Storage systems for building-integrated photovoltaic (BIPV) and building-integrated photovoltaic/thermal (BIPVT) installations: Environmental profile and other aspects.

In recent years there has been an increasing interest in Building-Integrated Photovoltaic (BIPV) and Building-Integrated Photovoltaic/Thermal (BIPVT) systems since they produce clean energy and replace conventional building envelope materials. By taking into account that storage is a key factor in the effective use of renewable energy, the present article is an overview about storage systems which are appropriate for BIPV and BIPVT applications. The literature review shows that there are multiple storage solutions, based on different kinds of materials (batteries, Phase Change Material (PCM) components, etc.). In terms of BIPV and BIPVT with batteries or PCMs or water tanks as storage systems, most of the installations are non-concentrating, façade- or roof-integrated, water- or air-based (in the case of BIPVT) and include silicon-based PV cells, lead-acid or lithium-ion batteries, paraffin- or salt-based PCMs. Regarding parameters that affect the environmental profile of storage systems, in the case of batteries critical factors such as material manufacturing, accidental release of electrolytes, inhalation toxicity, flammable elements, degradation and end-of-life management play a pivotal role. Regarding PCMs, there are some materials that are corrosive and present fire-safety issues as well as high toxicity in terms of human health and ecosystems. Concerning water storage tanks, based on certain studies about tanks with volumes of 300 L and 600 L, their impacts range from 5.9 to 11.7 GJprim and from 0.3 to 1.0 t CO2.eq. Finally, it should be noted that additional storage options such as Trombe walls, pebble beds and nanotechnologies are critically discussed. The contribution of the present article to the existing literature is associated with the fact that it presents a critical review about storage devices in the case of BIPV and BIPVT applications, by placing emphasis on the environmental profile of certain storage materials.

Biogas production by means of an anaerobic-digestion plant in France: LCA of greenhouse-gas emissions and other environmental indicators.

The present article assesses the environmental profile of a real-scale anaerobic-digestion plant that has been developed in France. The system utilises 13652 t of different types of feedstock related to food industry, agriculture, etc. The study is based on Life Cycle Assessment (LCA) according to Global Warming Potential (GWP), Cumulative Energy Demand (CED), ReCiPe midpoint/endpoint and USEtox. The life-cycle inventory includes real data from various sources of waste as well as the transportation distances. By considering the impact of both anaerobic digestion and transportation for the whole system, the following findings have been found: 6430 t CO2.eq (GWP 100a); 67194 GJprim (CED); 231100 Pts (ReCiPe endpoint single-score: Human health), 146932 Pts (ReCiPe endpoint single-score: Ecosystems), 171568 Pts (ReCiPe endpoint single-score: Resources). Furthermore, USEtox results, for the whole system and by taking into account both anaerobic digestion and transportation, show that based on: 1) Human toxicity/cancer, anaerobic-digestion phase has around 21 times higher value comparing to transportation, 2) Ecotoxicity, anaerobic-digestion phase presents about 77 times higher value than transportation. Regarding the impact of both phases (anaerobic digestion; transportation) per t of waste or per MWh of electricity, the findings show values of 0.5-0.6 t CO2.eq per t of feedstock (or digestate) or per MWh of electricity produced (not net). A separate subsection with comparisons of the present findings with literature studies about LCA of anaerobic-digestion plants has been included. In general, a good agreement has been observed. Moreover, comparisons of the impact of the electricity produced by means of the present biogas system with the impact of conventional electricity mixes of several countries are presented and discussed, proving the environmental benefits of the proposed anaerobic-digestion plant.

Payback times and multiple midpoint/endpoint impact categories about Building-Integrated Solar Thermal (BIST) collectors.

The purpose of the present article is the evaluation, by means of life cycle assessment, of a system which consists of vacuum-tube solar thermal collectors. The system is appropriate for building integration and it has been developed in France. The methods ReCiPe and USEtox have been adopted. Regarding life-cycle results, according to the scenario "without recycling" and for 30-year system lifespan, ReCiPe payback time was calculated to be 18.14 years based on France's electricity mix whereas by using Spain's electricity mix (hypothetical scenario) it was found to be 4.03 years. Recycling offers a ReCiPe-payback time reduction of 2.66 years based on France's electricity mix and 0.59 years based on Spain's electricity mix. All the studied cases show ReCiPe payback times much lower than an assumed system-lifespan of 30 years. On the basis of ReCiPe midpoint and by considering material manufacturing of the 16 collectors and the additional elements of the system (scenario "without recycling"), among glass-, aluminium-, copper- and steel-based components, the copper-based ones present the highest impact in 15 of the 18 impact categories. For instance, for Freshwater eutrophication, the copper-based elements have a score that is around 30 times higher comparing to that of the aluminium-based ones. The USEtox findings, for the material manufacturing of the 16 collectors and the supplementary elements of the system and for the scenario "without recycling", reveal that the material with the highest total score in terms of: i) human toxicity/cancer is copper (6.7E-09 CTUh), ii) human toxicity non-cancer is propylene glycol (4.0E-08 CTUh), iii) ecotoxicity is copper (2.06 CTUe). Recycling of the metals, according to USEtox, offers an impact reduction of 20-95%. A discussion about factors that influence the environmental profile of building-integrated solar systems is also provided.

Cumulative energy demand and global warming potential of a building-integrated solar thermal system with/without phase change material.

