Bifunctional Additive for Lithium-Sulfur Batteries Based on the Metal-Phthalocyanine Complex.

With extremely high specific capacity and high energy density, lithium-sulfur batteries (LSBs) have attracted enormous interest as promising candidates for energy storage devices. However, several problems, such as the shuttle effect and sluggish redox kinetics, hinder the successful realization of LSBs on an industrial scale. Therefore, designing an efficient electrode material to inhibit the shuttle effect and improve the reaction kinetics of polysulfides (LiPS) is of utmost significance. Herein, a bifunctional additive with excellent polysulfide adsorption and superior catalytic behavior is developed using the phthalocyanine-tetrasulfonic acid nickel complex tetrasodium salt (Ni-PCTs) additive. Ni-PCTs provide effective trapping of LiPS due to their abundant sulfonic acid groups. Moreover, Ni-PCTs exhibit effective catalytic conversion of LiPS due to the presence of N atoms in the phthalocyanine ring as well as the central Ni atoms. Consequently, the as-assembled LSBs, with a 10 wt % Ni-PCTs additive, exhibit a significant increase in specific capacities, such as the high initial specific capacity of 1283 mA h g-1 at 0.15 mA/cm2 and a stable specific capacity of 623 mA h g-1 after 400 cycles. The current study demonstrates the promise of metal phthalocyanines for sulfur cathodes, opening up avenues for further research and development of LSBs.

Ultraviolet In Situ Polymerized Binders with Polysulfide-Trapping Properties for Long-Cycle-Life Lithium-Sulfur Batteries.

Lithium-sulfur batteries (LSBs) represent a promising energy storage system due to the high theoretical energy density of the cathode; however, the high temperature and long-time drying required for electrode production result in high energy consumption and low efficiency. Ultraviolet (UV)-curing technology is an effective strategy to solve the abovementioned problems. However, carbon black and other conductive agents used in the production of the battery industry show strong absorption of UV light; thus, a single photoinitiator cannot absorb enough light intensity to realize initiation, limiting its application in the battery industry. In this work, the concept of full-band absorption is introduced into the manufacturing process of the LSB cathode to solve the abovementioned problems. The full-band absorption of photoinitiators in the UV band is successfully realized by combining the photoinitiators 2-benzyl-2-dimethylamino-1-(4-morpholinylphenyl)-1-butanone, 2-isopropyl thioxanthone, and bis (2,4,6-trimethyl benzoyl)-phenoxyphosphine. An ultraviolet in situ polymerized polyurethane acrylate (PUA) binder is successfully prepared by the combination of photoinitiators. PUA is used as the binder of LSBs and exhibits an excellent long-cycle performance of 1500 cycles with a low decay rate of 0.04% per cycle at 0.5 C. Thus, UV-curing technology provides a new prospect and possibility of industrialization for battery manufacturing.

A Supramolecular Hydrogel Enabled by the Synergy of Hydrophobic Interaction and Quadruple Hydrogen Bonding.

The increasing preference for minimally invasive surgery requires novel soft materials that are injectable, with rapid self-healing abilities, and biocompatible. Here, by utilizing the synergetic effect of hydrophobic interaction and quadruple hydrogen bonding, an injectable supramolecular hydrogel with excellent self-healing ability was synthesized. A unique ABA triblock copolymer was designed containing a central poly(ethylene oxide) block and terminal poly(methylmethacrylate) (PMMA) block, with ureido pyrimidinone (UPy) moieties randomly incorporated (termed MA-UPy-PEO-UPy-MA). The PMMA block could offer a hydrophobic microenvironment for UPy moieties in water and thus boost the corresponding quadruple hydrogen bonding interaction of Upy-Upy dimers. Owing to the synergetic effect of hydrophobicity and quadruple hydrogen bonding interaction, the obtained MA-UPy-PEO-UPy-MA hydrogel exhibited excellent self-healing properties, and injectable capability, as well as superior mechanical strength, and therefore, it holds great promise in tissue engineering applications, including in cell support and drug release.

Vegetable Oil-Based Waterborne Polyurethane as Eco-Binders for Sulfur Cathodes in Lithium-Sulfur Batteries.

Lithium-sulfur batteries (LSBs) suffer from well-known fast capacity losses despite their extremely high theoretical capacity and energy density. These losses are caused by dissolution of lithium polysulfide (LiPS) in ether-based electrolytes and have become the main bottleneck to widespread applications of LSBs. Therefore, there is a significant need for electrode materials that have a strong adsorption capacity for LiPS. Herein, a waterborne polyurethane (WPUN) containing sulfamic acid (NH2 SO3 H) polymer is designed and synthesized as an aqueous-based, ecofriendly binder by neutralizing sulfamic acid with a tung oil-based polyurethane prepolymer. UV-vis spectroscopy shows that the WPUN strongly immobilizes LiPS and thus is an effective inhibitor of the LiPS. Moreover, the WPUN binder has excellent adhesive and mechanical properties that improve the integrity of sulfur cathodes. The WPUN-based cathodes exhibit a significant improvement in their specific capacity and maintain a capacity of 617 mAh g-1 after 200 cycles at 0.5C. Besides, the LSBs assembled with the WPUN-based cathodes show good rate performance from 0.2C (737 mAh g-1 ) to 4C (586 mAh g-1 ), which is significantly higher than that of LSBs assembled with a commercial polymer binder. The structural design of the presented binder provides a new perspective for obtaining high-performance LSBs.