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1.
Mar Pollut Bull ; 135: 569-580, 2018 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-30301075

RESUMO

Theoretical arguments and numerical investigations were conducted to understand the transport of oil droplets under ice. It was found that the boundary layer (BL) in the water under ice produces a downward velocity that reaches up to 0.2% of horizontal current speed, and is, in general, larger than the rise velocity of 70 µm oil droplets. The eddy diffusivity was found to increase with depth and to decrease gradually afterward. Neglecting the gradient of eddy diffusivity when conducting Lagrangian transport of oil droplets would result in an unphysical spatial distribution. When the downward velocity of water was neglected, oil accumulated at the water-ice interface regardless of the attachment efficiency. The lift force was found to scrape off droplets of the ice, especially for droplets ≤ 70 µm. These findings suggest that previous oil spill simulations may have overestimated the number of small droplets (≤70 µm) at the water-ice interface.


Assuntos
Petróleo/análise , Poluentes Químicos da Água/análise , Simulação por Computador , Difusão , Gelo , Poluição por Petróleo/análise , Água
2.
Environ Sci Process Impacts ; 19(7): 928-938, 2017 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-28613323

RESUMO

Canada's production, transport, and sale of diluted bitumen (dilbit) products are expected to increase by a million barrels per day over the next decade. The anticipated growth in oil production and transport increases the risk of oil spills in aquatic areas and places greater demands on oil spill capabilities to respond to spills, which have raised stakeholder concerns. Current oil spill models only predict the transport of bitumen blends that are used in contingency plans and oil spill response strategies, rather than changes in the oil's physical properties that are relevant to spill response. We conducted weathering studies of five oil products (two conventional oils and three bitumen blends) in the Department of Fisheries and Oceans' flume tank. We also considered two initial oil slick thicknesses, 4.0 mm and 7.0 mm. We found that there is a major difference in the time evolution of oil properties (density and viscosity), raising doubts on weathering models that do not consider the thickness of oil. We also developed empirical expressions for the evolution of the density and viscosity of these oil products. The findings from the 4.0 mm results were incorporated with data from the literature to provide an update on the factors to consider during the decision making for spills of diluted bitumen products. The matrix indicated that most response options, including chemical dispersants, work much more effectively within 48 hours of the initiation of weathering. After this window of opportunity closes, natural attenuation or in situ burning is the only option remaining, but containment of oil is a limiting factor for in situ burning.


Assuntos
Recuperação e Remediação Ambiental/métodos , Hidrocarbonetos/análise , Modelos Teóricos , Poluição por Petróleo/análise , Poluentes Químicos da Água/análise , Canadá , Tomada de Decisões , Hidrocarbonetos/química , Viscosidade , Poluentes Químicos da Água/química , Tempo (Meteorologia)
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