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J Agric Food Chem ; 53(10): 4091-5, 2005 May 18.
Artigo em Inglês | MEDLINE | ID: mdl-15884844

RESUMO

The retention process of sulcotrione and its two hydrolysis products, 1,3-cyclohexanedione (CHD) and 2-chloro-4-methylsulfonylbenzoic acid (CMBA), were studied in four different soils (Belgium, Landes, Perpignan, and Martinique) under laboratory conditions. Adsorption isotherms were well fitted by a Freundlich relationship. The values of K(fa) ranged from 0.4 to 27.0, and the most adsorbed compound was CHD regardless the soil type. Sulcotrione and CMBA exhibited similar retention behaviors. According to adsorption and desorption results, sulcotrione presents a moderate affinity with soil components; however, its leaching capacity needs to be carefully assessed. Clay content seemed to be the most important factor influencing the adsorption capacity of each compound, whereas organic matter and pH had little influence. The soils were classified according to their adsorption capacity in the following decreasing order: Martinique, Belgium, Landes, Perpignan.


Assuntos
Cicloexanonas/química , Herbicidas/química , Mesilatos/química , Solo/análise , Adsorção , Silicatos de Alumínio/química , Fenômenos Químicos , Físico-Química , Argila , Concentração de Íons de Hidrogênio , Hidrólise , Cinética
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