RESUMO
Polar poly(vinylidene fluoride) (PVDF) nanotubes have attracted significant attention due to their excellent piezoelectric and ferroelectric properties, yet a tunable fabrication of homogeneous polar PVDF nanotubes remains a challenge. Here, a simple method is reported to fabricate polar PVDF nanotubes using anodize aluminum oxide (AAO) membranes as templates that are removed by etching in a potassium hydroxide (KOH) solution and then ageing at room temperature. PVDF nanotubes originally crystallized in the AAO membrane are pure α-crystals with very low crystallinity, yet after being released from the templates, the crystallinity of the nanotubes markedly increases with ageing at room temperature, leading to the formation of ß-PVDF crystals in a very short time, with the formation of γ crystals after longer ageing times. A large amount of γ crystals formed when the released PVDF nanotubes are heated to ≈130 °C. The formation of polar PVDF nanotubes released from the AAO templates treated with higher concentrations of alkaline solution results from the reaction of the surface of the PVDF nanotubes with the alkaline solution and structure reorganization under confined conditions. This large-scale preparation of ß- and γ-PVDF opens a new pathway to produce polar PVDF nanomaterials.
RESUMO
Polyimide (PI) can be used as a cladding insulation for high frequency power transformers, and along-side discharge can lead to insulation failure, so material modification techniques are used. In this paper, different doped nano-SiO2 are introduced into polyimide for nanocomposite modification. The results of testing the life time of high-frequency electrical stress along-side discharge show that the 10% SiO2 doping has the longest life time. The results show that: for composites prone to corona, their flashover causes more damage, and both positive half-cycle and polarity reversal discharges are more violent; compared to pure PI, the positive half-cycle and overall discharge amplitude and number of modified films are smaller, but the negative half-cycle is larger; at creeping development stages, the number of discharges is smaller, and the discharge amplitude of both films fluctuates in the mid-term, with the modified films having fewer discharges and the PI films discharging more violently in the later stages. The increase in the intensity of the discharge was greater in the later stages, and the amplitude and number of discharges were much higher than those of the modified film, which led to a rapid breakdown of the pure polyimide film. Further research found that resistivity plays an important role in the structural properties of the material in the middle and late stages, light energy absorption in the modified film plays an important role, the distribution of traps also affects the discharge process, and in the late stages of the discharge, the heating of the material itself has a greater impact on the breakdown, so the pure polyimide film as a whole discharges more severely and has the shortest life.
RESUMO
In this work, different types of polyethylene (linear, spiral nanofibers and microspheres) were obtained via confined polymerization by a PPM-supported Ziegler-Natta catalyst. Firstly, the Ziegler-Natta catalyst was chemical bonded inside the porous polymer microspheres (PPMs) supports with different pore diameter and supports size through chemical reaction. Then slightly and highly confined polymerization occurred in the PPM-supported Ziegler-Natta catalysts. SEM results illustrated that the slightly confined polymerization was easy to obtain linear and spiral nanofibers, and the nanofibers were observed in polyethylene catalyzed by PPMs-1#/cat and PPMs-2#/cat with low pore diameter (about 23â nm). Furthermore, the highly confined polymerization produced polyethylene microspheres, which obtained through other PPM-supported Ziegler-Natta catalysts with high pore diameter. In addition, high second melting point (Tm2: up to 143.3 °C) is a unique property of the polyethylene obtained by the PPM-supported Ziegler-Natta catalyst after removing the residue through physical treatment. The high Tm2 was ascribed to low surface free energy (σe), which was owing to the entanglement of polyethylene polymerized in the PPMs supports with interconnected multi-modal pore structure.
RESUMO
Poly(vinylidene fluoride) (PVDF) nanotubes were fabricated by melt-wetting into porous anodic aluminum oxide (AAO) templates with two different interfacial properties: one is pristine AAO, and the other is modified by FOTS (AAO-F). Their crystallization and melting behaviors are compared with those of a bulk sample. For the PVDF in AAO-F, the nonisothermal crystallization temperature is slightly lower than that of bulk, and the melting temperature is similar to that of bulk. For the PVDF in pristine AAO, when the pore diameter is 200 nm, the crystallization is induced by two kinds of nucleation: heterogeneous nucleation and interface-induced nucleation. On the contrary, in the AAO template with pore diameter smaller than 200 nm, only interface-induced nucleation occurs. The melting temperature of PVDF crystals in the pristine AAO is much higher than that of bulk which can be attributed to the presence of an interfacial layer of PVDF on the template inner surface. The interaction between PVDF and AAO template produces the interfacial layer. Such an interfacial layer plays an important role in enhancing the melting temperature of PVDF crystals. The higher melting peak is always observed when the PVDF is nonisothermally crystallized in the AAO template irrespective of the thermal erasing temperature suggesting the interfacial layer is very stable on the AAO template surface. If the PVDF nanostructures are released from AAO template, the higher melting peak disappears with the enhancement of thermal erasing temperature.
