specify the irradiation of this area from various sources. The evaluation includes the contributions from natural sources, such as radon, terrestrial radiation and cosmic radiation, together with the contribution from inhalation and ingestion of radionuclides. Medical irradiation and nuclear fallout are also included.

K(alpha)/K(beta) ratios of fluorescence X-rays as an information source on the depth distribution of iron in a low Z matrix.

This paper describes how the K(alpha)/K(beta) count rate ratio of the characteristic X-rays of a given element can be applied to determine the depth at which a layer or a grain of that element is located. The theoretical background and a basic description of the K(alpha)/K(beta) technique are given in the introduction. The experimental part of the paper deals with measurements of thick standard pure iron, intermediately thick iron foils, and layers prepared with a powder of Prussian blue. All these specimens were analyzed alone, and they were also analyzed overlaid with a low Z matrix. The light matrix consisted of sheets of paper of known thickness. Paper was chosen, because we take into account the subsequent application of this technique to surveys of historical monuments. The relation between the K(alpha) count rate, the K(alpha)/K(beta) count rate ratio, and the distribution of iron in the paper matrix are presented here.

Application of the advanced radon diagnosis methods in the indoor building environment.

The health risk and dose calculations from exposure to indoor radon and its decay products are generally based on long-term integral measurements and standard ICRP recommendations. In this context, the results of assessments predicate more about human activities inside the building instead of a quality and an effectiveness of applied measures against the radon. The present paper is focused on a set of different measuring techniques and methods practically used for a classification of buildings regarding to the radon protection requirements. The fundamental quantitative and qualitative procedures of radon transport pathways and radon sources analysis, commonly named as radon diagnostic methods are performed in detail.

Investigation and remediation of houses affected by radon phenomena connected with earlier exploration of silver and uranium ore.

The sources of gamma radiation inside buildings affected by earlier silver and uranium mining activities are discussed. Possibilities how to reduce gamma dose rates from building materials were studied on several houses located in the old mining town Jáchymov. Results of the efficiency analysis are presented. Experience obtained up to now indicates that it is almost impossible to reduce the gamma dose rates in such buildings to the level corresponding with the natural background, because some of the gamma radiation sources cannot be completely removed from the building structures.

Monitoring DNA damage in wood small-reed (Calamagrostis epigejos) plants growing in a sediment reservoir with substrates from uranium mining.

For most plant species growing in polluted areas genotoxicity assays are not available. We have studied the possibility of using the alkaline protocol of the Comet assay as a method for detecting induced DNA damage in a grass Calamagrostis epigejos, growing wild in highly polluted areas. To calibrate the Comet assay for C. epigejos, two model mutagens were applied: the monofunctional alkylating agent ethyl methanesulfonate (EMS) and gamma-rays. With increasing concentrations of EMS (0 to 10 mM, 18 h treatment at 26 degrees C) applied on excised leaves, the DNA damage, as expressed by the tail moment (TM) values, increased from 4.7 +/- 0.9 to 60.8 +/- 2.7 microns. After gamma irradiation (0 to 30 Gy) the TM value increased from 4.2 +/- 0.2 to 48.1 +/- 1.7 microns. A 24 to 72 h recovery of leaves after EMS treatment in an EMS-free medium did not result in a significant change in the induced EMS damage. By contrast, a 24 h recovery after gamma-irradiation led to a complete repair of DNA damage measurable by the Comet assay. We have measured the DNA damage in nuclei of leaves of C. epigejos plants growing in the area of a sediment reservoir with substrates from uranium mining, where the ore was exploited through leaching with sulfuric acid. The average specific activity of natural radionuclides measured in the substrate was for 226Ra = 11,818 Bq kg-1, for 232Th = 66 Bq kg-1 and for 40K = 75 Bq kg-1. No significant increase in the DNA damage in plants growing on the sediment substrate above the DNA damage in control plants was detected by the Comet assay.

Quality control of the stereotactic radiosurgery procedure with the polymer-gel dosimetry.

