Partially coherent laser beam shaping in a zoom homogenizer.

This paper proposes a synthesis method including wave optics and geometric optics to design the zoom homogenizer for partially coherent laser beams and discusses the effects of the spatial coherence and system parameters on the beam performance. Based on the principles of pseudo-mode representation and matrix optics, a numerical model for fast simulation has been built and the parameter constraints for avoiding beamlet crosstalk have been presented. The relation of the size and the divergence angle of the highly uniform beams formed in the defocused plane with system parameters has been developed. The variations in the intensity profile and the uniformity of the variable-size beams during zooming have been explored.

Designing diffractive optical elements for shaping partially coherent beams by proximity correction.

We propose a new method to design diffractive optical elements (DOE) for shaping partially coherent beams. The diffraction patterns of a DOE under a certain partially coherent beam can be modeled by the convolution of the coherent diffraction pattern and the inherent degree of coherent function. Two basic types of diffraction anomalies induced by partially coherent beams are discussed, including line-end shortening and corner rounding. A proximity correction (PC) method similar to the optical proximity correction (OPC) technique in lithography is used to compensate for these anomalies. The designed DOE exhibits good performance in partially coherent beam shaping and noise suppression.

Photoacoustic identification of laser-induced microbubbles as light scattering centers for optical limiting in a liquid suspension of graphene nanosheets.

Liquid suspensions of carbon nanotubes, graphene and transition metal dichalcogenides have exhibited excellent performance in optical limiting. However, the underlying mechanism has remained elusive and is generally ascribed to their superior nonlinear optical properties such as nonlinear absorption or nonlinear scattering. Using graphene as an example, we show that photo-thermal microbubbles are responsible for optical limiting as strong light scattering centers: graphene sheets absorb incident light and become heated up above the boiling point of water, resulting in vapor and microbubble generation. This conclusion is based on the direct observation of bubbles above the laser beam as well as a strong correlation between laser-induced ultrasound and optical limiting. In situ Raman scattering of graphene further confirms that the temperature of graphene under laser pulses rises above the boiling point of water but still remains too low to vaporize graphene and create graphene plasma bubbles. Photo-thermal bubble scattering is not a nonlinear optical process and requires very low laser intensity. This understanding helps us to design more efficient optical limiting materials and understand the intrinsic nonlinear optical properties of nanomaterials.

Extrinsic Green Photoluminescence from the Edges of 2D Cesium Lead Halides.

Since the first report of the green emission of 2D all-inorganic CsPb2 Br5 , its bandgap and photoluminescence (PL) origin have generated intense debate and remained controversial. After the discovery that PL centers occupy only specific morphological structures in CsPb2 Br5 , a two-step highly sensitive and noninvasive optical technique is employed to resolve the controversy. Same-spot Raman-PL as a static property-structure probe reveals that CsPbBr3 nanocrystals are contributing to the green emission of CsPb2 Br5 ; pressure-dependent Raman-PL with a diamond anvil cell as a dynamic probe further rules out point defects such as Br vacancies as an alternative mechanism. Optical absorption under hydrostatic pressure shows that the bandgap of CsPb2 Br5 is 0.3-0.4 eV higher than previously reported values and remains nearly constant with pressure up to 2 GPa in good agreement with full-fledged density functional theory (DFT) calculations. Using ion exchange of Br with Cl and I, it is further proved that CsPbBr3- x Xx (X = Cl or I) is responsible for the strong visible PL in CsPb2 Br5- x Xx . This experimental approach is applicable to all PL-active materials to distinguish intrinsic defects from extrinsic nanocrystals, and the findings pave the way for new design and development of highly efficient optoelectronic devices based on all-inorganic lead halides.

4.24 µm mid-infrared laser based on a single Fe2+-doped ZnSe microcrystal.

In this Letter, we report for the first time, to the best of our knowledge, a micron-sized mid-infrared Fe2+:ZnSe laser based on a single microcrystal. Typical laser emissions centering at 4.24 µm are observed from a selected Fe2+-doped ZnSe microcrystal under 2.94 µm excitation of Er:YAG laser at room temperature. The laser linewidth is ∼10 nm, the pulse width is ∼50 ns, and the lasing threshold is ∼7.4 mJ/pulse. The lasing wavelength is stable as the pump energy increases and is consistent with the strong absorption position of carbon dioxide in the atmosphere.