Crystalline germanium high-Q microresonators for mid-IR.

High-quality-factor optical microresonators have become an appealing object for numerous applications. However, the mid-infrared band experiences a lack of applicable materials for nonlinear photonics. Crystalline germanium demonstrates attractive material properties such as high nonlinear refractive index, large transparency window including the mid-IR band, particularly long wave multiphonon absorption limit. Nevertheless, the reported optical losses in germanium microresonators might not allow the potential of the Ge-based devices to be revealed. In this study, we report the fabrication of germanium microresonators with radii of 1.35 and 1.5 mm, exhibiting exceptional quality factors (Q-factors) exceeding 20 million, approaching the absorption-limited values at a wavelength of 2.68 µm. These Q-factors are a hundred times higher than previously reported, to the best of our knowledge. We measured the two-photon absorption coefficient combined with free-carrier absorption leveraging the high-Q of the resonators (obtained ßTPA = (0.71 ± 0.12) · 10-8 m/W at 2.68 µm). This research underscores the potential of whispering gallery mode microresonators as valuable tools for measuring absorption coefficients at different wavelengths, providing a comprehensive analysis of various loss mechanisms. Furthermore, the exceptional Q-factors observed in germanium microresonators open intriguing opportunities for the advancement of germanium-based photonics within the mid-infrared spectral band.

Multi-frequency self-injection locking of a FSR-tunable multimode laser diode.

This study presents the controllable multi-frequency self-injection locking regimes realization with an original experimental setup composed of a reflective semiconductor optical amplifier, an external feedback mirror, and a high-Q chip-scale Si3N4 ring microresonator. Our findings demonstrate the conditions of multiple modes' simultaneous locking being analogous to Vernier effect. We varied the free spectral range of the external-cavity laser by its length tuning, enabling the robust generations from 1 to 4 self-injection locked narrow lines on demand, that is important for optical telecommunications, and photonic-based microwave and THz sources.

Hybrid Silicon Nitride Photonic Integrated Circuits Covered by Single-Walled Carbon Nanotube Films.

The integration of low-dimensional materials with optical waveguides presents promising opportunities for enhancing light manipulation in passive photonic circuits. In this study, we investigate the potential of aerosol-synthesized single-walled carbon nanotube (SWCNT) films for silicon nitride photonic circuits as a basis for developing integrated optics devices. Specifically, by measuring the optical response of SWCNT-covered waveguides, we retrieve the main SWCNT film parameters, such as absorption, nonlinear refractive, and thermo-optic coefficients, and we demonstrate the enhancement of all-optical wavelength conversion and the photoresponse with a 1.2 GHz bandwidth.

Optimization of laser stabilization via self-injection locking to a whispering-gallery-mode microresonator: experimental study.

Self-injection locking of a diode laser to a high-quality-factor microresonator is widely used for frequency stabilization and linewidth narrowing. We constructed several microresonator-based laser sources with measured instantaneous linewidths of 1 Hz and used them for investigation and implementation of the self-injection locking effect. We studied analytically and experimentally the dependence of the stabilization coefficient on tunable parameters such as locking phase and coupling rate. It was shown that precise control of the locking phase allows fine-tuning of the generated frequency from the stabilized laser diode. We also showed that it is possible for such laser sources to realize fast continuous and linear frequency modulation by injection current tuning inside the self-injection locking regime. We conceptually demonstrate coherent frequency-modulated continuous wave LIDAR over a distance of 10 km using such a microresonator-stabilized laser diode in the frequency-chirping regime and measure velocities as low as sub-micrometer per second in the unmodulated case. These results could be of interest to cutting-edge technology applications such as space debris monitoring and long-range object classification, high-resolution spectroscopy, and others.

Dual-laser self-injection locking to an integrated microresonator.

Diode laser self-injection locking (SIL) to a whispering gallery mode of a high quality factor resonator is a widely used method for laser linewidth narrowing and high-frequency noise suppression. SIL has already been used for the demonstration of ultra-low-noise photonic microwave oscillators and soliton microcomb generation and has a wide range of possible applications. Up to date, SIL was demonstrated only with a single laser. However, multi-frequency and narrow-linewidth laser sources are in high demand for modern telecommunication systems, quantum technologies, and microwave photonics. Here we experimentally demonstrate the dual-laser SIL of two multifrequency laser diodes to different modes of an integrated Si3N4 microresonator. Simultaneous spectrum collapse of both lasers, as well as linewidth narrowing and high-frequency noise suppression , as well as strong nonlinear interaction of the two fields with each other, are observed. Locking both lasers to the same mode results in a simultaneous frequency and phase stabilization and coherent addition of their outputs. Additionally, we provide a comprehensive dual-SIL theory and investigate the influence of lasers on each other caused by nonlinear effects in the microresonator.