PURPOSE: To assess the entire geometric and dosimetric (relative) uncertainties of the radiosurgery procedure with the Leksell gamma knife. MATERIALS AND METHODS: The entire Leksell gamma knife stereotactic radiosurgery treatment procedure was simulated with the use of a special water filled head phantom and polymer-gel dosimeter evaluated by nuclear magnetic resonance (NMR). A test vessel filled with the polymer-gel dosimeter was fixed in the head phantom. The phantom underwent stereotactic NMR imaging, treatment planning and then irradiation according to the treatment plan prepared exactly the same way as in the ordinary treatment procedure for a patient. The treatment plan was represented by one isocenter positioned approximately centrally in the head phantom. This procedure was subsequently repeated for all four collimators (4, 8, 14, 18mm) used on the Leksell gamma knife. Evaluation of dosimeters was performed on a Siemens EXPERT 1T NMR scanner. Dose profiles in X, Y and Z axes through the ellipsoidal shaped dose distribution were obtained to compare experimental results from the irradiated phantom with the treatment planning system calculations. RESULTS: Reasonable agreement was observed between the treatment planning system calculations of relative dose distribution and the measured data. The maximum observed deviation in the spatial position between the center of the measured and calculated dose profiles was 0.6mm. The maximum observed difference in full width of half maximum between calculated and measured profiles was 1.2mm. CONCLUSIONS: The use of polymer-gel dosimetry for a verification of stereotactic procedures has some unique advantages that can be summarized as follows: the dosimeter itself is tissue equivalent, three-dimensional dose distributions can be measured and the dosimeter allows simulation of the patient's procedures without any limitations.

Evaluation of geometric and dosimetric inaccuracies of stereotactic irradiation in the rat brain.

OBJECTIVE: To evaluate geometric and dosimetric inaccuracies in the irradiation of the rat brain with the Leksell Gamma Knife. MATERIALS AND METHODS: Altogether three types of dosimeters were employed for these measurements: (a) a thermoluminescent dosimeter, (b) a semiconductor detector and (c) a polymer gel dosimeter. The thermoluminescent dosimeter and the semiconductor detector were calibrated using an ion chamber and then implanted in the brain of a rat cadaver and used for absolute dose determination. A special glass phantom mimicking exactly the shape of the rat body filled with the polymer gel was used for measurements of the relative dose distribution and evaluation of geometric inaccuracies during the stereotactic irradiation in the rat brain. RESULTS: Both thermoluminescent and semiconductor detectors, due to their size, measured mean doses. The observed results demonstrated that the Leksell GammaPlan can be employed for the calculation of absorbed doses in irradiation of experimental animals. In our case, it was necessary to apply a correction factor of 1.078 for the absolute absorbed dose to obtain reliable results. A comparison of calculated dose profiles using the treatment planning system in all three axes with those measured by the polymer gel dosimeter demonstrated a very good geometric agreement with the mean deviation in profile position of 0.5 mm. CONCLUSION: The results indicate that this technique can effectively check the geometric and dosimetric accuracy of stereotactic irradiation in the rat brain. The Leksell GammaPlan can be employed for the calculation of absorbed doses, but the correction factor of 1.078 had to be applied for the absolute dose calculations in our irradiation geometry.

Application of polymer gel dosimetry in gamma knife radiosurgery.

OBJECT: The purpose of this study was to investigate the use of a polymer gel-based dosimeter for the evaluation of geometric and dosimetric inaccuracies during gamma knife radiosurgery and during the irradiation of an experimental animal. METHODS: A polymer gel dosimeter, based on acrylic monomers, was used for experiments conducted in this study. The accuracy of the dosimeter was evaluated on a Siemens EXPERT 1-tesla scanner in the transmitter/receiver head coil with the use of a multiecho sequence with 16 echoes, TE 22.5 to 360 msec, TR 2000 msec, slice thickness 2 mm, field of view 255 mm, and a pixel size of 0.5 x 0.5 mm2. Two experiments were conducted. First, the head phantom containing the polymer gel dosimeter was irradiated using 4-, 8-, 14-, and 18-mm isocenters. Second, a specially designed rat phantom was irradiated by four 4-mm isocenters. The dose profiles in the x, y, and z axes were calculated in the treatment planning system and measured with the polymer gel dosimeter and the results were compared. There was good agreement between the measured and calculated dose profiles. The maximum deviation in the spatial position of the center of measured and calculated dose profiles was 0.5 mm in the head phantom and 1 mm in the rat phantom. The maximum deviation in the width of the selected reference isodose of measured profiles was 1.2 mm in the head phantom and 1.1 mm in the rat phantom. CONCLUSIONS: The use of the polymer gel-based dosimeter for the verification of stereotactic procedures has advantages compared with other dosimetric systems. The dosimeter itself is tissue equivalent. Three-dimensional dose distributions can be measured and the dosimeter allows simulation of the therapeutic procedures.