1.
J Org Chem
; 88(17): 12531-12541, 2023 09 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37560896
RESUMO
We report on the stereoselective multigram scale preparation of cyclohexyl- and phenyl thioglycosides of 2-azido-2-deoxy-ß-d-gluco- and galactopyranosides from d-N-acetylglucosamine using a catalytic and solvent-free method. Two of the prepared building blocks were used as key intermediates for the synthesis of human milk oligosaccharides LNT and LNnT in their protected form.