RESUMO
In the present study, a facile nano-sized gamma alumina was synthesized and then examined for immobilization of cobalt and cesium ions individually from aqueous solutions. The comprehensive analysis of functional groups, phase composition, surface morphology and sorption characteristics of the synthesized nano-sized Ï alumina was executed. It was deduced that acquired material was low-crystalline with a high elimination efficacy towards the concerned cations under slightly alkali and acidic conditions. Time-transient elimination scrutiny was executed and cobalt elimination rate was found relatively faster than cesium cations. Equilibrium sorption examinations confirmed that the sorption is proceeding via two diverse sites on the scavenger surface. Cobalt and cesium elimination is a spontaneous endothermic reaction of increased chaos. The attained results proved the high proficiency of the synthesized scavenger in the cations immobilization.
RESUMO
Adsorption of radioactive europium from aqueous solution was achieved using activated carbon - epoxy composite. The preparation of activated carbon - epoxy composite was reported using gamma radiation. The ratio of the activated carbon: epoxy was 50:50 Wt %. Irradiation of the mixture by the dose 20 KGy in gamma cell was performed. The physicochemical properties of the prepared composite were investigated by using different analytical techniques. The obtained results were analyzed using different kinetic models. The sorption kinetic process fitted with the pseudo-second-order model preferably than the pseudo-first-order model. The sorption mechanism was achieved by multi-diffusion steps comprising both film and intra-particle diffusion. The monolayer capacity of the composite was 297.62 mg/g. The thermodynamic parameters were studied. The negative value of ΔG0 and the positive value of ΔH0 revealed the spontaneous and endothermic nature of the sorption process.
