Transmission enhancement through square coaxial aperture arrays in metallic film: when leaky modes filter infrared light for multispectral imaging.

The diffractive behavior of arrays of square coaxial apertures in a gold layer is studied. These structures exhibit a resonant transmission enhancement that is used to design tunable bandpass filters for multispectral imaging in the 7-13 µm wavelength range. A modal analysis is used for this design and the study of their spectral features. Thus we show that the resonance peak is due to the excitation of leaky modes of the open photonic structure. Fourier transform infrared (FTIR) spectrophotometry transmission measurements of samples deposited on Si substrate show good agreement with numerical results and demonstrate angular tolerance of up to 30 degrees of the fabricated filters.

Laser-induced damage thresholds of bulk and coating optical materials at 1030 nm, 500 fs.

We report on extensive femtosecond laser damage threshold measurements of optical materials in both bulk and thin-film form. This study, which is based on published and new data, involved simple oxide and fluoride films, composite films made from a mixture of two dielectric materials, metallic films, and the surfaces of various bulk materials: oxides, fluorides, semiconductors, and ionic crystals. The samples were tested in comparable conditions at 1030 nm, 375 to 600 fs, under single-pulse irradiation. A large number of different samples prepared by different deposition techniques have been tested, involving classical materials used in the fabrication of optical thin film components (Ag, AlF3, Al2O3, HfO2, MgF2, Nb2O5, Pt, Sc2O3, SiO2, Ta2O5, Y2O3, and ZrO2) and their combination with codeposition processes. Their behaviors are compared with the surfaces of bulk materials (Al2O3, BaF2, CaF2, Ge, KBr, LiF, MgF2, NaCl, Quartz, Si, ZnS, ZnSe, and different silica glasses). Tabulated values of results are presented and discussed.

Relation of optical properties and femtosecond laser damage resistance for Al2O3/AlF3 and Al2O3/SiO2 composite coatings.

We report on the realization of aluminum oxyfluoride thin films and alumina/silica mixture coatings with different ratios by ion beam sputtering. The atomic compositions quantified by energy dispersive x-ray spectroscopy are correlated with the optical properties calculated from spectrophotometry and laser calorimetry measurements. Furthermore, the femtosecond laser damage resistance (τ=400 fs) of single layers is investigated in the infrared at 1030 nm and in the ultraviolet at 343 nm wavelengths. Experimental results on the wavelength scaling of the laser-induced damage threshold for oxyfluoride and oxide composite coatings are presented.

Laser-induced damage in composites of scandium, hafnium, aluminum oxides with silicon oxide in the infrared.

The laser-induced damage of mixtures of Sc2O3, HfO2, Al2O3 with SiO2 has been characterized in the infrared for both nanosecond and subpicosecond pulses. Laser-induced damage thresholds (LIDTs) are reported and discussed versus band gap for different compositions. The distributions versus fluence of nanosecond damage precursor densities are extracted fitting damage probability curves. Two models are used: first, a statistical approach, i.e., direct calculation of damage precursor density from damage probability, and second a thermal model based on absorption of initiator. The results show a good agreement. The nature, shape, and size of these precursors are discussed. The critical temperature in the thermal model is dependent on the band gap energy.

Adaptive Perfectly Matched Layer for Wood's anomalies in diffraction gratings.

We propose an Adaptive Perfectly Matched Layer (APML) to be used in diffraction grating modeling. With a properly tailored co-ordinate stretching depending both on the incident field and on grating parameters, the APML may efficiently absorb diffracted orders near grazing angles (the so-called Wood's anomalies). The new design is implemented in a finite element method (FEM) scheme and applied on a numerical example of a dielectric slit grating. Its performances are compared with classical PML with constant stretching coefficient.

Femtosecond laser damage resistance of oxide and mixture oxide optical coatings.

We report on the laser damage resistance of ion beam-sputtered oxide materials (Al2O3, Nb2O5, HfO2, SiO2, Ta2O5, ZrO2) and mixtures of Al2O3-SiO2, Nb2O5-SiO2, HfO2-SiO2, Ta2O5-SiO2, and ZrO2-SiO2, irradiated by single 500 fs pulses at 1030 nm. Laser-induced damage threshold (LIDT), refractive index, and bandgaps of the single-layer coatings are measured. For pure oxide materials a linear evolution of the LIDT with bandgap is observed. The results are in accordance with our simulations based on photo-ionization and avalanche-ionization. In the case of mixtures, however, deviations from the previous behaviors are evidenced. The evolution of the LIDT as a function of the refractive index is analyzed, and an empirical description of the relation between refractive index and LIDT is proposed.

Nanosecond-laser-induced damage in potassium titanyl phosphate: pure 532 nm pumping and frequency conversion situations.

