Bis(4-acetyl-anilinium) hexa-chlorido-stannate(IV).

In the title compound, (C(8)H(10)NO)(2)[SnCl(6)], the Sn(IV) atom exists in an octa-hedral coordination environment. In the crystal, inter-molecular N-H⋯O and N-H⋯Cl hydrogen bonds link the cations and anions into a three-dimensional framework.

Bis[3-(meth-oxy-carbon-yl)anilinium] hexa-chloridostannate(IV).

In the title compound, (NH(3)C(6)H(4)CO(2)CH(3))(2)[SnCl(6)], the anions are situated on inversion centers so the asymmetric unit contains one cation and one half-anion. In the crystal, inter-molecular N-H⋯Cl and N-H⋯O hydrogen bonds link the cations and anions into layers parallel to the ac plane. The crystal packing exhibits voids of 37 Å(3).