1.
Org Lett
; 8(11): 2261-3, 2006 May 25.
Artigo
em Inglês
| MEDLINE
| ID: mdl-16706501
RESUMO
[reaction: see text] Dichloromethane serves as a novel electrophilic carbene equivalent which adds to an enamine double bond. The presence of other alkene moieties in the enamine partner is well tolerated. Even enamines derived from sterically hindered ketones react readily with dichloromethane promoted by TiCl(4)-Mg.