Nanosecond-laser-induced damage measurements in the bulk of KTiOPO4 (KTP) crystals are reported using incident 532 nm light or using incident 1064 nm light, which pumps more or less efficient second harmonic generation. No damage threshold fatigue effect is observed with pure 532 nm irradiation. The damage threshold of Z-polarized light is higher than the one for X- or Y-polarized light. During frequency doubling, the damage threshold was found to be lower than for pure 1064 or 532 nm irradiation. More data to quantify the cooperative damage mechanism were generated by performing fluence ramp experiments with varying conditions and monitoring the conversion efficiency. All damage thresholds plotted against the conversion efficiency align close to a characteristic curve.

Laser-induced damage of hafnia coatings as a function of pulse duration in the femtosecond to nanosecond range.

Laser-damage thresholds and morphologies of hafnia single layers exposed under femtosecond, picosecond, and nanosecond single pulses (1030/1064 nm) are reported. The samples were made with different deposition parameters in order to study how the damage behavior of the samples evolves with the pulse duration and how it is linked to the deposition process. In the femtosecond to picosecond regime, the scaling law of the laser-induced damage threshold as a function of pulse duration is in good agreement with the models of photo and avalanche ionization based on the rate equation for free electron generation. However, differences in the damage morphologies between samples are shown. No correlation between the nanosecond and femtosecond/picosecond laser-damage resistance of hafnia coatings could be established. We also report evidence of the transition in damage mechanisms for hafnia, from an ablation process linked to intrinsic properties of the material to a defect-induced process, that exists between a few picoseconds and a few tens of picoseconds.

Characterization of zirconia- and niobia-silica mixture coatings produced by ion-beam sputtering.

ZrO2-SiO2 and Nb2O5-SiO2 mixture coatings as well as those of pure zirconia (ZrO2), niobia (Nb2O5), and silica (SiO2) deposited by ion-beam sputtering were investigated. Refractive-index dispersions, bandgaps, and volumetric fractions of materials in mixed coatings were analyzed from spectrophotometric data. Optical scattering, surface roughness, nanostructure, and optical resistance were also studied. Zirconia-silica mixtures experience the transition from crystalline to amorphous phase by increasing the content of SiO2. This also results in reduced surface roughness. All niobia and silica coatings and their mixtures were amorphous. The obtained laser-induced damage thresholds in the subpicosecond range also correlates with respect to the silica content in both zirconia- and niobia-silica mixtures.

All-purpose finite element formulation for arbitrarily shaped crossed-gratings embedded in a multilayered stack.

We propose a novel formulation of the finite element method adapted to the calculation of the vector field diffracted by an arbitrarily shaped crossed-grating embedded in a multilayered stack and illuminated by an arbitrarily polarized plane wave under oblique incidence. A complete energy balance (transmitted and reflected diffraction efficiencies and losses) is deduced from field maps. The accuracy of the proposed formulation has been tested using classical cases computed with independent methods. Moreover, to illustrate the independence of our method with respect to the shape of the diffractive object, we present the global energy balance resulting from the diffraction of a plane wave by a lossy thin torus crossed-grating. Finally, computation time and convergence as a function of the mesh refinement are discussed. As far as integrated energy values are concerned, the presented method shows a remarkable convergence even for coarse meshes.

Multiple pulse nanosecond laser induced damage study in LiB3O5 crystals.

Multiple pulse nanosecond laser induced damage in the bulk of LiB3O5 (LBO) crystals was investigated at 1064 nm, 532 nm and 355 nm. Scanning electron microscopy of cleaved damage sites confirmed the presence of different zones that have already been reported in the case of KH2PO4 (KDP). Multi pulse measurements reveal a strong decrease of the damage threshold with increasing pulse number at 1064 nm (fatigue effect). A weaker fatigue effect was observed at 532 nm and no fatigue effect was found at 355 nm. This observation is best explained by an inherently statistical light matter interaction generating laser induced damage. Finally, a polarization dependent damage threshold anisotropy was evidenced at all three wavelengths, being strongest at 1064 nm. The results indicate the importance of Li+ vacancy stabilized color centers for the damage mechanism.

Nanosecond laser induced damage in RbTiOPO4: the missing influence of crystal quality.

Nanosecond laser induced damage in RbTiOPO(4) (RTP) an isomorphic material to the more widely known KTiOPO(4) (KTP) is studied in crystals with varying properties. The ionic conductivity along the z-axes of the tested crystals ranged from 1.5 10(-9) S/cm to 1.1 10(-12) S/cm. Further, different growth sectors with different absorption in the range of hundreds of ppm/cm and differing zones in inhomogeneous crystals have been investigated. Despite these important differences in crystal quality, no significant difference could be observed in the laser damage resistance at 1064 nm. Thus growth induced defects only play a minor role in nanosecond laser induced damage in RTP. Transient, laser induced defects are discussed in analogy with KTP as possible laser damage precursors.

Versatile full-vectorial finite element model for crossed gratings.

