1.
Dalton Trans
; 40(7): 1567-75, 2011 Feb 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21225078
RESUMO
First Suzuki-Miyaura coupling reactions applied to (η(5)-chloro-cyclohexadienyl)Mn(CO)3 complexes are described and lead to the syntheses of (η(5)-aryl-cyclohexadienyl)Mn(CO)3 and of cationic (η(6)-arene)Mn(CO)3 complexes after rearomatization. The structures of two of the new complexes have been investigated by X-ray diffraction study.
Assuntos
Compostos Organometálicos/síntese química , Cristalografia por Raios X , Modelos Moleculares , Estrutura Molecular , Compostos Organometálicos/química , Estereoisomerismo
2.
Dalton Trans
; (1): 27-9, 2009 Jan 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-19081966
RESUMO
The synthesis of (eta5-cyclohexadienyl)Mn(CO)3-based planar chiral ligands is realized by an efficient lithiation/electrophilic quench procedure, and the coordinating properties of one of them are highlighted together with its optical resolution.