Challenges on optical printing of colloidal nanoparticles.

While colloidal chemistry provides ways to obtain a great variety of nanoparticles with different shapes, sizes, material compositions, and surface functions, their controlled deposition and combination on arbitrary positions of substrates remain a considerable challenge. Over the last ten years, optical printing arose as a versatile method to achieve this purpose for different kinds of nanoparticles. In this article, we review the state of the art of optical printing of single nanoparticles and discuss its strengths, limitations, and future perspectives by focusing on four main challenges: printing accuracy, resolution, selectivity, and nanoparticle photostability.

Complex colloidal structures with non-linear optical properties formed in an optical trap.

Illumination of a colloidal suspension of dielectric nanoparticles (50 nm in radius) with counter-propagating non-interfering laser beams of sufficient power leads to spatial redistribution of particles due to associated optical forces and formation of colloidal structures composed of thousands of nanoparticles along the beams. We employ a weak probe beam propagating through the colloidal structure and demonstrate that the colloidal structure acts effectively as a non-linear optical medium, similar to a gradient index lens, with optical transformation properties externally tunable by trapping laser power. With an increasing number of nanoparticles we observe the formation of a more complex colloidal structure axially and even laterally and we explain the origin of this process.

Spin to orbital light momentum conversion visualized by particle trajectory.

In a tightly focused beam of light having both spin and orbital angular momentum, the beam exhibits the spin-orbit interaction phenomenon. We demonstrate here that this interaction gives rise to series of subtle, but observable, effects on the dynamics of a dielectric microsphere trapped in such a beam. In our setup, we control the strength of spin-orbit interaction with the width, polarization and vorticity of the beam and record how these parameters influence radius and orbiting frequency of the same single orbiting particle pushed by the laser beam. Using Richard and Wolf model of the non-paraxial beam focusing, we found a very good agreement between the experimental results and the theoretical model based on calculation of the optical forces using the generalized Lorenz-Mie theory extended to a non-paraxial vortex beam. Especially the radius of the particle orbit seems to be a promising parameter characterizing the spin to orbital momentum conversion independently on the trapping beam power.

Optomechanical properties of optically self-arranged colloidal waveguides.

When a suspension of wavelength-sized polystyrene spheres is illuminated with non-interfering counter-propagating Gaussian beams, the particles self-arrange into a colloidal waveguide (CWG). Mutual force interaction among particles is mediated by scattered light, referred to as the optical binding. We analyzed the longitudinal and lateral motion of particles in such CWGs made of an increasing number of particles with diameters of either 520 or 657 nm. We observed the enhancement of the binding stiffness of neighboring particles by more than an order of magnitude. This enhancement is done by optical means, mainly due to a local increase of optical intensity due to multiple light scattering in an optically bound structure.

Enhancement of the 'tractor-beam' pulling force on an optically bound structure.

Recently, increasing attention has been devoted to mastering a new technique of optical delivery of micro-objects tractor-beam'1, 2, 3, 4, 5, 6, 7, 8, 9. Such beams have uniform intensity profiles along their propagation direction and can exert a negative force that, in contrast to the familiar pushing force associated with radiation pressure, pulls the scatterer toward the light source. It was experimentally observed that under certain circumstances, the pulling force can be significantly enhanced6 if a non-spherical scatterer, for example, a linear chain of optically bound objects10, 11, 12, is optically transported. Here we demonstrate that motion of two optically bound objects in a tractor beam strongly depends on theirs mutual distance and spatial orientation. Such configuration-dependent optical forces add extra flexibility to our ability to control matter with light. Understanding these interactions opens the door to new applications involving the formation, sorting or delivery of colloidal self-organized structures.

Accuracy and Mechanistic Details of Optical Printing of Single Au and Ag Nanoparticles.

Optical printing is a powerful all-optical method that allows the incorporation of colloidal nanoparticles (NPs) onto substrates with nanometric precision. Here, we present a systematic study of the accuracy of optical printing of Au and Ag NPs, using different laser powers and wavelengths. When using light of wavelength tuned to the localized surface plasmon resonance (LSPR) of the NPs, the accuracy improves as the laser power is reduced, whereas for wavelengths off the LSPR, the accuracy is independent of the laser power. Complementary studies of the printing times of the NPs reveal the roles of Brownian and deterministic motion. Calculated trajectories of the NPs, taking into account the interplay between optical forces, electrostatic forces, and Brownian motion, allowed us to rationalize the experimental results and gain a detailed insight into the mechanism of the printing process. A clear framework is laid out for future optimizations of optical printing and optical manipulation of NPs near substrates.

Non-spherical gold nanoparticles trapped in optical tweezers: shape matters.