Building-integrated solar thermal (BIST) systems are a specific type of solar thermal systems which are integrated into the building and they participate in building functionality. The present article is about the life-cycle assessment of different options of a BIST system (Mediterranean climatic conditions: Ajaccio, France). The environmental profile of the studied configurations is assessed by means of CED (cumulative energy demand), GWP (global warming potential) and EPBT (energy payback time). The proposed configurations (for the collector) include: i) a system without PCM (phase change material) using only rock wool as insulation and ii) a system with PCM (myristic acid) and rock wool. Concerning life-cycle results based on CED and GWP 100a (scenario without recycling), the configuration without PCM shows 0.67 MJprim/kWh and 0.06 kg CO2.eq/kWh while the configuration with PCM presents 0.74 MJprim/kWh and 0.08 kg CO2.eq/kWh. Regarding EPBT, if the inputs for pumping/auxiliary heating are not taken into account, both configurations (with/without PCM) have almost the same EPBT (about 1.3 years). On the other hand, if the inputs for pumping/auxiliary heating are considered, EPBT is lower for the system with PCM. In addition, scenarios with recycling have been examined and the results demonstrate that recycling considerably improves the environmental profile of the studied configurations.

Renal adaptive mechanisms in aged and hypertensive humans: possible effects of treatment.

BACKGROUND: In the aging kidney renal blood flow and glomerular filtration rate are reduced due to glomerulosclerosis. On this regard, hypertension has synergistic effects and may lead to end-stage renal disease in a significant proportion of cases. MATERIAL AND METHODS: To study the effects of antihypertensive drugs in an acute setting, we expressly designed an acute experiment to assess the renal response to mental stress (MS). In healthy elderly, the response was characterized by a prolonged and pronounced renal vasoconstriction, due to a reduction in renal autacoid modulatory capacity, particularly of prostaglandins. In older patients with isolated systolic hypertension, the response to MS was impaired, being characterized by a passive vasodilation with hyperfiltration. The effects of antihypertensive drugs were evaluated twice in adults patients with mild to moderate essential hypertension: after two weeks of pharmacological wash-out and after two weeks of treatment with the ACE-inhibitor trandolapril (4 mg), or the non-dihydropyridinic Ca2+ channel blocker verapamil (240 mg), or both (2 mg + 180 mg). RESULTS: While the three antihypertensive regimens reduced blood pressure to a similar extent, their effects on the renal response to MS were different. Each regimen re-established a renal vasoconstrictive response to adrenergic activation. However, with trandolapril, renal vasoconstriction was limited, as it occurs physiologically, to the period of blood pressure rise, while verapamil, or the combination of the two drugs, were associated with more prolonged vasoconstriction. CONCLUSIONS: Further studies are needed to confirm the nephroprotective effects of these drugs, particularly of ACE-inhibitors. These data may be a pathophysiological basis for future clinical trials.

Changes in renal autacoids and hemodynamics associated with aging and isolated systolic hypertension.

The aging kidney is characterized by a decrease in renal blood flow and glomerular filtration rate mainly due to glomerulosclerosis. Nevertheless, even in the presence of these changes, the kidney maintains its functionality until advanced age. However, there is a tendency towards greater renal vasoconstriction in the elderly as compared with young individuals. This occurs either in physiological circumstances such as physical exercise, or in disease manifestations, such as the effective circulatory volume depletion that develops, for example, in heart failure. This tendency may be secondary to the reduction of renal autacoid modulatory capacity, particularly at the vasodilating prostaglandin level. In an acute experimental model we could demonstrate that, in the healthy elderly, the renal response to adrenergic activation by mental stress is characterized by a prolonged and pronounced vasoconstriction. In addition to this, in elderly patients affected by isolated systolic hypertension, we demonstrated an impairment of renal hemodynamic and humoral adaptation capacity in response to adrenergic activation and blood pressure increase. In the presence of sudden blood pressure increase, the kidney of these patients responds with a passive vasodilation and a glomerular filtration rate increase without any activation of humoral modulatory substances. The impairment in renal adaptation capacity may predispose these patients to renal injury, particularly in the presence of the many hypertensive peaks which characterize everyday life of elderly individuals. In conclusion, these results show that renal adaptation capacity of elderly patients with isolated systolic hypertension is completely lost. Further studies will elucidate whether antihypertensive treatment per se, or specific classes of antihypertensive drugs, are able to revert this impairment.

Changes in renal autacoids in aged human hypertensives.

The aging process determines several modifications of the kidney, that, however, do not provoke any dysfunction in normal conditions. But in the elderly--in the presence of stressful situations and particularly when adrenergic activation is present--the kidney is more vulnerable than in the young, and renal failure may arise. Variations typical of the aging kidney are accelerated when hypertension overlaps the physiological renal process, because both senescence and hypertension weight on the same structures, i.e. glomeruli. We studied renal hemodynamic adaptation capacity both in the healthy elderly and in patients affected by isolated systolic hypertension, in an acute experiment which requires the application of a mental stress-induced adrenergic activation. In hypertensive patients we have already demonstrated a total lack of renal adaptation capacity. In fact, while the elderly normotensives react with a prolonged and pronounced vasoconstriction, in those with isolated systolic hypertension, adrenergic activation induces a passive renal vasodilation and glomerular hyperfiltration. The anomalous adaptation capacity of renal hemodynamics is probably due to an impairment in the paracrine response of renal vasculature. Indeed in the hypertensive elderly, unlike in the normotensive one, no variations of autacoid production occur during the adrenergic activation. Following on from this, pattients affected by isolated systolic hypertension passively suffer the many hypertensive peaks which characterize their every day life. The altered renal autoregulation of the elderly with isolated systolic hypertension may explain the accelerated glomerulosclerosis and the greater incidence of renal damage and end-stage renal disease which characterize this condition. These aspects underline the primary role of the antihypertensive treatment of isolated systolic hypertension, not only for the prevention of cardiovascular mortality but also of renal damage and/or end-stage renal disease.