Stockholm Convention organochlorine pesticides and polycyclic aromatic hydrocarbons in Hong Kong air.

Organochlorine pesticides (OCPs) including eight of the original nine pesticides listed in the Stockholm Convention on Persistent Organic Pollutants, and polycyclic aromatic hydrocarbons (PAHs) were measured in 90 air samples collected from January 2004 to March 2005, and in 304 air samples collected from January 1998 to December 2005 in Hong Kong, respectively. The annual average OCP concentrations at Tap Mun, Yuen Long and Tsuen Wan were 135+/-140 (ND-482), 186+/-183 (ND-656), and 190+/-239 fg m(-3) (ND-966), respectively, while annual (January 1998 to December 2005) average concentrations of total PAHs at Tsuen Wan, and Central/Western were 578+/-261 (117-938) and 588+/-248ngm(-3) (103-874), respectively. No seasonal and spatial variations in OCP concentrations were observed due to trace levels, and estimation of carcinogenic risks of OC pesticides was low. Naphthalene (>70%) was the dominant PAH in terms of concentrations measured. The sum of three-ring PAHs, including acenaphthene, acenaphthylene, anthracene, fluorene and phenanthrene, contributed to around 20% of the total PAH concentration while the contribution of heavier PAHs (sum of four-, five- and six-rings) was less than 5%. t-Values of the paired samples T-test for the individual PAHs showed that the concentrations of benzo(a)pyrene, the relative high cancer risk PAH, and most of the PAHs detected at Tsuen Wan and Central/Western were significantly different (p<0.01), with higher concentrations detected at Tsuen Wan. Several PAHs exhibited strong seasonality with higher concentrations in winter. Sources of PAHs were determined by investigating PAH isomer ratios which suggested petrogenic sources as primary sources of PAHs in Hong Kong air.

A review on the usage of POP pesticides in China, with emphasis on DDT loadings in human milk.

This article attempts to review the usage of nine pesticides included in the 12 Stockholm Convention persistent organic pollutants (POPs) in China and to examine the extent of DDT contamination in human milk, focusing on the Chinese populations. By comparing all the data available concerning DDTs in human milk from 19 countries, it is revealed that the Chinese populations exhibit rather high concentrations of DDTs, due to the fact that China has been a major producer and consumer of DDTs in the past, and also uses DDT for vector control, resulting in higher background levels of DDTs in different ecological compartments. The high body loading of DDT in Chinese populations is also related to the high dietary intake due to contamination of food. When comparing the data obtained recently (1998-2002), the coastal populations such as Guangzhou (DDE+DDT 2.13 microgg(-1) fat), Hong Kong (2.87 microgg(-1) fat) and Dalian (2.13 microgg(-1) fat) contain higher concentrations of DDTs which may reflect the dietary difference of consuming more meat and fish, than other Chinese populations (Beijing 1.96 microgg(-1) fat; Shenyang 0.87 microgg(-1) fat). In general, the rather low ratio of DDE/DDT (e.g., 4.07 for Guangzhou) of the Chinese milk samples reflected the more recent releases of DDT. It is recommended to impose a tighter control on the use of DDT for vector control as well as for agricultural application, conduct regular monitoring of DDT concentrations in different ecological compartments which include air, water, sediment and biota. Human milk is a preferred indicator reflecting human body loadings of POPs including DDTs, as well as the risk which may impose on our next generation. A national wide survey is needed to investigate the intake of POPs, including POP pesticides, due to dietary differences, with a strong focus on the more sensitive populations, e.g., coastal residents who consume a large amount of fish.