Surface-Enhanced Raman Scattering-Active Gold-Decorated Silicon Nanowire Substrates for Label-Free Detection of Bilirubin.

Bilirubin (BR) is a product of hemoglobin breakdown, and its increasing levels in the blood may indicate liver disorders and lead to jaundice. Kernicterus is most dangerous in newborns when the unconjugated BR concentration can quickly rise to toxic levels, causing neurological damage and even death. The development of an accurate, fast, and sensitive sensor for BR detection will help reduce diagnostic time and ensure successful treatment. In this study, we propose a new method for creating a surface-enhanced Raman scattering (SERS)-active substrate based on gold-decorated silicon nanowires (Au@SiNWs) for sensitive label-free BR detection. Gold-assisted chemical etching of crystalline silicon wafers was used to synthesize SiNWs, the tops of which were then additionally decorated with gold nanoparticles. The low detection limit of model analyte 4-mercaptopyridine down to the concentration of 10-8 M demonstrated the excellent sensitivity of the obtained substrates for SERS application. The theoretical full-wave electromagnetic simulations of Raman scattering in the Au@SiNW substrates showed that the major contribution to the total SERS signal comes from the analyte molecules located on the SiNW surface near the gold nanoparticles. Therefore, for efficient BR adsorption and SERS detection, the surface of the SiNWs was modified with amino groups. Label-free detection of BR using amino modified Au@SiNWs with high point-to-point, scan-to-scan, and batch-to-batch reproducibility with a detection limit of 10-6 M has been demonstrated. Artificial urine, mimicking human urine samples, was used as the matrix to get insights into the influence of different parameters such as matrix complexity on the overall BR SERS signal. The signal stability was demonstrated for 7 days after adsorption of BR with a concentration of 5 × 10-5 M, which is the required sensitivity for clinical applications.

Gold nanoparticle-carbon nanotube multilayers on silica microspheres: Optoacoustic-Raman enhancement and potential biomedical applications.

There has been growing interest in recent years in developing multifunctional materials for studying the structure interface in biological systems. In this regard, the multimodal systems, which possess activity in the near-infrared (NIR) region, become even more critical for the possibility of improving examined biotissue depth and, eventually, data analysis. Herein, we engineered bi-modal contrast agents by integrating carbon nanotubes (CNT) and gold nanoparticles (AuNP) around silica microspheres using the Layer-by-Layer self-assembly method. The experimental studies revealed that microspheres with CNT sandwiched between AuNP exhibit strong absorption in the visible and NIR regions and high optoacoustic contrast (OA, also called photoacoustics) and Raman scattering when illuminated with 532 nm and 785 nm lasers, respectively. The developed microspheres demonstrated amplification of the signal in the OA flow cytometry at the laser wavelength of 1064 nm. This finding was further validated with ex vivo brain tissue using a portable Raman spectrometer and imaging with the Raster-scanning OA mesoscopy technique. The obtained data suggest that the developed contrast agents can be promising in applications of localization OA tomography (LOT), OA flow cytometry, and multiplex SERS detection.

Single-walled carbon nanotube membranes as non-reflective substrates for nanophotonic applications.

We demonstrate that single-walled carbon nanotube (SWCNT) membranes can be successfully utilized as nanometer-thick substrates for enhanced visualization and facilitated study of individual nanoparticles. As model objects, we transfer optically resonant 200 nm silicon nanoparticles onto pristine and ethanol-densified SWCNT membranes by the femtosecond laser printing method. We image nanoparticles by scanning electron and bright-field optical microscopy, and characterize by linear and Raman scattering spectroscopy. The use of a pristine SWCNT membrane allows to achieve an order-of-magnitude enhancement of the optical contrast of the nanoparticle bright field image over the results shown in the case of the glass substrate use. The observed optical contrast enhancement is in agreement with the spectrophotometric measurements showing an extremely low specular reflectance of the pristine membrane (≤0.1%). Owing to the high transparency, negligibly small reflectance and thickness, SWCNT membranes offer a variety of perspective applications in nanophotonics, bioimaging and synchrotron radiation studies.