We demonstrate the accuracy of the finite-element method to calculate the diffraction efficiencies of an arbitrarily shaped crossed grating in a multilayered stack illuminated by an arbitrarily polarized plane wave under oblique incidence. The method has been validated by using classical cases found in the literature. Finally, to illustrate the independence of our method with respect to the shape of the diffractive object, we present the global energy balance resulting from the diffraction of a plane wave by a lossy thin torus crossed grating.

Multiscale analysis of the laser-induced damage threshold in optical coatings.

We have investigated the influence of laser beam size on laser-induced damage threshold (LIDT) in the case of single- and multiple-shot irradiation. The study was performed on hafnia thin films deposited with various technologies (evaporation, sputtering, with or without ion assistance). LIDT measurements were carried out at 1064 nm and 12 ns with a spot size ranging from a few tens to a few hundreds of micrometers, in 1-on-1 and R-on-1 modes. These measurements were compared with simulations obtained with the statistical theory of laser-induced damage caused by initiating inclusions. We show how to obtain information on the initiating defect properties and the related physical damage mechanisms with a multiscale study. Under certain conditions, it is possible with this method to discriminate different defects, estimate their densities, and follow the evolution of the defects under multiple irradiation. The different metrology implications of our approach, particularly for obtaining a functional LIDT of optical components are discussed.

Laser damage resistance of hafnia thin films deposited by electron beam deposition, reactive low voltage ion plating, and dual ion beam sputtering.

A comparative study is made of the laser damage resistance of hafnia coatings deposited on fused silica substrates with different technologies: electron beam deposition (from Hf or HfO(2) starting material), reactive low voltage ion plating, and dual ion beam sputtering. The laser damage thresholds of these coatings are determined at 1064 and 355 nm using a nanosecond pulsed YAG laser and a one-on-one test procedure. The results are associated with a complete characterization of the samples: refractive index n measured by spectrophotometry, extinction coefficient k measured by photothermal deflection, and roughness measured by atomic force microscopy.

The finite element method as applied to the diffraction by an anisotropic grating.

The main goal of the method proposed in this paper is the numerical study of various kinds of anisotropic gratings deposited on isotropic substrates, without any constraint upon the diffractive pattern geometry or electromagnetic properties. To that end we propose a new FEM (Finite Element Method) formulation which rigorously deals with each infinite issue inherent to grating problems. As an example, 2D numerical experiments are presented in the cases of the diffraction of a plane wave by an anisotropic aragonite grating on silica substrate (for the two polarization cases and at normal or oblique incidence). We emphasize the interesting property that the diffracted field is non symmetric in a geometrically symmetric configuration.

Simultaneous absorption, scattering, and luminescence mappings for the characterization of optical coatings and surfaces.

An experimental setup, based on the laser-induced deflection technique, is developed to measure simultaneously the 244 nm laser absorption, scattering, and luminescence on optical components. The different techniques and methods that have been specifically developed to obtain both high resolution (micronic) and sensitivity (a few 10(-7) of the incident power for the absorption, 10(-8) for scattering and fluorescence) are presented. Different applications are then explored: the study of losses in deep UV multilayer coatings (HfO2/SiO2 mirrors) and the analysis of contamination defects on bare substrate and structural defects in optical coatings.

High-resolution photothermal microscope: a sensitive tool for the detection of isolated absorbing defects in optical coatings.

The photothermal deflection technique allows us to highlight the presence of inhomogeneities of absorption in optical components. This nondestructive tool is of great interest to the study of the role of contaminants, inclusions, and impurities in the laser-induced damage process. We show that the detection of nanometer-sized isolated absorbing defects requires the development of an adapted photothermal setup with high detectivity and high spatial resolution. Thus it is essential to improve the resolving power up to its theoretical limit.

Photothermal deflection in multilayer coatings: modeling and experiment.

A model of the photothermal deflection signal in multilayer coatings is presented that takes into account optical interference effects and heat flow within the stack. Measurements are then taken of high-reflectivity HfO2/SiO2 ultraviolet mirrors made by plasma ion assisted deposition and compared to calculations. Good agreement is found between the experimental results and the model. Using this model for the calibration and the setup described, one can measure absorption in multilayer coatings accurately down to 10(-7) of the incident power.

Localized pulsed laser interaction with submicronic gold particles embedded in silica: a method for investigating laser damage initiation.

Laser damage phenomena in fused silica are currently under study because of numerous related high power laser applications. Nanosized defects are believed to be responsible for some laser damage initiation. In order to predict and to quantify this initiation process, engineered submicronic gold defects were embedded in silica. The study of these samples by localized pulsed irradiation of isolated gold particles coupled with Nomarski, atomic force and photothermal microscope observations permits us to discriminate between two distinct stages of material modification: one detectable at the surface and the second in the neighbourhood of the embedded particle. Comparison between the observations and simulations results in good agreement if we assume that inclusion melting initiates the damage.