Polytypic Two-Dimensional FeAs with High Anisotropy.

In the realm of two-dimensional (2D) crystal growth, the chemical composition often determines the thermodynamically favored crystallographic structures. This relationship poses a challenge in synthesizing novel 2D crystals without altering their chemical elements, resulting in the rarity of achieving specific crystallographic symmetries or lattice parameters. We present 2D polymorphic FeAs crystals that completely differ from bulk orthorhombic FeAs (Pnma), differing in the stacking sequence, i.e., polytypes. Preparing polytypic FeAs outlines a strategy for independently controlling each symmetry operator, which includes the mirror plane for 2Q-FeAs (I4/mmm) and the glide plane for 1Q-FeAs (P4/nmm). As such, compared to bulk FeAs, polytypic 2D FeAs shows highly anisotropic properties such as electrical conductivity, Young's modulus, and friction coefficient. This work represents a concept of expanding 2D crystal libraries with a given chemical composition but various crystal symmetries.

Nontypical Wulff-Shape Silicon Nanosheets with High Catalytic Activity.

Nanostructured silicon with an equilibrium shape has exhibited hydrogen evolution reaction activity mainly owing to its high surface area, which is distinct from that of bulk silicon. Such a Wulff shape of silicon favors low-surface-energy planes, resulting in silicon being an anisotropic and predictably faceted solid in which certain planes are favored, but this limits further improvement of the catalytic activity. Here, we introduce nanoporous silicon nanosheets that possess high-surface-energy crystal planes, leading to an unconventional Wulff shape that bolsters the catalytic activity. The high-index plane, uncommonly seen in the Wulff shape of bulk Si, has a band structure optimally aligned with the redox potential necessary for hydrogen generation, resulting in an apparent quantum yield (AQY) of 12.1% at a 400 nm wavelength. The enhanced light absorption in nanoporous silicon nanosheets also contributes to the high photocatalytic activity. Collectively, the strategy of making crystals with nontypical Wulff shapes can provide a route toward various classes of photocatalysts for hydrogen production.

Protection and Installation of FBG Strain Sensor in Deep Boreholes for Subsurface Faults Behavior Monitoring.

Fiber optic sensors are gradually replacing electrical sensors in geotechnical applications owing to their immunity to electrical interference, durability, and cost-effectiveness. However, additional protective measures are required to prevent loss of functionality due to damage to the sensors, cables, or connection parts (splices and/or connectors) during installation and completion processes in borehole applications. We introduce two cases of installing fiber Bragg grating (FBG) strain sensors in 1 km boreholes to monitor the behavior of deep subsurface faults. We present our fiber-reinforced plastic (FRP) forming schemes to protect sensors and splices. We also present uniaxial load test and post-completion monitoring results for assessing the effects and performance of the protective measures. The uniaxial load test and post-completion monitoring show that FBG sensors are well protected by FRP forming without significant impact on sensor performance itself and that they are successfully installed in deep boreholes. In addition to summarizing our learning from experiences, we also suggest several points for consideration to improve the applicability of FBG sensors in borehole environment of the geotechnical field.

Enhancing Li Ion Battery Performance by Mechanical Resonance.

The quest for safe and high-performance Li ion batteries (LIBs) motivates intense efforts seeking a high-energy but reliable anode, cathode, and nonflammable electrolyte. For any of these, exploring new electrochemistry methods that enhance safety and performance by employing well-designed electrodes and electrolytes are required. Electrolyte wetting, governed by thermodynamics, is another critical issue in increasing Li ion transport through the separator. Herein, we report an approach to enhancing LIB performance by applying mechanical resonant vibration to increase electrolyte wettability on the separator. Wetting is activated at a resonant frequency with a capillary wave along the surface of the electrolyte, allowing the electrolyte to infiltrate into the porous separator by inertia force. This mechanical resonance, rather than electrochemistry, leads to the high specific capacity, rate capability, and cycling stability of LIBs. The concept of the mechanical approach is a promising yet simple strategy for the development of safer LIBs using liquid electrolytes.

Neuromorphic van der Waals crystals for substantial energy generation.