We present the results of a theoretical analysis focused on three-dimensional optical trapping of non-spherical gold nanoparticles using a tightly focused laser beam (i.e. optical tweezers). We investigate how the wavelength of the trapping beam enhances trapping stiffness and determines the stable orientation of nonspherical nanoparticles in the optical trap which reveals the optimal trapping wavelength. We consider nanoparticles with diameters being between 20 nm and 254 nm illuminated by a highly focused laser beam at wavelength 1064 nm and compare our results based on the coupled-dipole method with published theoretical and experimental data. We demonstrate that by considering the non-spherical morphology of the nanoparticle we can explain the experimentally observed three-dimensional trapping of plasmonic nanoparticles with size higher than 170 nm. These results will contribute to a better understanding of the trapping and alignment of real metal nanoparticles in optical tweezers and their applications as optically controllable nanosources of heat or probes of weak forces and torques.

Complex rotational dynamics of multiple spheroidal particles in a circularly polarized, dual beam trap.

We examine the rotational dynamics of spheroidal particles in an optical trap comprising counter-propagating Gaussian beams of opposing helicity. Isolated spheroids undergo continuous rotation with frequencies determined by their size and aspect ratio, whilst pairs of spheroids display phase locking behaviour. The introduction of additional particles leads to yet more complex behaviour. Experimental results are supported by numerical calculations.

Three-dimensional optical trapping of a plasmonic nanoparticle using low numerical aperture optical tweezers.

It was previously believed that larger metal nanoparticles behave as tiny mirrors that are pushed by the light beam radiative force along the direction of beam propagation, without a chance to be confined. However, several groups have recently reported successful optical trapping of gold and silver particles as large as 250 nm. We offer a possible explanation based on the fact that metal nanoparticles naturally occur in various non-spherical shapes and their optical properties differ significantly due to changes in localized plasmon excitation. We demonstrate experimentally and support theoretically three-dimensional confinement of large gold nanoparticles in an optical trap based on very low numerical aperture optics. We showed theoretically that the unique properties of gold nanoprisms allow an increase of trapping force by an order of magnitude at certain aspect ratios. These results pave the way to spatial manipulation of plasmonic nanoparticles using an optical fibre, with interesting applications in biology and medicine.

Rotation, oscillation and hydrodynamic synchronization of optically trapped oblate spheroidal microparticles.

While the behavior of optically trapped dielectric spherical particles has been extensively studied, the behavior of non-spherical particles remains mainly unexplored. In this work we focus on the dynamics of oblate spheroidal particles trapped in a tightly focused elliptically-polarized vortex beam. In our experiments we used polystyrene spheroids of aspect ratio of major to minor axes equal to 2.55 and of a volume equal to a sphere of diameter 1.7µm. We demonstrate that such particles can be trapped in three dimensions, with the minor axis oriented perpendicular to both the beam polarization (linear) and the beam propagation, can spin in a circularly polarized beam and an optical vortex beam around the axis parallel with the beam propagation. We also observed that these particles can exhibit a periodic motion in the plane transversal to the beam propagation. We measured that the transfer of the orbital angular momentum from the vortex beam to the spheroid gives rise to torques one order of magnitude stronger comparing to the circularly polarized Gaussian beam. We employed a phase-only spatial light modulator to generate several vortex beam traps with one spheroid in each of them. Due to independent setting of beams parameters we controlled spheroids frequency and sense of rotation and observed hydrodynamic phase and frequency locking of rotating spheroids. These optically driven spheroids offer a simple alternative approach to the former techniques based on birefringent, absorbing or chiral microrotors.

Optical sorting of nonspherical and living microobjects in moving interference structures.

Contactless, sterile and nondestructive separation of microobjects or living cells is demanded in many areas of biology and analytical chemistry, as well as in physics or engineering. Here we demonstrate advanced sorting methods based on the optical forces exerted by travelling interference fringes with tunable periodicity controlled by a spatial light modulator. Besides the sorting of spherical particles we also demonstrate separation of algal cells of different sizes and particles of different shapes. The three presented methods offer simultaneous sorting of more objects in static suspension placed in a Petri dish or on a microscope slide.

Optical alignment and confinement of an ellipsoidal nanorod in optical tweezers: a theoretical study.

Within the Rayleigh approximation, we investigate the behavior of an individual ellipsoidal metal nanorod that is optically confined in three dimensions using a single focused laser beam. We focus on the description of the optical torque and optical force acting upon the nanorod placed into a linearly polarized Gaussian beam (scalar description of the electric field) or a strongly focused beam (vector field description). The study comprises the influence of the trapping laser wavelength, the angular aperture of focusing optics, the orientation of the ellipsoidal nanorod, and the aspect ratio of its principal axes. The results reveal a significantly different behavior of the nanorod if the trapping wavelength is longer or shorter than the wavelength corresponding to the longitudinal plasmon resonance mode. Published experimental observations are compared with our theoretical predictions with satisfactory results.