Modeling Leidenfrost Levitation of Soft Elastic Solids.

The elastic Leidenfrost effect occurs when a vaporizable soft solid is lowered onto a hot surface. Evaporative flow couples to elastic deformation, giving spontaneous bouncing or steady-state floating. The effect embodies an unexplored interplay between thermodynamics, elasticity, and lubrication: despite being observed, its basic theoretical description remains a challenge. Here, we provide a theory of elastic Leidenfrost floating. As weight increases, a rigid solid sits closer to the hot surface. By contrast, we discover an elasticity-dominated regime where the heavier the solid, the higher it floats. This geometry-governed behavior is reminiscent of the dynamics of large liquid Leidenfrost drops. We show that this elastic regime is characterized by Hertzian behavior of the solid's underbelly and derive how the float height scales with materials parameters. Introducing a dimensionless elastic Leidenfrost number, we capture the crossover between rigid and Hertzian behavior. Our results provide theoretical underpinning for recent experiments, and point to the design of novel soft machines.

Engineered nanomaterials for carbon capture and bioenergy production in microbial electrochemical technologies: A review.

The mounting threat of global warming, fuelled by industrialization and anthropogenic activities, is undeniable. In 2017, atmospheric carbon dioxide (CO2), the primary greenhouse gas, exceeded 410 ppm for the first time. Shockingly, on April 28, 2023, this figure surged even higher, reaching an alarming 425 ppm. Even though extensive research has been conducted on developing efficient carbon capture and storage technologies, most suffer from high costs, short lifespans, and significant environmental impacts. Recently, the use of engineered nanomaterials (ENM), particularly in microbial electrochemical technologies (METs), has gained momentum owing to their appropriate physicochemical properties and catalytic activity. By implementing ENM, the MET variants like microbial electrosynthesis (MES) and photosynthetic microbial fuel cells (pMFC) can enhance carbon capture efficiency with simultaneous bioenergy production and wastewater treatment. This review provides an overview of ENMs' role in carbon capture within MES and pMFC, highlighting advancements and charting future research directions.

Waste-derived iron catalyzed bio-electro-Fenton process for the cathodic degradation of surfactants.

The application of waste-derived iron for reuse in wastewater treatment is an effective way of utilizing waste and attaining sustainability in the overall process. In the present investigation, bio-electro-Fenton process was initiated for the cathodic degradation of surfactants using waste-iron catalyzed MFC (WFe-MFC). The waste-iron was derived from spent tonner ink using calcination at 600 °C. Three surfactants namely, sodium dodecyl sulphate (SDS), cetyltrimethylammonium bromide, and Triton x-100 were selected as target pollutants. The effect of experimental factors like application of catalyst, contact time, external resistance, and anodic substrate concentration on the SDS degradation was investigated. At a neutral pH, the cathodic surfactants removal efficiency in WFe-MFC was above 85% in a contact time of 180 min with the initial surfactant concentration of ∼20 mg L-1 and external resistance of 100 Ω. The long-term operation using secondary treated real wastewater with unchanged cathode proved that the catalyst was still active to produce effluent SDS concentration of less than 1 mg L-1 in 4 h of contact time after 16 cycles. In a way, the present investigation suggests a potential application for spent tonner ink in the form of Fenton catalyst for wastewater treatment via bio-electro-Fenton MFC.

Microbial fuel cell coupled Fenton oxidation for the cathodic degradation of emerging contaminants from wastewater: Applications and challenges.

Urbanization and industrialization have resulted in the escalation of the occurrence of emerging contaminants (EC) in the wastewater and ultimately to the receiving water bodies due to their bio-refractory nature. The presence of ECs in the water bodies adversely affects all three domains of life, viz. bacteria, archaea and eukaryotes, and eventually the ecosystem. Fenton oxidation is one of the most suitable method that is capable of degrading a variety of ECs by employing a strong oxidizing agent in the form of •OH. The coupling of Fenton oxidation with microbial fuel cell (MFC) offers benefits, such as low-cost, minimal requirement of external energy, and in-situ generation of oxidizing agents. The resulting system, termed as bio-electro-Fenton MFC (BEF-MFC), is capable of degrading the ECs in the cathodic chamber, while harvesting bioelectricity and simultaneously removing oxidizable organic matter from wastewater in the anodic chamber. This review discusses the applications of BEF-MFC for the treatment of dyes, pharmaceuticals, pesticides, and real complex wastewaters. Additionally, the effect of operating conditions on the performance of BEF-MFC are elaborated and emphasis is also given on possible future direction of research that can be adopted in BEF-MFC in the purview of up-scaling.

