1.
Angew Chem Int Ed Engl
; 39(13): 2327-2330, 2000 Jul 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-10941080
2.
Angew Chem Int Ed Engl
; 38(22): 3357-3359, 1999 Nov 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-10602193
RESUMO
The Nozaki-Hiyama reaction can be performed in an enantioselective catalytic way! The catalytic system utilizes 10 mol % of an inexpensive chiral [Cr(salen)] complex. The [Cr(salen)]/Mn/Me(3)SiCl system effectively promotes the enantioselective addition of allyl chloride to aliphatic and aromatic aldehydes at room temperature (65-89 % ee, 40-60 % yield).