On the Origins of Some Spectroscopic Properties of "Purple Iron" (the Tetraoxoferrate(VI) Ion) and Its Pourbaix Safe-Space.

In this work, the authors attempt to interpret the visible, infrared and Raman spectra of ferrate(VI) by means of theoretical physical-inorganic chemistry and historical highlights in this field of interest. In addition, the sacrificial decomposition of ferrate(VI) during water treatment will also be discussed together with a brief mention of how Rayleigh scattering caused by the decomposition of FeVIO42- may render absorbance readings erroneous. This work is not a compendium of all the instrumental methods of analysis which have been deployed to identify ferrate(VI) or to study its plethora of reactions, but mention will be made of the relevant techniques (e.g., Mössbauer Spectroscopy amongst others) which support and advance this overall discourse at appropriate junctures, without undue elaboration on the foundational physics of these techniques.

Behaviour of neonicotinoids in contrasting soils.

Neonicotinoids are widely used to control insect pests in agriculture. Their presence in the environment can affect the health of non-target insects and aquatic animals. The behaviour of four neonicotinoids, namely imidacloprid, acetamiprid, thiacloprid and thiamethoxam, has been investigated in soils with contrasting characteristics to understand their migration in soil and ecological risk. Among the study neonicotinoids, thiamethoxam and thiacloprid were found to be the least and most sorbed neonicotinoids by all the soils, respectively (up to 186 time greater adsorption of thiacloprid), and their uptake was affected by the content of organic matter in the soil. Leaching studies in columns confirmed that thiamethoxam leached out of the soils readily, pointing out to a relatively high risk of ground water contamination with possible ecological impact when thiamethoxam is used in soils with low organic matter. In soil column studies, the soil with the lowest organic matter presents the greatest residue of neonicotinoids in the sub-surface (≤5 cm). In contrast the soil richer in organic matter presented most of the contamination deeper down in the column; a factor to be considered in the remediation from soil.