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1.
ACS Nano ; 17(14): 13241-13255, 2023 Jul 25.
Artigo em Inglês | MEDLINE | ID: mdl-37382382

RESUMO

Dendrite growth and low Coulombic efficiency impede the practical application of Li-metal batteries. As such, monitoring Li deposition and stripping in real-time is crucial to understanding the fundamental lithium growth kinetics. This work presents an operando optical microscopic technique that enables precise current density control and quantification of Li layer properties (i.e., thickness and porosity) to study Li growth in various electrolytes. We discover the robustness and porosity of the remaining capping layer after the Li stripping process as the critical features governing the subsequent dendrite propagation behavior, resulting in distinct capping and stacking phenomena that affect Li growth upon cycling. While dendrite propagation quickly occurs through the fracture of the fragile Li capping layer, uniform Li plating/stripping can be facilitated by the compact and robust capping layer even at high current densities. This technique can be extended to evaluate dendrite suppression treatments in various metal batteries, providing in-depth information on metal growth mechanisms.

2.
Materials (Basel) ; 12(9)2019 May 08.
Artigo em Inglês | MEDLINE | ID: mdl-31071936

RESUMO

In this study, we investigate direct current (DC)/alternating current (AC) characteristic variability induced by work function fluctuation (WKF) with respect to different nanosized metal grains and the variation of aspect ratios (ARs) of channel cross-sections on a 10 nm gate gate-all-around (GAA) nanowire (NW) metal-oxide-semiconductor field-effect transistor (MOSFET) device. The associated timing and power fluctuations of the GAA NW complementary metal-oxide-semiconductor (CMOS) circuits are further estimated and analyzed simultaneously. The experimentally validated device and circuit simulation running on a parallel computing system are intensively performed while considering the effects of WKF and various ARs to access the device's nominal and fluctuated characteristics. To provide the best accuracy of simulation, we herein calibrate the simulation results and experimental data by adjusting the fitting parameters of the mobility model. Transfer characteristics, dynamic timing, and power consumption of the tested circuit are calculated using a mixed device-circuit simulation technique. The timing fluctuation mainly follows the trend of the variation of threshold voltage. The fluctuation terms of power consumption comprising static, short-circuit, and dynamic powers are governed by the trend that the larger the grain size, the larger the fluctuation.

3.
Biomed Res Int ; 2015: 897674, 2015.
Artigo em Inglês | MEDLINE | ID: mdl-25918724

RESUMO

BACKGROUND: This study investigated the epidemiology of torus palatinus (TP) and torus mandibularis (TM) in hemodialysis patients and analyzed the influences of hyperparathyroidism on the formation of oral tori. METHOD: During 2013, 119 hemodialysis patients were recruited for dental examinations for this study. RESULTS: The prevalence of oral tori in our sample group was high at 33.6% (40 of 119). The most common location of tori was TP (70.0%), followed by TM (20.0%), and then both TP and TM (10.0%). Of the 40 tori cases, most (67.5%) were <2 cm in size; moreover, the majority (52.5%) were flat in shape. In symmetry, most (70.0%) occurred in the midline, followed by bilateral sides (20.0%). Notably, the levels of intact parathyroid hormone did not differ in patients with or without tori (P = 0.611). Furthermore, patients with tori did not differ from patients without tori in inflammatory variables such as log high-sensitivity C-reactive protein (P = 1.000) or nutritional variables such as albumin (P = 0.247). Finally, there were no differences between patients with and without tori in adequacy of dialysis (P = 0.577). CONCLUSIONS: Neither hyperparathyroidism nor inflammation malnutrition syndrome was found to contribute to the formation of oral tori in chronic hemodialysis patients. Further studies are warranted.


Assuntos
Exostose/epidemiologia , Hiperparatireoidismo/epidemiologia , Hiperparatireoidismo/terapia , Desnutrição/epidemiologia , Desnutrição/terapia , Mandíbula/anormalidades , Palato Duro/anormalidades , Diálise Renal/efeitos adversos , Idoso , Exostose/etiologia , Feminino , Humanos , Masculino , Pessoa de Meia-Idade , Síndrome
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