Self-supply groundwater in five communities: Moshie Zongo, Aboabo, Kotei, Ayeduase and Apemso in Kumasi Metropolis, Ghana.

Self-supply water has been acknowledged as a viable alternative to meeting the water needs of inhabitants. This study was designed to determine the main issues that influence self-supply water coverage in five (5) communities in the Kumasi Metropolis. The research employed a well-structured questionnaires and a total of 369 households were surveyed. The Statistical Package for Social Sciences (SPSS) version 26 and Microsoft Excel (2016) tools were used to analyse the data. The outcomes of the research show that a greater number of the respondents (77 %) did not have connections to the Ghana Water Company Limited (GWCL) distribution system. Approximately, 69 % of respondents had access to alternative water sources with mechanized boreholes forming the majority (32 %). However, a greater number of the respondents (64 %) did not disinfect their water to make it potable. The most favourable drinking water source for a greater number of the residents (51 %) was sachet water. The study showed there was a significant association between respondents' type or source of water with religion (p < 0.000), household size (p < 0.000), duration of stay (p = 0.026) and number of dependents (p = 0.006). However, there was no association between type or source of water with educational level (p = 0.130), occupation (p = 0.310), income level (p = 0.139) and type of home (p = 0.102). This study revealed that self-supply is contributing to the water needs of some residents in Kumasi and could contribute to the country's accomplishment of SDG 6.1 if residents ensure that it is safely managed. To broaden the scope of the study and the impact of self-supply groundwater, additional studies should be conducted in other communities, as well as the extent of other beneficiaries who have access to self-supply facilities other than the owners.

Mechanistic insights into contaminant transport dynamics in the saturated porous system in the presence of low permeability region using numerical simulations and temporal moment analysis.

The influence of low permeability porous media (LPPM) on contaminant transport dynamics in saturated porous systems was investigated using numerical simulations and temporal moments of contaminant concentrations. Two-dimensional flow and contaminant transport simulations were conducted, considering various parameters such as longitudinal dispersivity (ranging from 15 to 60 m), the ratio of transverse to longitudinal dispersivity (ranging from 0.05 to 0.2), retardation factor (ranging from 1 to 4), and hydraulic gradient (ranging from 0.005 to 0.02) for both homogeneous and heterogeneous porous systems. The findings revealed significant differences in the transport behavior of conservative and highly reactive contaminants between the porous systems without and with the LPPM region. The center of mass of contaminant plume and peak concentration zone were observed inside the LPPM region for the heterogeneous porous system, especially during the source off-loading period. Furthermore, asymmetric distributions of the zeroth temporal moment (ZTM), mean residence time (MRT), and variance of the breakthrough curve (BTC) were observed along the longitudinal distance within the LPPM region for heterogeneous porous system, highlighting the impact of heterogeneity on contaminant plume evolution dynamics. The moment analysis results provided insights into the influence of LPPM region on time-averaged contaminant transport dynamics in adjacent porous systems. These findings can help risk managers understand the complex fate and transport dynamics in heterogeneous porous systems. Future studies could explore the modelling of multispecies contaminants in heterogeneous saturated porous systems subjected to fluctuating water table.

Assessment of in situ stabilization and heavy metal toxicity reduction of sugar mill pressmud through pilot scale composting.

Owing to a huge amount of industrial organic waste generation in the recent past, concerned industries are facing immense challenges for in situ treatment and disposal of such wastes. Therefore, in this study, the efficacy assessment of in situ windrow composting of pressmud (PM) produced by sugar industry has been investigated. Samples were grabbed and mixed from windrows having composting days of 15 (PM15), 30 (PM30), and 45 (PM45) and were collected along with a compost sample from the 60th day (PMC) windrow. An investigation of physico-chemical parameters including pH, electrical conductivity, moisture content, volatile solids (VS), ash content, biochemical oxygen demand, chemical oxygen demand, total nitrogen, and C/N ratio was performed for raw PM and other aforementioned samples. Moreover, speciation of heavy metals (Cu, Cr, Ni, Pb, Cd, and Zn), X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopic analyses were performed for PM and PMC to evaluate the heavy metal toxicity and mineralogical and chemical changes. The analysis showed 20.33% reduction in VS content and 53.65% increase in TN content after 60 days of in situ windrow composting. The pH and EC values of PMC were found to be lesser than that of upper values recommended for agricultural purposes. Furthermore, the speciation analysis showed significant reduction in bioavailability of heavy metals. The XRD and FTIR results were confirmatory for transformation of heavy metals into relatively stable forms. The study recommends the windrow composting practice as effective bioconversion technique that stabilizes organic content, enhances humification, and diminishes heavy metal bioavailability for PM and similar other sludges.

