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1.
Materials (Basel) ; 16(3)2023 Jan 26.
Artigo em Inglês | MEDLINE | ID: mdl-36770090

RESUMO

The development of new lightweight materials is required for the automotive industry to reduce the impact of carbon dioxide emissions on the environment. The lightweight, high-manganese steels are the prospective alloys for this purpose. Hot deformation is one of the stages of the production of steel. Hot deformation behavior is mainly determined by chemical composition and thermomechanical parameters. In the paper, an artificial neural network (ANN) model with high accuracy was constructed to describe the high Mn steel deformation behavior in dependence on the concentration of the alloying elements (C, Mn, Si, and Al), the deformation temperature, the strain rate, and the strain. The approval compression tests of the Fe-28Mn-8Al-1C were made at temperatures of 900-1150 °C and strain rates of 0.1-10 s-1 with an application of the Gleeble 3800 thermomechanical simulator. The ANN-based model showed high accuracy, and the low average relative error of calculation for both training (5.4%) and verification (7.5%) datasets supports the high accuracy of the built model. The hot deformation effective activation energy values for predicted (401 ± 5 kJ/mol) and experimental data (385 ± 22 kJ/mol) are in satisfactory accordance, which allows applying the model for the hot deformation analysis of the high-Mn steels with different concentrations of the main alloying elements.

2.
Sci Rep ; 5: 7799, 2015 Jan 15.
Artigo em Inglês | MEDLINE | ID: mdl-25589472

RESUMO

Zr-Pd metallic glassy thin films with a hierarchical nano-scale structure, produced by magnetron sputtering of the Zr and Pd powder mixture, demonstrate a unique combination of physical and biochemical properties. Thermal stability of the nano-structured glassy samples, their resistance to oxidation in dry air and phase transformation behavior are discussed in the present work. These binary alloy samples also show exceptionally high corrosion resistance and spontaneous passivation in a simulated body fluid. Experiments on the catalytic activity and biocompatibility of this nanostructured metallic glass indicate that this is a very suitable material for biochemical applications. Compared to the multicomponent alloys studied earlier this binary alloy has much simpler chemical composition, which makes preparation of the sample with defined stoichiometry easier, especially when the elements have different sputtering rates.


Assuntos
Bioquímica/métodos , Vidro/química , Nanoestruturas/química , Paládio/química , Zircônio/química , Fosfatase Alcalina/metabolismo , Animais , Catálise , Eletrólise , Humanos , Nanoestruturas/ultraestrutura , Osteoblastos/citologia , Osteoblastos/enzimologia , Espectroscopia Fotoeletrônica , Soluções , Difração de Raios X
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