1.
Acta Crystallogr Sect E Struct Rep Online
; 67(Pt 11): m1510, 2011 Nov.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22219760
RESUMO
In the title compound, [Mo(C(34)H(54)N(2)O(2))O(2)]·CHCl(3), the molybdenum(VI) ion exhibits a cis-dioxide distorted octa-hedral geometry. Two anionic phenolate O-atom donors and two neutral N-atom donors of the ligand are trans and cis, respectively. The Mo=O bond lengths and the O=Mo=O bond angle are typical for six-coordinated dioxomolyb-denum(VI) complexes. The Mo-N bond lengths are longer than 2.30â Å, as expected for a trans O=Mo-N structure.