Advancements in the dominion of fate and transport of pharmaceuticals and personal care products in the environment-a bibliometric study.

The study on the fate and transport of Pharmaceuticals and Personal Care Products, PPCPs (FTP) in the environment, has received particular attention for over two decades. The PPCPs threaten ecology and human health even at low concentrations due to their synergistic effects and long-range transport. The research aims to provide an inclusive map of the scientific background of FTP research over the last 25 years, from 1996 to 2020, to identify the main characteristics, evolution, salient research themes, trends, and research hotspots in the field of interest. Bibliometric networks were synthesized and analyzed for 577 journal articles extracted from the Scopus database. Consequently, seven major themes of FTP research were identified as follows: (i) PPCPs category; (ii) hazardous effects; (iii) occurrence of PPCPs; (iv) PPCPs in organisms; (v) remediation; (vi) FTP-governing processes; and (vii) assessment in the environment. The themes gave an in-depth picture of the sources of PPCPs and their transport and fate processes in the environment, which originated from sewage treatment plants and transported further to sediment/soils/groundwater/oceans that act as the PPCPs' major sink. The article provided a rigorous analysis of the research landscape in the FTP study conducted during the specified years. The prominent research themes, content analysis, and research hotspots identified in the study may serve as the basis of real-time guidance to lead future research areas and a prior review for policymakers and practitioners.

Mutual information based weighted variance approach for uncertainty quantification of climate projections.

Future climate projections are a vital source of information that aid in deriving effective mitigation and adaptation measures. Due to the inherent uncertainty in these climate projections, quantification of uncertainty is essential for increasing its credibility in policymaking. While quantifying the uncertainty, often the possible dependency between the General Circulation Models (GCMs) due to their shared common model code, literature, ideas of representation processes, parameterization schemes, evaluation datasets etc., are ignored. As this will lead to wrong conclusions, the inter-model dependency and the respective independence weights need to be considered, for a realistic quantification of uncertainty. Here, we present the detailed step-wise methodology of a "mutual information based independence weight" framework, that accounts for the linear and nonlinear dependence between GCMs and the equitability property.•A brief illustration of the utility of this method is provided by applying it to the multi-model ensemble of 20 GCMs.•The weighted variance approach seemingly reduces the uncertainty about one GCM given the knowledge of another.

A bibliometric and visual analysis of contaminant transport modeling in the groundwater system: current trends, hotspots, and future directions.

Contaminant transport modeling (CTM) in the groundwater represents the complex bio-geo-chemical processes in the subsurface system and plays a vital role in designing remediation strategies for contaminated sites. Hence, this study evaluated 1955 articles on CTM-based studies published from 2010 to 2022 by utilizing the Scopus® database to provide a quantitative analysis of current trends and future directions. A systematic approach comprised of a bibliometric survey and visualization of various networks was conducted with the VOSviewer and Biblioshiny software for quantitative analysis of progress of CTM research field over the past decade. The hotspots and evolution of themes of CTM were found using Sankey diagrams, and thematic maps. It was observed that articles were published at an exponential rate over past 5 years. The analysis of Scopus® database revealed that the average citations per article and the average citations per year per article were 14.7 and 2.225. In the past decade, USA published 489 articles and emerged as the leading country based on mutual collaborations and cooperation with other top 9 most productive countries. Flinders University was ranked in the first position based on the number of articles, followed by Pacific Northwest National Laboratory. The findings obtained from this study can help researchers identify exploitation and core areas, to understand better the direction of research of mathematical model development, and to determine hotspots of CTM research field.

Performance of field-scale permeable reactive barriers: An overview on potentials and possible implications for in-situ groundwater remediation applications.

