Optical Hydrogen Sensing Properties of e-Beam WO3 Films Decorated with Gold Nanoparticles.

Tungsten oxide thin films with different thicknesses, crystallinity and morphology were synthesized by e-beam deposition followed by thermal treatment and acid boiling. The films with different surface morphologies were coated with gold nanoparticles and tested as optical sensing materials towards hydrogen. X-ray diffraction, scanning electron microscopy, ellipsometry and UV-VIS spectroscopy were employed to characterize the structural, morphological and optical properties of the film. We demonstrated a good response towards hydrogen in air, reaching a good selectivity among other common reducing gases, such as ammonia and carbon monoxide. The sensitivity has been proven to be highly dependent on the thickness and crystallinity of the samples.

Electrical Properties of Aluminum Nitride Thick Films Magnetron Sputtered on Aluminum Substrates.

The realization of a c-axis oriented aluminum nitride thick film on aluminum substrates is a promising step in the development of transducers for applications with a working temperature up to about 600 °C. The present paper deals with the realization of AlN thick films by means of reactive magnetron sputtering with a pulsed DC power supply, operating in continuous mode for 50 h. Two values (0.4 and 0.8) of nitrogen concentration were used; operative pressure and power were set at 0.3 Pa and 150 W, respectively. The thickness of the obtained aluminum nitride films on the aluminum substrate, assessed with a profilometer, varied from 20 to 30 µm. The preferential orientation of AlN crystals was verified by X-ray diffraction. Finally, as the main focus of the investigation, the films underwent electrical characterization by means of an LCR-meter used on a parallel plate capacitor set-up and a test system based on a cantilever beam configuration. AlN conductivity and ε33 permittivity were derived in the 100 Hz-300 kHz frequency range. Magnetron sputtering operation with nitrogen concentration equal to 0.4 resulted in the preferred operative condition, leading to a d31 piezoelectric coefficient, in magnitude, of 0.52 × 10-12 C/N.

Rad-hard properties of the optical glass adopted for the PLATO space telescope refractive components.

PLAnetary Transits and Oscillations of stars (PLATO) is a medium sized mission (M3) selected by the European Space Agency (ESA) for launch in 2026. The PLATO payload includes 26 telescopes all based on a six-element refractive optical scheme. Some components will be eventually manufactured by S-FPL51, N-KZFS11 and S-FTM16 glass whose radiation resistance is partially or totally unknown. The radiation-resistance properties of such materials have been investigated by using a 60Co γ-rays source as probe. Each optical component has been characterized by a depth profile curve which describes the transmission loss as a function of the thickness in dependence of the impinging dose. A model to simulate the throughput of the whole instrument has been developed and used to verify the instrument performance considering different stellar spectra.

Palladium on plastic substrates for plasmonic devices.

Innovative chips based on palladium thin films deposited on plastic substrates have been tested in the Kretschmann surface plasmon resonance (SPR) configuration. The new chips combine the advantages of a plastic support that is interesting and commercially appealing and the physical properties of palladium, showing inverted surface plasmon resonance (ISPR). The detection of DNA chains has been selected as the target of the experiment, since it can be applied to several medical early diagnostic tools, such as different biomarkers of cancers or cystic fibrosis. The results are encouraging for the use of palladium in SPR-based sensors of interest for both the advancement of biodevices and the development of hydrogen sensors.

Stability of EUV multilayer coatings to low energy alpha particles bombardment.

Future solar missions will investigate the Sun from very close distances and optical components are constantly exposed to low energy ions irradiation. In this work we present the results of a new experiment related to low energy alpha particles bombardments on Mo/Si multilayer optical coatings. Different multilayer samples, with and without a protecting capping layer, have been exposed to low energy alpha particles (4keV), fixing the ions fluency and varying the time of exposure in order to change the total dose accumulated. The experimental parameters have been selected considering the potential application of the coatings to future solar missions. Results show that the physical processes occurred at the uppermost interfaces can strongly damage the structure.

Extreme ultraviolet multilayer for the FERMI@Elettra free electron laser beam transport system.

In this work we present the design of a Pd/B4C multilayer structure optimized for high reflectance at 6.67 nm. The structure has been deposited and also characterized along one year in order to investigate its temporal stability. This coating has been developed for the beam transport system of FERMI@Elettra Free Electron Laser: the use of an additional aperiodic capping layer on top of the structure combines the high reflectance with filter properties useful in rejecting the fundamental harmonic when the goal is to select the third FEL harmonic.

Capped Mo/Si multilayers with improved performance at 30.4 nm for future solar missions.

Novel capping layer structures have been deposited on periodic Mo/Si multilayers to optimize reflectance at 30.4 nm. Design, deposition and characterization of such coatings are presented. Most of the structures proposed show improved performance with respect to standard Mo/Si multilayers and are stable over time. Reflectance at 121.6 nm and in the visible spectral range have been also tested to explore the applicability of such coatings to the Multi Element Telescope for Imaging and Spectroscopy (METIS) instrument, a coronagraph being developed for the ESA Solar Orbiter platform.

Stability of extreme ultraviolet multilayer coatings to low energy proton bombardment.

In this work we present results of an new experiment related to low energy protons bombardments on nano-structured optical coatings. Multilayer structures protected by different capping layers have been fabricated and exposed to low energy protons (1 keV). The experimental parameters have been selected considering the potential application of the coatings to solar mission instrumentation. Future solar missions will investigate the Sun from very close distances and optical components are constantly exposed to low energy ion particles irradiation. The experiment was repeated fixing the proton flux while varying the total dose accumulated. Results show that physical processes occurred at the uppermost interfaces can strongly damage the structure.

Iridium/silicon multilayers for extreme ultraviolet applications in the 20-35 nm wavelength range.

We have developed an Ir/Si multilayer for extreme ultraviolet (EUV) applications. Normal incidence reflectance measurements of a prototype film tuned to 30 nm wavelength show superior performance relative to a conventional Mo/Si multilayer structure; we also find good stability over time. Transmission electron microscopy and electron dispersive x-ray spectroscopy have been used to examine the microstructure and interface properties of this system: we find amorphous Si layers and polycrystalline Ir layers, with asymmetric interlayer regions of mixed composition. Potential applications of Ir/Si multilayers include instrumentation for solar physics and laboratory EUV beam manipulation.