A novel bio-electro-Fenton process for eliminating sodium dodecyl sulphate from wastewater using dual chamber microbial fuel cell.

The frequent occurrence of surfactants in urban wastewaters represents a multifaceted environmental concern. In this investigation, bio-electro-Fenton-microbial fuel cell (BEF-MFC) was developed for the degradation of sodium dodecyl sulphate (SDS) from wastewater. The synthesised cathode catalyst (powdered activated carbon and iron oxide) facilitated the Fenton reaction in the cathodic chamber of the MFC, concurrently generating a maximum power density of 105.67 mW m-2. The overall performance of the BEF-MFC for SDS removal and power generation excelled the control MFC (C-MFC) having carbon black coated cathode under similar operating conditions. Although, the rate of SDS degradation was favourable in acidic pH, under neutral pH, 70.8 ± 6.4% of SDS degradation was achieved in 120 min in BEF-MFC. A comparison of environmental impacts of BEF-MFC with up-flow MFC and electrochemical oxidation using life cycle assessment tool suggests that BEF-MFC can be one of the promising technologies for the tertiary treatment of wastewater.

Methanogenesis inhibitors used in bio-electrochemical systems: A review revealing reality to decide future direction and applications.

Microbial fuel cell (MFC) is a robust technology capable of treating real wastewaters by utilizing mixed anaerobic microbiota as inoculum for producing electricity from oxidation of the biodegradable matters. However, these mixed microbiota comprises of both electroactive microorganisms (EAM) and substrate/electron scavenging microorganisms such as methanogens. Hence, in order to maximize bioelectricity from MFC, different physio-chemical techniques have been applied in past investigations to suppress activity of methanogens. Interestingly, recent investigations exhibit that methanogens can produce electricity in MFC and possess the cellular machinery like cytochrome c and Type IV pili to perform extracellular electron transfer (EET) in the presence of suitable electron acceptors. Hence, in this review, in-depth analysis of versatile behaviour of methanogens in both MFC and natural anaerobic conditions with different inhibition techniques is explored. This review also discusses the future research directions based on the latest scientific evidence on role of methanogens for EET in MFC.

Waste-derived biochar: Applications and future perspective in microbial fuel cells.

Application of microbial fuel cell (MFC) is coming to the forefront as a dual-purpose system for wastewater treatment and energy recovery. Future research should emphasize on developing low-cost field-scale MFCs for removal of organic matter, nutrients, xenobiotic and recalcitrant compounds from wastewaters and powering low energy devices. For achieving this, low-cost electrodes, low-cost yet efficient cathode catalysts and proton exchange membrane (PEM) should be developed from waste-based resources to salvage the waste-derived material as much as possible, thereby reducing the fabrication cost of this device. Biochar is one such low-cost material, which has wide range of applications. This review discusses different applications of biochar in MFC, viz. in the form of standalone electrodes, electrocatalyst and material for PEM in light of different characteristics of biochar. Further emphasis is given on the future direction of research for implementation of biochar-based PEMs and electrodes in field-scale MFCs.

Numerical modeling of the dynamics of bubble oscillations subjected to fast variations in the ambient pressure with a coupled level set and volume of fluid method.

A numerical method for modeling and understanding the dynamics of bubble oscillations subjected to fast variations in the ambient pressure is proposed under low Mach number conditions. In the present work, the method uses a single-fluid continuum formalism of weakly compressible axisymmetric Navier-Stokes equations for the numerical simulation of liquid-gas flows with surface tension and adopts the interface capturing approach based on a coupled level set and volume of fluid (CLSVOF) method for describing the moving and deformed interfaces. To demonstrate the efficacy of the proposed method, first, the numerical results of the radial oscillations of a spherical gas bubble are tested with the numerical solutions of Rayleigh-Plesset equation. Then, the numerical method is applied to reproduce the growth and subsequent collapse of a bubble in an infinite liquid medium observed in experiments. Finally, the numerical simulation of the interaction of two oscillating bubbles at small separation distance is evaluated in response to a moderate step change in the ambient pressure. It is shown that two deformable bubbles undergo coupled radial and oscillatory translational motions which eventually results in the bubbles' attraction and coalescence caused by the secondary Bjerknes forces. The numerical predictions show very good accuracy with the experimental and numerical results reported in the literature.