Permeable reactive barriers (PRBs) are significant among all the promising remediation technologies for treating contaminated groundwater. Since the first commercial full field-scale PRB emplacement in Sunnyvale, California, in 1994-1995, >200 PRB systems have been installed worldwide. The main working principle of a PRB is to treat a variety of contaminants downstream from the contaminated source zone ("hot spot"). However, to accurately assess the longevity of PRBs, it is essential to know the total contaminant mass in the source area and its approximate geometry. PRBs are regarded as both a safeguarding and an advanced decontamination technique, depending on the contamination scenario and its outcome during the operational lifetime of the barrier. In the last three decades, many PRBs have performed very well, that is, met expected clean-up goals at a variety of contaminated sites. However, there is still the necessity of thoroughly evaluating the implications of the performance of different PRB designs and reactive or adsorptive materials worldwide. Therefore, this study presents a comprehensive overview of field-scale PRBs applications and their long-term performance after on-site emplacements. This paper provides in-depth insight into this passive in-situ remediation technology for treating and even eliminating a contaminated plume over a long time in the subsurface. The overview will help all stakeholders worldwide understand the implications of PRBs and guide them to take all the required measures before its on-site application to avoid any potential failure.

Application of temporal moment analysis to interpret colloid and colloid-facilitated solute transport under varying size exclusion and attachment coefficient.

Colloidal particles can attach the contaminants like heavy metals and radionuclides and act as contaminant carriers to provide a faster movement of pollutants through the interconnecting pores of the porous medium. The electrostatic repulsive force between the negatively charged colloids and the solid surface restricts the transport of the mobile colloids to the larger pores of the porous medium and initiates the size exclusion mechanism. The temporal moment analysis is treated as an effective tool to interpret the solute breakthrough curves for analyzing the statistical behavior of the contaminants. In past literature, the temporal moments have not been incorporated with the breakthrough curves of colloids and colloid-facilitated contaminants for statistical interpretation. In this research study, the temporal variations of concentrations of mobile colloids, solute attached to the mobile colloids, and the dissolved solute are obtained numerically in a fully saturated one-dimensional column considering a continuous source for varying size exclusion and colloid attachment coefficient. Utilizing the simulated spatially varying breakthrough curves, the temporal moments are estimated to calculate the mass recovery, average residence time, and the spreading of mobile colloids and dissolved solutes. The temporal moment analysis suggests that the velocity enhancement for higher size exclusion reduces the average residence time of the mobile colloids and the solute adsorbed to the mobile colloids significantly. The mass recovery of mobile colloids and the solute attached to the mobile colloids increases at a specific depth for higher size exclusion. The estimated second central moment attributes that the solute spreading follows the nonlinear trend for low size exclusion. The peaks of the relative concentration of mobile colloids and solute attached to mobile colloids drastically decrease with an increase in attachment coefficient. The peak of the relative concentration of dissolved contaminant enhances with attachment coefficient. The high second temporal moment of the dissolved contaminant at a higher attachment coefficient indicates the slow interaction of dissolved solute and porous medium and that enables a greater spreading of solute through the interconnecting porous medium. The study suggests that the faster movement of mobile colloids and the solute attached to the mobile colloids at higher exclusion imparts a potential risk of groundwater contamination and thorough statistical interpretation is needful to analyze the behavior of colloids and colloid-facilitated contaminants. The research work does not consider the transient flow field and the effect of the presence of air phase in the partially saturated soil column in the groundwater system.

Dry tomb - bioreactor landfilling approach for enhanced biodegradation and biomethane generation from municipal solid waste Co-disposed with sugar mill pressmud.

In this study, anaerobic co-landfilling of municipal solid waste (MSW) and sugar mill pressmud (PM) was performed in four different proportions [PM:MSW] viz. 0:1 (control: BR1), 1:3 (BR2), 1:1 (BR3) and 3:1 (BR4). Efficacy assessment of Dry tomb - Bioreactor landfill (DTLF - BRLF) operation was carried out through leachate characterization and biomethane production. Leachate recirculation as a part of bioreactor operation after 194th day onwards showed promising degradation of co-wastes. Moreover, leachate decontamination and methane production were reliant on co-disposal proportions of PM and MSW. Maximum biomethane generation of 46.355L was obtained in landfill lysimeter BR3 followed by BR4 (34.680L), BR2 (24.275L) and BR1 (12.850L). Both logistic function and Gompertz growth models showed efficient fitting (R2 > 0.99) for observed methane production. This research could be a baseline study for selective operation of combined dry tomb and bioreactor landfilling at full scale in co-disposal scenarios.

An integrated permeable reactive barrier and photobioreactor approach for simultaneous removal of nitrate, phosphate and hexavalent chromium: A combined batch and continuous flow study.

