Performance and mechanism of U(vi) removal from solution by humic acid-coated Fe3O4 nanoparticle-modified biochar from filamentous green algae.

The adsorbent material humic acid-coated Fe3O4 nanoparticle-modified biochar from filamentous green algae was fabricated by introducing the composites of humic acid-coated Fe3O4 nanoparticles onto biochar from filamentous green algae using the co-precipitation method. Then, the removal of U(vi) from solution by humic acid-Fe3O4/BC was carried out through batch experiments. The results of the characterization showed that the reaction conditions had an important influence on U(vi) removal by humic acid-Fe3O4/BC. The pseudo-second-order kinetic model and Langmuir model better illustrate the adsorption process of U(vi) on the surface of humic acid-Fe3O4/BC. The adsorption processes were dominated by chemisorption and monolayer adsorption. The maximum adsorption capacity of U(vi) by humic acid-Fe3O4/BC could be calculated, and it could reach 555.56 mg g-1. The probable mechanisms of U(vi) removal by humic acid-Fe3O4/BC were reduction reaction, inner-sphere surface complexation and electrostatic adsorption. The high stability and reusability of humic acid-Fe3O4/BC made it more promising in U(vi) removal applications.

Effects of Fe(II) and humic acid on U(VI) mobilization onto oxidized carbon nanofibers derived from the pyrolysis of bacterial cellulose.

The effects of Fe(II) and humic acid on U(VI) immobilization onto oxidized carbon nanofibers (Ox-CNFs, pyrolysis of bacterial cellulose) were investigated by batch, spectroscopic and modeling techniques, with results suggesting that, Ox-CNFs exhibited fast adsorption rate (adsorption equilibrium within 3 h), high adsorption performance (maximum adsorption capacity of 208.4 mg/g), good recyclability (no notable change after five regenerations) in the presence of Fe(II) towards U(VI) from aqueous solutions (e.g., 40 % reduction and 10 % adsorption at pH 8.0), which was attributed to the various oxygen-containing functional groups, excellent chemical stability, large specific surface area and high redox effect. U(VI) adsorption increased with increasing pH from 2.0 to 5.0, then high-level plateau and remarkable decrease were observed at 5.0-6.0 and at pH > 6.0, respectively. According to FT-IR and XPS analysis, a negative correlation between U(VI) reduction and organic in the presence of Fe(II) implied that U(VI) reduction was driven by Fe(II) while inhibited by humic acid. The interaction mechanism of U(VI) on Ox-CNFs was demonstrated to be adsorption and ion exchange at low pH and reduction at high pH according to XPS and surface complexation modeling. These findings filled the knowledge gaps pertaining to the effect of Fe(II) on the transformation and fate of U(VI) in the actual environment. This carbon material with distinctive performance and unique topology offers a potential platform for actual application in environmental remediation.