1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 1): m148-9, 2007 Dec 12.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21200502
RESUMO
The Ni atom in the title complex, (C(24)H(20)P)(2)[Ni(C(9)H(17)NO(2)S(3))(2)], lies on a twofold axis within a square-planar geometry defined by four S atoms derived from two dithio-carbimate dianions, each forming a four-membered chelate ring. A small distortion, described by a deviation of the Ni(II) atom by 0.083â (1)â Å from the plane through the four S atoms, and also by the torsion angles about the Ni-S bonds, implies a folded conformation for the chelate ring.