Controlling ion transport in nanofluidics is fundamental to water purification, bio-sensing, energy storage, energy conversion, and numerous other applications. For any of these, it is essential to design nanofluidic channels that are stable in the liquid phase and enable specific ions to pass. A human neuron is one such system, where electrical signals are transmitted by cation transport for high-speed communication related to neuromorphic computing. Here, we present a concept of neuro-inspired energy harvesting that uses confined van der Waals crystal and demonstrate a method to maximise the ion diffusion flux to generate an electromotive force. The confined nanochannel is robust in liquids as in neuron cells, enabling steady-state ion diffusion for hundred of hours and exhibiting ion selectivity of 95.8%, energy conversion efficiency of 41.4%, and power density of 5.26 W/m2. This fundamental understanding and rational design strategy can enable previously unrealisable applications of passive-type large-scale power generation.

Sparked Reduced Graphene Oxide for Low-Temperature Sodium-Beta Alumina Batteries.

Wetting Na metal on the solid electrolyte of a liquid Na battery determines the operating temperature and performance of the battery. At low temperatures below 200 °C, liquid Na wets poorly on a solid electrolyte near its melting temperature (Tm = 98 °C), limiting its suitability for use in low-temperature batteries used for large-scale energy-storage systems. Herein, we propose the use of sparked reduced graphene oxide (rGO) that can improve the Na wetting in sodium-beta alumina batteries (NBBs), allowing operation at lower temperatures. Experimental and computational studies indicated rGO layers with nanogaps exhibited complete liquid Na wetting regardless of the surface energy between the liquid Na and the graphene oxide, which originated from the capillary force in the gap. Employing sparked rGO significantly enhanced the cell performance at 175 °C; the cell retained almost 100% Coulombic efficiency after the initial cycle, which is a substantial improvement over cells without sparked rGO. These results suggest that coating sparked rGO is a promising but simple strategy for the development of low-temperature NBBs.

Bismuth Islands for Low-Temperature Sodium-Beta Alumina Batteries.

Wetting of the liquid metal on the solid electrolyte of a liquid metal battery controls the operating temperature and performance of the battery. Liquid sodium electrodes are particularly attractive because of their low cost, natural abundance, and geological distribution. However, they wet poorly on a solid electrolyte near its melting temperature, limiting their widespread suitability for low-temperature batteries to be used for large-scale energy storage systems. Herein, we develop an isolated metal-island strategy that can improve sodium wetting in sodium-beta alumina batteries that allows operation at lower temperatures. Our results suggest that in situ heat treatment of a solid electrolyte followed by bismuth deposition effectively eliminates oxygen and moisture from the surface of the solid electrolyte, preventing the formation of an oxide layer on the liquid sodium, leading to enhanced wetting. We also show that employing isolated bismuth islands significantly improves cell performance, with cells retaining 94% of their charge after the initial cycle, an improvement over cells without bismuth islands. These results suggest that coating isolated metal islands is a promising and straightforward strategy for the development of low-temperature sodium-ß alumina batteries.

Distributed Temperature Sensing Monitoring of Well Completion Processes in a CO2 Geological Storage Demonstration Site.

The Distributed Temperature Sensing (DTS) profiles obtained during well completion of a CO2 monitoring well were analyzed to characterize each well completion process in terms of temperature anomalies. Before analysis, we corrected the depth by redistributing the discrepancy, and then explored three temperature calibration methods. Consequently, we confirmed the depth discrepancy could be well corrected with conventional error redistribution techniques. Among three temperature calibration methods, the conventional method shows the best results. However, pointwise methods using heat coil or in-well divers also showed reliable accuracy, which allows them to be alternatives when the conventional method is not affordable. The DTS data revealed that each well completion processes can be characterized by their own distinctive temperature anomaly patterns. During gravel packing, the sand progression was monitorable with clear step-like temperature change due to the thermal bridge effect of sand. The DTS data during the cementing operation, also, clearly showed the progression up of the cement slurry and the exothermic reaction associated with curing of cement. During gas lift operations, we could observe the effect of casing transition as well as typical highly oscillating thermal response to gas lifting.

Twisted Dual-Cycle Fiber Optic Bending Loss Characteristics for Strain Measurement.

