Cd2+ removal efficiency of activated carbon from Prosopis juliflora: Optimization of preparation parameters by the Box-Behnken Design of Response Surface Methodology.

The study focuses on the preparation of activated carbon from Prosopis juliflora (PJAC) wood by pyrolysis and chemical activation. The objective is to assess its effectiveness as an adsorbent for synthesizing a composite adsorbent coating (CAC) for Cadmium (Cd2+) removal from aqueous solution. The effect of preparation factors related to Cd2+ removal efficiency was assessed. The Design of Experiments (DoE) for the adsorption of Cd2+ on the PJAC were done using the Box-Behnken Design (BBD) of the Response Surface Methodology (RSM) (Design Expert software version 11). The influence of impregnation ratio (IR), carbonization time (t), and carbonization temperature (T) on the Cd (II) percent (%) removal was evaluated. The response surface graphs in 3D were also generated for the response variable, and the higher R2 coefficient values were fitted into the polynomial quadric model. The results indicated that all the variable preparation factors were significant in the Cd2+ removal by PJAC with carbonization temperature being the most significant. At the optimum conditions i.e. impregnation ratio (1.8), carbonization temperature (595 °C) and carbonization time (174 min), the model predicted a 99.9 % Cd2+ removal efficiency while the adsorption experiment obtained a 96.7 % removal efficiency, respectively. Later, the morphological and chemical properties of the PJAC prepared with optimal parameters were analyzed using different characterization techniques including SBET, SEM-EDX, pHPZC, FTIR and XRD. The SEM images revealed a rough and porous morphological surface with an SBET of 600.4 m2/g and a near neutral pHPZC of 6.92. The XRD pattern indicated the crystalline nature of the prepared adsorbent. The pre and post adsorption FTIR spectrum of the PJAC demonstrated a distinct difference with the latter showing a reduction in peak intensity and height. These results underpin the potential of utilizing invasive plants like Prosopis Juliflora as adsorbents for heavy metal removal.

Cadmium removal from aqueous solution by blended bamboo sawdust/rice-husk biochar; optimization of influencing parameters.

This study attempted to investigate the adsorptive potential of blended bamboo (Oxytenanthera abyssinica) sawdust/rice husk (BSD/RH) at a ratio of 1:1 carbonized at 400 °C for the sorption of cadmium ions from synthetic solutions in batch mode. The Box-Behnken Design in response surface methodology (RSM) was used to achieve the best removal efficiency and adsorption capacity of the biochar. With a p-value of 0.0001, the initial Cd2+ concentration and adsorbent dose were discovered to be the most significant parameters controlling the adsorption capacity and removal efficiency of Cd2+ from the solution. At a pH of 8.95, ionic strength of 0.020 mol/L KNO3, a contact time of 15 min, an initial concentration of 200 mg/L, and an adsorbent dose of 0.5 g, the optimum Cd2+ removal and adsorption capacity of 99.97% and 358.65 mg/g, respectively, were obtained. The optimized conditions were later used to determine the removal efficiency and adsorption capacity of pristine biochars of rice husk and bamboo sawdust, which were found to be 79.8% and 83.7%, respectively. This finding indicates the potential for using biosorbent derived from blended feedstock materials to remove heavy metals such as cadmium.

Many studies investigated the pollutant removal potential of agricultural wastes as single feedstock adsorbent materials. The novel aspect of this study is that it examines their potentials on Cd²⁺ removal by combining two feedstocks (bamboo saw dust and rice husk) while optimizing the common influencing factors. Furthermore, a comparative analytical study was carried out between the blended feedstock biochar and their respective pristine ones. According to the findings, using blended biochar instead of pristine biochar results in a significant increase in Cd removal efficiency.

Room temperature synthesis of pillared-layer metal-organic frameworks (MOFs).

A pillared-layer MOF, {[Cu2(Fu)2(BPY)]·H2O} n , was synthesized at room temperature employing a mixture of water and methanol as the reaction solvent. By using the sodium salts of fumarate, instead of the native acids, the target MOF could be readily prepared in aqueous media. The PXRD of this MOF was found to be in good agreement with the simulated diffractogram from single crystal data of related MOF made at a higher temperature using DMF as the solvent. In addition to characterization by PXRD, TGA, and ESEM, N2-sorption measurements revealed the formation of mesopores in the MOF's structure under study. The electronic band gap and magnetic properties of this pillared-layer MOF were also studied.

Efficient anaerobic digestion of a mild wet air pretreated molasses ethanol distillery stillage: A comparative approach.

The effect of a mild, wet air pretreatment and the subsequent anaerobic digestion (AD) was examined on the recovery of a complex and toxic molasses ethanol distillery stillage. The biogas yield and organics removal due to pretreatment were compared with the raw stillage AD. The application of a scoria support in this industrial residue AD process stability was also assessed. Consequently, a statistically significant cumulative specific methane recovery difference (p-value = 0.000) with an almost complete biological oxygen demand (BOD) removal and a significant chemical oxygen demand (COD) reduction, which were 100% and 92% respectively were achieved. Additionally, the biogas recovery rate was hastened due to pretreatment. The application of scoria, whose property has been instrumentally inspected, has helped stabilize the pH in the AD systems. In a comparative approach, this study suggests the energy benefit and an ecofriendly discharge of stillage by the ethanol industry towards sustainability.

Controlling Particle Morphology and Pore Size in the Synthesis of Ordered Mesoporous Materials.

Ordered mesoporous materials have attracted considerable attention due to their potential applications in catalysis, adsorption, and separation technologies, as well as biomedical applications. In the present manuscript, we aim at a rational design to obtain the desired surface functionality (Ti and/or hydrophobic groups) while obtaining short channels (short diffusion paths) and large pore size (>10 nm). Santa Barbara Amorphous material SBA-15 and periodic mesoporous organosilica PMO materials are synthesized using Pluronic PE 10400 (P104) surfactant under mild acidic conditions to obtain hexagonal platelet-like particles with very short mesochannels (300-450 nm). The use of expanders, such as 1, 3, 5-trimethylbenzene (TMB) and 1, 3, 5-triisopropylbenzene (TIPB) were tested in order to increase the pore size. TMB yielded in the formation of vesicles in all the syntheses attempted, whereas P104 combined with TIPB resulted both in expanded (E) E-SBA-15 and E-PMO with 12.3 nm pore size short channel particles in both cases. Furthermore, the synthesis method was expanded to the incorporation of small amount of Ti via co-condensation method using titanocene as titanium source. As a result, Ti-E-SBA-15 was obtained with 15.5 nm pore size and isolated Ti-sites maintaining platelet hexagonal morphology. Ti-PMO was obtained with 7.8 nm and short channels, although the pore size under the tried synthesis conditions could not be expanded further without losing the structural ordering.

1,3-Ninhydrin dihydrazone featuring an R4(4)(12) motif with 4 symmetry and comprising only N and H atoms.

In the title compound [systematic name: (1Z,3Z)-1,3-dihydrazinylidene-1H-inden-2(3H)-one], C(9)H(8)N(4)O, isolated molecules possess approximate noncrystallographic C(2v) symmetry and their cis conformation and planarity are assisted by a pair of short intramolecular N-H···O hydrogen bonds. Each molecule is asymmetrically involved in an extensive three-dimensional network of N-H···O and N-H···N hydrogen bonds, and the structure also exhibits weaker π-π and C=O···C interactions. The structure features an R(4)(4)(12) motif consisting solely of N and H atoms and possessing crystallographic 4 symmetry.