Scleroglucan-Based Foam Incorporating Recycled Rigid Polyurethane Waste for Novel Insulation Material Production.

This study details the synthesis and performance evaluation of a novel lightweight thermal and acoustic insulation material, resulting from the combination of a scleroglucan-based hydrogel and recycled rigid polyurethane waste powder. Through a sublimation-driven water-removal process, a porous three-dimensional network structure is formed, showcasing notable thermal and acoustic insulation properties. Experimental data are presented to highlight the material's performance, including comparisons with commercially available mineral wool and polymeric foams. This material versatility is demonstrated through tunable mechanical, thermal and acoustic characteristics, achieved by strategically adjusting the concentration of the biopolymer and additives. This adaptability positions the material as a promising candidate for different insulation applications. Addressing environmental concerns related to rigid polyurethane waste disposal, the study contributes to the circular economy.

Expanded Glass for Thermal and Acoustic Insulation from Recycled Post-Consumer Glass and Textile Industry Process Waste.

The production of glass foams obtained by recycling post-consumer glass and textile industry processing waste is presented. The mechanical, thermal and acoustic properties were characterized as a function of process temperature and time. The results showed that it is possible to produce glass foams with thermal and acoustic insulation properties from a mixture consisting of 96.5% of glass waste, 1% of textile waste and 2.5% of manganese dioxide, processed at temperatures between 800 and 900 °C for a time between 30 and 90 min. The samples had density in the range of 200-300 kg m-3, porosity of 87-92%, thermal conductivity of 85-105 mW m-1 K-1, noise-reducing factors of 0.15-0.40 and compressive strength of 1.2-3.0 MPa. Although their insulation performance was not as outstanding as that of polymer foams, these materials can emerge as competitive candidates for applications requiring non-flammability and high-temperature load bearing capacity in combination with low weight, mechanical strength, and thermal and acoustic insulation properties. The use of secondary raw materials (which accounted for 97.5% by weight of the synthetic blend) limits the energy required compared to that needed for the extraction, transportation and processing of primary raw materials, making these foams attractive also in terms of environmental footprint.

A sustainable acoustic customization of open porous materials using recycled plastics.

Foams are commonly used as sound absorbers and thermal insulators for many industrial and construction applications. The insulating materials market is currently dominated by inorganic fibres like glass and mineral wool, as well as plastic foams. However, worldwide plastics consumption produces huge amounts of waste, generating concerns about soil, air and especially seawater pollution. Hence, new methods for recycling marine microplastic litter according to cleaner production criteria are being sought. This paper presents a novel, sustainable and eco-friendly foamy material made of microplastic waste, namely polyethylene terephthalate (PET) and polystyrene (PS), incorporated into a bio-based matrix. Samples with different compositions were prepared and then characterized for sound absorption properties. Evidence is presented of very good acoustic performances and of how the acoustic characteristics of the end product can be customized using different microplastic content and type. This allows envisioning many industrial and civil applications for this novel open-cell material.

A critical review on marine litter in the Adriatic Sea: Focus on plastic pollution.

Marine litter affects various habitats across the world. This review focuses on the Adriatic region, considering the presence of marine litter as well as microplastics (mPs) and macroplastics (MPs) in different environments (water, beach, seabed and biota). Data from 53 scientific papers were critically analysed, providing a snapshot of this type of contamination, and evidencing critical issues. The final part of the review provides considerations on spatial and temporal trends, comparing data with the available information provided by transport forecasting models. It emerges that the most investigated areas are those most subjected to the contribution of rivers, tourism or have the greatest relevance to nature conservation. Our analysis also reveals that, even though many international research projects have played a fundamental role in the creation of shared methods and protocols, currently available data are difficult to compare. Nevertheless, our results enhance knowledge of the state of the art in the research carried out so far, and on the situation regarding pollution due to the marine litter in the Adriatic Sea, as well as highlighting avenues for future investigation.

Microplastic's story.

The problem of microplastic pollution is now the order of the day in front of everyone's eyes affecting the environment and the health of leaving creature. This work aims to retrace the history of microplastics in a critical way through a substantial bibliographic collection, defining the points still unresolved and those that can be resolved. Presence of marine litter in different environments is reviewed on a global scale, focusing in particular on micro and macro plastics definition, classification and characterization techniques.

Transparent carbon nanotubes promote the outgrowth of enthorino-dentate projections in lesioned organ slice cultures.

The increasing engineering of carbon-based nanomaterials as components of neuroregenerative interfaces is motivated by their dimensional compatibility with subcellular compartments of excitable cells, such as axons and synapses. In neuroscience applications, carbon nanotubes (CNTs) have been used to improve electronic device performance by exploiting their physical properties. Besides, when manufactured to interface neuronal networks formation in vitro, CNT carpets have shown their unique ability to potentiate synaptic networks formation and function. Due to the low optical transparency of CNTs films, further developments of these materials in neural prosthesis fabrication or in implementing interfacing devices to be paired with in vivo imaging or in vitro optogenetic approaches are currently limited. In the present work, we exploit a new method to fabricate CNTs by growing them on a fused silica surface, which results in a transparent CNT-based substrate (tCNTs). We show that tCNTs favor dissociated primary neurons network formation and function, an effect comparable to the one observed for their dark counterparts. We further adopt tCNTs to support the growth of intact or lesioned entorhinal-hippocampal complex organotypic cultures (EHCs). Through immunocytochemistry and electrophysiological field potential recordings, we show here that tCNTs platforms are suitable substrates for the growth of EHCs and we unmask their ability to significantly increase the signal synchronization and fiber sprouting between the cortex and the hippocampus with respect to Controls. tCNTs transparency and ability to enhance recovery of lesioned brain cultures, make them optimal candidates to implement implantable devices in regenerative medicine and tissue engineering.

A home-made system for IPCE measurement of standard and dye-sensitized solar cells.

A home-made system for incident photon-to-electron conversion efficiency (IPCE) characterization, based on a double-beam UV-Vis spectrophotometer, has been set up. In addition to its low cost (compared to the commercially available apparatuses), the double-beam configuration gives the advantage to measure, autonomously and with no need for supplementary equipment, the lamp power in real time, compensating possible variations of the spectral emission intensity and quality, thus reducing measurement times. To manage the optical and electronic components of the system, a custom software has been developed. Validations carried out on a common silicon-based photodiode and on a dye-sensitized solar cell confirm the possibility to adopt this system for determining the IPCE of solar cells, including dye-sensitized ones.