The intensity-based fiber optic sensor (FOS) head using twisted dual-cycle bending loss is proposed and experimentally demonstrate. The bending loss characteristics depend on the steel wire radius, number, and distance. To determine the effects of these parameters, two samples in each of seven configuration cases of the proposed FOS head were bonded to fiber reinforced plastics coupons, and tensile and flexural strain tests were repeated five times for each coupon. The bending loss of the manufactured FOS heads was measured and converted to the tensile and flexural strain as a function of configuration cases. The measurement range, sensitivity, and average measurement errors of the tensile load and flexural strain were 4.5 kN and 1,760 µÎµ, 0.70 to 3.99 dB/kN and 0.930 to 6.554 dB/mm, and 57.7 N, and 42.6 µÎµ, respectively. The sensing range of FOS head were 82 to 138 mm according to configuration cases. These results indicate that it is possible to measure load, tensile strain, and flexural strain using the proposed FOS head, and demonstrate that the sensitivities, the operating ranges, and the sensing range can be adjusted depending on the deformation characteristics of the measurement target.

An Optical Fiber Displacement Sensor Using RF Interrogation Technique.

We propose a novel non-contact optical fiber displacement sensor. It uses a radio frequency (RF) interrogation technique which is based on bidirectional modulation of a Mach-Zehnder electro-optical modulator (MZ-EOM). The displacement is measured from the free spectral range (FSR) which is determined by the dip frequencies of the modulated MZ-EOM transfer function. In experiments, the proposed sensor showed a sensitivity of 456 kHz/mm or 1.043 kHz/V in a measurement range of 7 mm. The displacement resolution of the proposed sensor depends on the linewidth and the power of the optical source. Resolution better than 0.05 µm would be achieved if an optical source which has a linewidth narrower than 1.5 nm and a received power larger than -36 dBm is used. Also, the multiplexing characteristic of the proposed sensor was experimentally validated.

A self-referencing intensity-based fiber optic sensor with multipoint sensing characteristics.

A self-referencing, intensity-based fiber optic sensor (FOS) is proposed and demonstrated. The theoretical analysis for the proposed design is given, and the validity of the theoretical analysis is confirmed via experiments. We define the measurement parameter, X, and the calibration factor, ß, to find the transfer function, , of the intensity-based FOS head. The self-referencing and multipoint sensing characteristics of the proposed system are validated by showing the measured and relative error versus the optical power attenuation of the sensor head for four cases: optical source fluctuation, various remote sensing point distances, fiber Bragg gratings (FBGs) with different characteristics, and multiple sensor heads with cascade and/or parallel forms. The power-budget analysis and limitations of the measurement rates are discussed, and the measurement results of fiber-reinforced plastic (FRP) coupon strain using the proposed FOS are given as an actual measurement. The proposed FOS has several benefits, including a self-referencing characteristic, the flexibility to determine FBGs, and a simple structure in terms of the number of devices and measuring procedure.

Novel RF interrogation of a fiber Bragg grating sensor using bidirectional modulation of a Mach-Zehnder electro-optical modulator.

We propose and experimentally demonstrate the novel radio-frequency (RF) interrogation of a fiber Bragg grating (FBG) sensor using bidirectional modulation of a Mach-Zehnder electro-optical modulator (MZ-EOM). Based on the microwave photonic technique and active detection, the transfer function of the proposed system was obtained, and the time delay was calculated from the change in the free spectral range (FSR) at different wavelengths over the optimal measuring range. The results show that the time delay and the wavelength variation have a good linear relationship, with a gradient of 9.31 ps/nm. An actual measurement taken with a sensing FBG for temperature variation shows the relationship with a gradient of 0.93 ps/10 °C. The developed system could be used for FBG temperature or strain sensing and other multiplexed sensor applications.

Effect of span length on the fit of zirconia framework fabricated using CAD/CAM system.

PURPOSE: The purpose of this study was to evaluate the effect of the span length on the fit of zirconia framework fabricated using CAD/CAM system. MATERIALS AND METHODS: Abutments for single, 4-unit and 6-unit fixed partial prostheses were fabricated. Ten zirconia frameworks were fabricated for each group. The marginal and internal gap were presented by means of replica technique and measured by measuring microscope (AXIO®, Carl Zeiss, Rochester, NY) and software (I-solution®, IMT i-solution Inc., Vancouver, BC, Canada). The results were statistically analyzed by multivariate analysis test and Dunnett T3 test for post hoc test (α=.05). RESULTS: There were statistically significant differences at 2, 4, 7, 8 points (mesio-distal section) and b, d, e, f, g (labio-lingual section). In some marginal reference points of 6-unit group (P<.05), the marginal gap were larger than 120 µm. CONCLUSION: Span length of zirconia core may have an influence on marginal and internal fit. Within the limitation of this study, the increase of span length of zirconia framework of 6 or more-unit fixed partial denture may decrease the marginal and internal fit.