RESUMO
Chiral Metal-Organic Frameworks (CMOFs) is a kind of material with great application value in recent years. Formed by the coordination of metal ions or metal clusters with organic ligands. It has ordered and adjustable pores, multi-dimensional network structure, large specific surface area and excellent adsorption properties. This material structure combines the properties of metal-organic frameworks (MOFs) with the chiral properties of chiral molecules. It has great advantages in catalysis, adsorption, separation and other fields. Therefore, it has a wide range of applications in chemistry, biology, medicine and materials science. In this paper, various synthesis strategies and preparation methods of chiral metal-organic frameworks are reviewed from different perspectives, and the advantages of each method are analyzed. In addition, the applications of chiral metal-organic framework materials in enantiomer recognition and separation, circular polarization luminescence and asymmetric catalysis are systematically summarized, and the corresponding mechanisms are discussed. Finally, the challenges and prospects of the development of chiral metal-organic frame materials are analyzed in detail.
RESUMO
The purity of enantiomers plays a critical role in human health and safety. Enantioseparation is an effective way and necessary process to obtain pure chiral compounds. Enantiomer membrane separation is a new chiral resolution technique, which has the potential for industrialization. This paper mainly summarizes the research status of enantioseparation membranes including membrane materials, preparation methods, factors affecting membrane properties, and separation mechanisms. In addition, the key problems and challenges to be solved in the research of enantioseparation membranes are analyzed. Last but not least, the future development trend of the chiral membrane is expected.
RESUMO
The mountain shale in Wufeng Formation-Member 1 of Longmaxi Formation in the complex structural area of northern Yunnan-Guizhou has great potential for exploration and development. In order to clarify the differences of reservoir quality and the longitudinal distribution law of different lithofacies, the lithofacies in Wufeng Formation-Member 1 of Longmaxi Formation was divided combined with core, logging, and analytical test data. Based on the data of total organic carbon, laminate structure, reservoir porosity types and physical properties, and gas content, the reservoir characteristics and advantageous lithofacies shale reservoir distribution were determined. The results show that the mountain shale lithofacies in the study area are divided into 7 major types and 20 subtypes. The high-carbon siliceous shale has the highest degree of organic pore development, specific surface area (average 28.55 cm2/g), and pore volume (average 0.0397 cm3/g). Two types of advantageous lithofacies shale reservoir in the study area were identified. The high-carbon siliceous shale reservoir could be considered as an excellent shale reservoir for shale gas and is mainly concentrated in the first section. It is mainly developed in layer-1 and the bottom of layer-2 of the Longmaxi Formation, providing favorable source-reservoir conditions for shale gas enrichment. The medium-carbon siliceous shale, medium-carbon clay siliceous shale, and medium-carbon calcareous siliceous shale, developed in the top of layer-2 and the bottom of layer-3 of the Longmaxi Formation, are assumed to be moderately promising for shale gas. Therefore, the research results deepen the understanding of the longitudinal distribution of the dominant shale reservoirs in the study area and are of great significance in promoting strategic transfer of the main shale gas exploration system in the south from the Sichuan basin to the outer basin.