In this study, simultaneous removal of nitrate (NO3-), phosphate (PO43-) and hexavalent chromium (Cr(VI)) from wastewater was investigated using a novel integrated filtration unit consisting of adsorbent based permeable reactive barrier (AB-PRB) and biosorption based photobioreactor (BSB-PBR). AB-PRB was comprising a mixture of low-cost adsorbents in an optimum proportion, whereas BSB-PBR carried C. vulgaris microalgae cultivated in controlled environment. The batch analysis for AB-PRB showed maximum removal efficiency of 95.7% and 98.0% for NO3- and PO43-, at pH-6, whereas 84.0% for Cr(VI) at pH-4. However, continuous flow study showed decreasing trend in removal efficiency of NO3-, PO43- and Cr(VI) with increasing flow rate from 10 ml min-1 to 30 ml min-1. Further, in BSB-PBR, maximum removal of 98.2% was achieved for Cr(VI) of 1.0 mg L-1 initial concentration at 3.3 days of hydraulic retention time (HRT). This study provides a novel integrated remediation approach for efficient removal of unlike contaminants.

Investigating leachate decontamination and biomethane augmentation through Co-disposal of paper mill sludge with municipal solid waste in simulated anaerobic landfill bioreactors.

The study aims to investigate the feasibility of anaerobic co-landfilling of effluent treatment plant sludge (ETPS) from paper mill and municipal solid waste (MSW) in prismoidal shaped simulated anaerobic landfill bioreactors. Both ETPS and MSW were co-disposed in 0:100 (R1), 25:75 (R2), 50:50 (R3) and 75:25 (R4) ratios. Periodic assessments of leachate characteristics and biomethane production were carried out for 300 days. ETPS co-disposal with MSW showed considerable reduction in biochemical oxygen demand of leachate (R2: 95.9%, R3: 97.5% and R4: 93.2%). Moreover, cumulative methane gas generations were 2.974, 6.085 and 4.653 times more in R2, R3 and R4 bioreactors as compared to R1. Gompertz growth model was found in well-fitting for methane generation with the observed data. Correlogram plotted among leachate parameters exhibited exclusive relationships and justified leachate trends. This simulation of co-landfilling could be baseline study for the implementation of technology at pilot scale.

Fate and contaminant transport model-driven probabilistic human health risk assessment of DNAPL-contaminated site.

In this study, fate and contaminant transport model-driven human health risk indexes were calculated due to the presence of dense non-aqueous phase liquids (DNAPLs) in the subsurface environment of air force base area in Florida, USA. Source concentration data of DNAPLs was used for the calculation of transport model-driven health risk indexes for the children and adult sub-population via direct oral ingestion and skin dermal contact exposure scenario using 10,000 Monte Carlo type simulations. The highest variation in the probability distribution of transformed DNAPL compound (cis-dichloroethene (cis-DCE) > vinyl chloride (VC)) was observed as compared to parent DNAPL (tetrachloroethene (PCE)) based on the 50-year simulation timespan. Transformed DNAPL compounds (VC, cis-DCE) posed the highest risk to human health for a longer duration (up to 15 years) in comparison to parent DNAPL (PCE), as non-carcinogenic hazard quotient varied from 400 to 1100. Carcinogenic health risks were observed as 3-order of magnitude higher than safe limit (HQSafe < 10-6) from 2nd to 5th year timespan and fall in the high-risk zone, indicating the need for a remediation plan for a contaminated site. Variance attribution analysis revealed that concentration, body weight, and exposure duration (contribution percentage - 70 to 95%) were the most important parameters, highlighting the impact of dispersivity and exposure model in the estimation of risk indexes. This approach can help decision-makers when a contaminated site with partial data on hydrogeological properties and with higher uncertainty in model parameters is to be assessed for the formulation of remediation measures.

Modelling gas generation for landfill.

A methodology was developed to predict the optimum long-term spatial and temporal generation of landfill gases such as methane, carbon dioxide, ammonia, and hydrogen sulphide on post-closure landfill. The model incorporated the chemical and the biochemical processes responsible for the degradation of the municipal solid waste. The developed model also takes into account the effects of heterogeneity with different layers as observed at the site of landfills' morphology. The important parameters for gas generation due to biodegradation such as temperature, pH, and moisture content were incorporated. The maximum and the minimum generations of methane and hydrogen sulphide were observed. The rate of gas generation was found almost same throughout the depth after 30 years of landfill closure. The proposed model would be very useful for landfill engineering in the mining landfill gas and proper design for landfill gas management systems.