1.
Chem Commun (Camb)
; 56(53): 7261-7264, 2020 Jul 02.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32469023
RESUMO
We prepare a novel COF for CO2 photoreduction with 99.9% CO selectivity in aqueous solution without a cocatalyst. DFT shows that the preferential adsorption of H+ on the COF results in increased CO2 adsorption energy providing an anchoring site of CO2, and with the cooperation of an ethylene group, CO2 reduction is triggered.