RESUMO
The title compound, tetrakis(mu-3,4,5-triethoxybenzoato-kappa(2)O:O')bis[(pyrazine-kappa N)rhodium(II)](Rh[bond]Rh), [Rh(2)(C(13)H(17)O(5))(4)(C(4)H(4)N(2))(2)], crystallizes on an inversion centre in the triclinic space group P1. The equatorial carboxylate ligands bridge the two Rh(II) atoms, giving a binuclear lantern-like structure. The pyrazine molecules occupy the two axial coordination sites. The phenyl rings are tilted by ca 10 degrees with respect to the attached carboxylate groups. The pyrazine planes have a torsion angle of ca 19 degrees around the Rh-N bond with respect to the plane of the nearer carboxylate group and are not coplanar with the Rh[bond]Rh bond.
RESUMO
The octahedral title compound, [Ru(C(2)H(5)O)(NO)(NO(2))(2)(C(6)H(16)N(2))], crystallizes in the rhombohedral space group P3(1) with an ethoxy ligand axially coordinated trans to the nitrosyl ligand. The RuII ion is equatorially coordinated by a tetramethylethylenediamine group acting as a bidentate ligand, and to two nitro moieties whose planes are tilted with respect to the mean equatorial plane. Each nitrogen ligand bonded to the metallic centre has a different hybridization state.
RESUMO
The title compound, catena-poly[[tetrakis(mu-decanoato-kappa(2)O:O')diruthenium(II,III)(Ru-Ru)]-mu-octanesulfonato-kappa(2)O:O'], [Ru(2)(C(10)H(19)O(2))(4)(C(8)H(17)O(3)S)], is an octanesulfonate derivative of the mixed-valence complex diruthenium tetradecanoate. The equatorial carboxylate ligands are bidentate, bridging two Ru atoms to form a dinuclear structure. Each of the two independent dinuclear metal complexes in the asymmetric unit is located at an inversion centre. The octanesulfonate anion bridges the two dinuclear units through axial coordination. The alkyl chains of the carboxylate and sulfonate ligands are arranged in a parallel manner. The global structure can be seen as infinite chains of polar moieties separated by a double layer of non-polar alkyl groups, without interdigitation of the alkyl chains.
