RESUMO
We report here the observation of the enhancement of Europium-tetracycline complex emission in Low Density Lipoprotein (LDL) solutions. Europium emission band of tetracycline solution containing Europium (III) chloride hexahydrate was tested to obtain effective enhancement in the presence of native LDL and oxidized LDL. Europium emission lifetime in the presence of lipoproteins was measured, resulting in a simple method to measure the lipoproteins quantity in an aqueous solution at physiological pH. This method shows that the complex can be used as a sensor to determine the different states of native and oxidized LDL in biological fluids.
RESUMO
A new lead fluoroborate glass (PbO-PbF2-B2O3) doped with ytterbium (Yb:PbFB) is presented. Samples with different concentrations of Yb3+ were produced and had their emission cross-sections, fluorescence lifetimes and minimum pump intensities determined. They have high refractive index of 2.2 and a density of 4.4 g/cm3. For a doping level of 1.153x1020 ions/cm3, the fluorescence lifetime, after excitation at 968 nm, is 0.81 ms, which is comparable to Yb:tellurite laser glass. Also, an emission band at 1022 nm is measured with emission cross-section of approximately 1.07x10-20 cm2 and fluorescence effective linewidth of 60 nm, which is comparable to Yb:phosphate laser glass.
RESUMO
The optical properties of a new family of neodymium doped BPG (Bi2O3-PbO-Ga2O3 ) glasses are presented. We measured a high refractive index, of 2.5, and a transmission cutoff in the far infrared at 8microm. Three intense emission bands are observed centered at 877nm, 1066nm and 1341nm. The emission cross-section is 10 -20 cm 2 and the total spectral linewidth is 30nm at 1066nm. The Judd-Ofelt parameters are calculated and used to evaluate transition probability, radiative lifetime and branching ratios. The optical properties of these Nd:BPG glasses show promise for their use as a new active laser material.
