RESUMO
The frequent use of chemicals has caused ecosystems and humans to be threatened due to their discharge into the environment. Multimedia environmental fate models could provide a comprehensive picture of transport behaviour and fate for organic chemicals in multiple environmental media. They have been designed and widely used for chemical risk assessment, chemical ranking and management support, and determination of chemical bioaccumulation. This study reviewed the principles, features and applicability of recent commonly used multimedia fate models from peer-reviewed literature. Fugacity-based and concentration-based models are now widely adopted for use in chemical fate evaluation, while they are more appropriate for volatile and semi-volatile chemicals. Or the fugacity-based models can use aquivalence equilibrium criterion to cations, anions and involatile chemicals. The MAMI and SESAMe models based on activity approach are applicable to neutral and ionizable molecules. However, interactions of ionic species with other water solutes are not taken into account in these models. Additionally, they could not directionally simulate how chemicals transported form one grid to another. Future attention should be focused on the reliability of transfer behaviour and fate of ionizable chemicals, as integrating the advantages of these two kinds of models into a reconstructed one may be a better choice. In a word, environmental multimedia models have been beneficial tools for chemical control and management, risk and effect estimation, and decision supporting.
